Fuel Cell Impedance Usability Judgment for Detection Accuracy

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Solution Overview

Problem

The existing methods for detecting the internal state of a fuel cell, particularly the wet/dry state of the electrolyte membrane, face accuracy issues due to the assumption of impedance values belonging to a straight part of the Nyquist diagram, leading to errors when they actually belong to an arcuate part, which affects the accuracy of hydrogen and oxygen detection.

Innovation Solution

A fuel cell internal state detection system that includes an estimation object state quantity setting unit, an impedance value acquisition unit, an impedance usability judging unit, and an estimation object state quantity calculation unit to determine whether the impedance values are usable for calculation, and performs an unusable-scene process when they are not, allowing for accurate detection of internal states by distinguishing between arc and non-arc regions in the impedance curve.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If the impedance value is used to calculate the ionomer resistance value based on a supposed equation from the imaginary part of the impedance, then the calculation can be performed, but the accuracy of detecting the wet/dry state of the electrolyte membrane is reduced when the impedance value belongs to an arcuate part of the Nyquist diagram

Engineering Contradiction:
Improvecalculation simplicityVSAvoiddetection accuracy
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The Nyquist diagram is divided into two distinct regions: a straight part and an arcuate part. The impedance usability judging unit segments the impedance data based on which region the measured impedance belongs to, applying different calculation approaches accordingly. This segmentation resolves the contradiction by ensuring that the simple supposed equation is only used when appropriate (straight part), while alternative methods are used for the arcuate part, thus maintaining both calculation simplicity where applicable and detection accuracy where required.

Inventive Principle:
Principle #1Segmentation

2Productivity

If the impedance value belongs to an arcuate part of the Nyquist diagram, then the calculation of ionomer resistance value can be performed, but the error between the calculated value and actual value becomes large

Engineering Contradiction:
Improvecalculation efficiencyVSAvoidcalculation accuracy
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The system dynamically adjusts the calculation method based on the characteristics of the measured impedance. The impedance usability judging unit evaluates whether the impedance belongs to the straight or arcuate part of the Nyquist diagram and automatically selects the appropriate calculation approach. This dynamic adaptation ensures that calculation efficiency is maintained through the simple supposed equation when valid, while calculation accuracy is preserved by switching to alternative methods when dealing with arcuate region impedances.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system changes the calculation parameters and methods based on the impedance characteristics. When the impedance is determined to be in the arcuate part, the system alters the calculation approach from the simple supposed equation to alternative methods that account for the arcuate characteristics. This parameter change resolves the contradiction by adapting the calculation methodology to the specific impedance region, thereby maintaining both efficiency and accuracy.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If the impedance usability judging unit is added to determine whether the impedance value is usable, then the detection accuracy is improved, but the device complexity increases

Engineering Contradiction:
Improvedetection accuracyVSAvoidsystem complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The impedance usability judging unit provides feedback on the quality and applicability of the measured impedance value. This feedback mechanism determines whether the impedance belongs to the straight or arcuate part of the Nyquist diagram and guides the subsequent calculation process. The feedback approach improves detection accuracy by ensuring that only suitable impedance values are used for calculation, while the complexity increase is minimized through automated decision-making algorithms that evaluate impedance characteristics.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This system enhances the accuracy of detecting internal states by determining the usability of impedance values, ensuring precise calculation of state quantities, thereby improving the detection of hydrogen, oxygen, and wet/dry states in fuel cells.

Implementation Method 1

In estimating/calculating the above state quantity, it is known to measure and use an impedance value.

Methodology Applied
Scientific EffectImpedance measurement: Electrical Resistance

Data Source

PatentUS10193174B2Fuel cell internal state detection system and state detection method
Publication Date: 2019.01.29 NISSAN MOTOR CO LTD
  • US10193174B2 patent drawing
  • US10193174B2 patent drawing
  • US10193174B2 patent drawing

AI summary

A fuel cell internal state detection system includes estimation object state quantity setting unit for setting a suitable estimation object state quantity as an index of an internal state, an impedance value acquisition unit configured to obtain an impedance value of a fuel cell, an impedance usability judging unit configured to judge whether or not the obtained impedance value is usable for the calculation of the estimation object state quantity, estimation object state quantity calculation unit for calculating the estimation object state quantity set by the estimation object state quantity setting unit on the basis of the obtained impedance value when the impedance value is judged to be usable for the calculation of the estimation object state quantity by the impedance usability judging unit, and an unusable-scene process execution unit configured to perform an unusable-scene process when the impedance value is judged not to be usable for the calculation of the estimation object state quantity by the impedance usability judging unit.