Fuel Cell Hydrogen Flow Sequence for LOHC Energy Systems

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Solution Overview

Problem

Existing energy generation methods using fuel cells with hydrogenated liquid organic hydrogen carriers (LOHC) face inefficiencies due to direct branching of hydrogen to heating devices, limiting electrical current generation efficiency.

Innovation Solution

Connecting the chemical reactor, fuel cell, and heating device in series, allowing hydrogen produced to flow through the fuel cell first, enabling partial load operation and optimizing hydrogen distribution through subreactors and heating subdevices based on electrical power requirements, with a controller/regulator managing flow and temperature for maximum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If hydrogen is directly branched to heating device from chemical reactor, then heating requirement is satisfied, but electrical power output efficiency decreases

Engineering Contradiction:
Improveelectrical power outputVSAvoidhydrogen utilization efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

Instead of the conventional approach where hydrogen is branched directly to the heating device, the patent inverts the flow sequence by routing hydrogen through the fuel cell first, then to the heating device. This reversal optimizes electrical power generation by ensuring the fuel cell operates with sufficient hydrogen supply (stoichiometric surplus), thereby resolving the contradiction between meeting heating requirements and maximizing electrical output efficiency.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent introduces dynamic control elements (controller/regulator) that adjust hydrogen flow distribution between the fuel cell and heating device based on real-time operational parameters. This dynamic adjustment allows the system to optimize electrical power output while satisfying heating requirements, transforming a static inefficient configuration into a dynamically optimized system.

Inventive Principle:
Principle #15Dynamics

2Power

If hydrogen flow is increased to fuel cell for maximum electrical output, then electrical power increases, but heat generation for reactor decreases

Engineering Contradiction:
Improveelectrical power outputVSAvoidreactor temperature
Core Design Contradiction:
PowerVSTemperature

Solution Approach 1:

The controller/regulator implements feedback control by continuously monitoring electrical power output requirements and reactor temperature needs, then dynamically adjusting hydrogen flow distribution. This feedback mechanism ensures that when electrical power demand increases, the system can allocate more hydrogen to the fuel cell while maintaining adequate heat generation for the reactor through coordinated control, thus resolving the trade-off between electrical output and reactor temperature.

Inventive Principle:
Principle #23Feedback

3Productivity

If series configuration is used (reactor-fuel cell-heating device), then electrical power output efficiency improves, but system complexity increases

Engineering Contradiction:
Improveenergy generation efficiencyVSAvoidsystem configuration complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The series configuration integrates multiple functions into a unified hydrogen flow path: the fuel cell generates electricity while its exhaust heat and the heating device work together to provide thermal energy for the reactor. This multi-functional integration achieves high energy generation efficiency without proportionally increasing system complexity, as the same hydrogen flow serves multiple purposes sequentially.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The controller/regulator acts as an intermediary that manages the complexity of the series configuration by automating hydrogen flow distribution and coordination between components. This intermediary control system simplifies operation and maintenance while enabling the sophisticated series configuration to achieve optimal energy generation efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration enhances electrical power output and heat utilization efficiency by operating the fuel cell with a stoichiometric hydrogen surplus, minimizing hydrogenated LOHC consumption, and optimizing heat generation, thereby improving overall energy generation efficiency.

Implementation Method 1

Electricity is generated with a high degree of efficiency in a fuel cell as a result of the electrochemical combination of hydrogen (H2) and oxygen (O2) at an electrode to form water (H2O)

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

In the chemical reactor, hydrogen is produced by at least partial dehydrogenation of the liquid organic hydrogen carrier

Methodology Applied
Scientific EffectDehydrogenation: Chemical Transport Reactions

Implementation Method 3

heat for the chemical reactor is generated in a heating device (e.g., a catalytic combustor) from at least a part of the produced hydrogen

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS10840529B2Method for generating energy and energy generation device for mobile applications
Publication Date: 2020.11.17 SIEMENS ENERGY GLOBAL GMBH & CO KG
  • US10840529B2 patent drawing
  • US10840529B2 patent drawing
  • US10840529B2 patent drawing

AI summary

A method for generating energy in mobile applications, such as water vehicles, wherein hydrogen is produced by at least partially dehydrogenating a hydrogenated liquid organic hydrogen carrier (LOHC) in a chemical reactor, where electricity and water are generated in at least one fuel cell and heat for the chemical reactor is generated in a heating device from the produced hydrogen, and where the hydrogen produced by the chemical reactor is first conducted through the at least one fuel cell and then supplied to the heating device, such that the at least one fuel cell can therefore be operated under partial load and thus with better efficiency than if the hydrogen for the heating device is branched off before the fuel cell.