Fuel Cell Control Device Warm-Up Voltage Management

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Solution Overview

Problem

During fuel cell system warm-up operations, insufficient oxygen supply to the cathode can lead to the generation of 'pumping hydrogen,' causing inefficiencies and potential oxygen shortages, which are not adequately addressed by existing technologies.

Innovation Solution

A fuel cell system with a control device that manages oxidant gas supply and current sweep to ensure sufficient oxygen is provided to the cathode, implementing stand-by control to maintain constant current until sufficient voltage is reached, and normal current control to prevent excessive current sweeps, thereby reducing hydrogen pumping and maintaining power generation stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If current sweep is started during warm-up operation with reduced oxidant gas supply, then warm-up efficiency is improved, but pumping hydrogen is generated at the cathode due to oxygen shortage

Engineering Contradiction:
Improvewarm-up efficiencyVSAvoidpumping hydrogen generation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The control device determines a voltage condition that must be satisfied before starting current sweep during warm-up operation. By establishing this preliminary voltage threshold, the system ensures sufficient oxygen is available at the cathode before high current is applied, preventing pumping hydrogen generation while still enabling efficient warm-up once the condition is met

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The control device continuously monitors the voltage of the fuel cell stack and uses this feedback to determine when to start current sweep. The voltage condition serves as a feedback mechanism that dynamically controls the timing of current sweep based on real-time stack voltage levels, ensuring oxygen availability before high current operation

Inventive Principle:
Principle #23Feedback

2Power

If oxidant gas supply is reduced during warm-up operation, then power generation output is improved, but oxygen shortage at cathode causes pumping hydrogen and potential oxygen depletion

Engineering Contradiction:
Improvepower generation outputVSAvoidoxygen supply quantity
Core Design Contradiction:
PowerVSQuantity of substance

Solution Approach 1:

The system dynamically adjusts oxidant gas supply based on operational phase and voltage conditions. During warm-up, oxidant gas supply is reduced to improve power output, but the control device dynamically determines when to start current sweep based on voltage conditions, creating a dynamic balance between power output and oxygen availability that prevents pumping hydrogen

Inventive Principle:
Principle #15Dynamics

3Speed

If current command value changes rapidly during warm-up, then response speed is improved, but voltage instability occurs and pumping hydrogen is generated

Engineering Contradiction:
Improveresponse speedVSAvoidvoltage stability
Core Design Contradiction:
SpeedVSStability of the object's composition

Solution Approach 1:

The control device establishes a voltage condition as a preliminary requirement before allowing current sweep to start. This preliminary voltage threshold ensures that the fuel cell stack is in a stable state with sufficient oxygen availability before rapid current changes are permitted, thereby maintaining voltage stability while enabling fast response when conditions are appropriate

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces the generation of pumping hydrogen, ensures stable power generation, and controls the charge/discharge of secondary batteries within acceptable limits by maintaining optimal oxygen supply and power balance during warm-up operations.

Implementation Method 1

a fuel cell stack 116 that has a plurality of stacked fuel cells 11

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

a temperature sensor 73 configured to measure a temperature related to the fuel cell system

Methodology Applied
Scientific EffectTemperature measurement:

Implementation Method 3

a voltage sensor 91 configured to measure a voltage of the fuel cell stack 116

Methodology Applied
Scientific EffectVoltage measurement:

Implementation Method 4

an oxidant gas supply system 30A configured to supply the cathode with an oxidant gas containing oxygen

Methodology Applied
Scientific EffectGas flow:

Implementation Method 5

a fuel gas supply system 50A configured to supply the anode with a fuel gas

Methodology Applied
Scientific EffectGas flow:

Data Source

PatentEP3902041B1Fuel cell system
Publication Date: 2023.03.22 TOYOTA JIDOSHA KK
  • EP3902041B1 patent drawingFigure 1
  • EP3902041B1 patent drawingFigure 2
  • EP3902041B1 patent drawingFigure 3

AI summary

A fuel cell system (10) includes a fuel cell stack (116) and a control device (60). The control device (60) raises the voltage of the fuel cell stack (116) until a predetermined voltage condition is met, by supplying a cathode with an oxidant gas before current sweep is started when the fuel cell system (10) is started and a value measured by a temperature sensor (38) is equal to or less than a temperature determined in advance. The control device (60) executes stand-by control, in which a current command value is kept constant, when a measured voltage value reaches a control start voltage value smaller than a voltage command value in a transition period, and ends the stand-by control by permitting a change in the current command value when the measured voltage value reaches a permission voltage value equal to or more than the voltage command value during execution of the stand-by control.