Fuel Cell Hydrogen Removal via Preliminary Voltage

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Solution Overview

Problem

Fuel cell systems face durability issues due to carbon corrosion from oxygen when air is left inside after shutdown and increased fire/explosion risks from high hydrogen concentrations upon restart.

Innovation Solution

A fuel cell system with a controller that applies voltages to move hydrogen from the cathode to the anode through an electrolyte membrane before operation, reducing oxygen and hydrogen concentrations, thereby preventing corrosion and safety hazards.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If air remains in the system after shutdown, then the system can be easily stopped, but carbon corrosion occurs due to oxygen reducing fuel cell durability

Engineering Contradiction:
Improvesystem shutdownVSAvoidfuel cell durability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The controller applies a preliminary voltage to the fuel cell stack before shutdown to actively remove oxygen from the system. This preliminary action prevents carbon corrosion by eliminating the harmful oxygen environment before the system stops operating, thereby protecting fuel cell durability while maintaining easy shutdown operation.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If hydrogen remains in the system after shutdown, then the system can be easily stopped, but the concentration of hydrogen in discharged gases increases creating fire or explosion danger

Engineering Contradiction:
Improvesystem shutdownVSAvoidfire or explosion danger
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The controller applies a preliminary voltage to the fuel cell stack before shutdown to actively remove hydrogen from the system. This preliminary action reduces hydrogen concentration in the system before shutdown, thereby eliminating fire or explosion dangers while maintaining easy shutdown operation.

Inventive Principle:
Principle #10Preliminary action

3Object-affected harmful factors

If voltage is applied to move hydrogen from cathode to anode, then hydrogen concentration in cathode decreases improving safety, but additional energy consumption occurs

Engineering Contradiction:
Improvehydrogen discharge riskVSAvoidenergy consumption
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The voltage application to move hydrogen occurs only briefly before shutdown rather than continuously. This preliminary, time-limited action sufficiently reduces hydrogen concentration to improve safety while minimizing additional energy consumption compared to continuous operation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively reduces oxygen and hydrogen concentrations, enhancing fuel cell durability and safety by minimizing carbon corrosion and hydrogen discharge risks.

Implementation Method 1

an electrolyte membrane, and a cathode and an anode that are a pair of electrodes disposed on opposite sides of the electrolyte membrane

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

when the voltages are applied to the cathode and the anode, hydrogen that resides in the cathode flows to the anode through the electrolyte membrane

Methodology Applied
Scientific EffectElectroosmosis: Electro-Osmosis

Data Source

PatentUS10818946B2Fuel cell system and method for controlling the same
Publication Date: 2020.10.27 HYUNDAI MOTOR CO LTD
  • US10818946B2 patent drawing
  • US10818946B2 patent drawing
  • US10818946B2 patent drawing

AI summary

A fuel cell system that has a fuel cell stack is provided. The system includes an electrolyte membrane, and a cathode and an anode that are a pair of electrodes disposed on opposite sides of the electrolyte membrane. A controller applies voltages to the cathode and the anode of the fuel cell stack before hydrogen that operates the fuel cell stack is supplied to the anode. When the voltages are applied to the cathode and the anode, hydrogen that resides in the cathode flows to the anode through the electrolyte membrane to decrease the concentration of the hydrogen in the cathode. The fuel cell system reduces the concentration of hydrogen discharged to the outside of the vehicle by reducing the concentration of hydrogen in the cathode before driving of the fuel cell is initiated.