Fuel Cell Voltage Control for Hydrogen Leakage Detection

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Solution Overview

Problem

Fuel cells face challenges in determining hydrogen leakage during startup, which can impair durability and lead to uneven gas distribution causing electrode degradation, and existing methods either overshoot voltage or require reaching open-circuit voltage to assess leakage, both of which are detrimental.

Innovation Solution

A fuel cell system with a control method that raises the voltage from a starting voltage to an operation voltage lower than open-circuit voltage and uses pressure sensors to determine hydrogen leakage by analyzing pressure changes before reaching operational voltage, allowing for accurate leakage detection without damaging the fuel cell.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen and air are supplied at high pressure to a fuel cell when the fuel cell starts operation, then the electrode degradation is prevented, but the voltage of the fuel cell overshoots its upper-limit voltage

Engineering Contradiction:
Improveelectrode durabilityVSAvoidvoltage overshoot
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent applies preliminary action by pressurizing the hydrogen and air systems before starting the fuel cell operation. The control device increases the pressure of hydrogen and air supplied to the fuel cell to predetermined levels before ignition, ensuring proper gas distribution in electrodes from the start and preventing degradation without causing voltage overshoot during normal operation.

Inventive Principle:
Principle #10Preliminary action

2Measurement precision

If the voltage of the fuel cell is raised to the open-circuit voltage to determine hydrogen leakage, then the leakage detection is performed, but the durability of the fuel cell is adversely affected

Engineering Contradiction:
Improvehydrogen leakage detection accuracyVSAvoidfuel cell durability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent applies parameter changes by monitoring the pressure change rate of the hydrogen system during the voltage raising process, rather than raising the voltage to open-circuit level. The control device calculates the rate of pressure change and compares it against threshold values to determine hydrogen leakage, enabling accurate detection while maintaining voltage below levels that damage the fuel cell.

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the voltage of the fuel cell is raised quickly during startup, then the startup time is reduced, but the voltage overshoots and electrode degradation occurs

Engineering Contradiction:
Improvestartup speedVSAvoidelectrode durability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent applies preliminary action by completing pressure normalization of hydrogen and air systems before initiating voltage rise. This ensures that when voltage is raised during startup, the gases are already properly distributed in the electrodes, preventing degradation even if voltage increases quickly. The control device normalizes pressures first, then raises voltage, achieving both fast startup and electrode protection.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables accurate hydrogen leakage detection without compromising fuel cell durability, preventing electrode degradation and voltage overshoot, and ensuring efficient startup operations.

Implementation Method 1

a fuel cell that generates electricity through an electrochemical reaction between a fuel gas and an oxidant gas

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

a pressure sensor that detects pressure in the hydrogen system

Methodology Applied
Scientific EffectPressure detection:

Data Source

PatentUS9853313B2Fuel cell system, control method for the fuel cell system, and electric vehicle equipped with the fuel cell system
Publication Date: 2017.12.26 TOYOTA JIDOSHA KK
  • US9853313B2 patent drawing
  • US9853313B2 patent drawing
  • US9853313B2 patent drawing

AI summary

A fuel cell system that includes a fuel cell that generates electricity through an electrochemical reaction between a fuel gas and an oxidant gas, and a control portion that determines whether there is leakage of the fuel gas. The control portion has start means for starting the fuel cell by raising the voltage of the fuel cell from a starting voltage to an operation voltage that is lower than an open-circuit voltage, and leakage determination means for determining whether there is leakage of the fuel gas before the voltage of the fuel cell reaches the operation voltage when the fuel cell is started.