Fuel Cell Electrolyte Membrane With Dual-Viscosity Pore Impregnation

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Solution Overview

Problem

Existing electrolyte membranes for fuel cells face challenges in achieving complete impregnation of pores with ionomer solutions, leading to discontinuous proton transport passages and reduced conductivity due to air bubbles trapped within the porous support.

Innovation Solution

The use of a porous support impregnated with two ionomer solutions of different viscosities, where a high-viscosity first ionomer solution is applied to one surface and a low-viscosity second ionomer solution to the opposite surface, forming distinct layers that occupy portions of the pores without mixing, thereby reducing bubble formation and enhancing proton conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If ionomer is injected multiple times into the pores of the porous support, then the pores can be filled with ionomer to form proton transport passages, but air bubbles are introduced and trapped in the pores, creating discontinuities

Engineering Contradiction:
Improvepore impregnation completenessVSAvoidproton transport continuity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

The patent changes the viscosity parameter of the ionomer solution to resolve the contradiction. By using a low-viscosity ionomer solution, the solution can easily penetrate and fill the pores of the porous support without trapping air bubbles, achieving both complete impregnation and continuous proton transport passages

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces a porogen as an intermediary substance during the membrane formation process. The porogen creates the porous structure in a controlled manner, allowing ionomer solution to uniformly penetrate the pores without air bubble entrapment, thus ensuring both complete filling and transport continuity

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If a single ionomer solution is used to impregnate the porous support, then the process is simple, but the ionomer cannot completely fill the pores, resulting in discontinuous proton transport passages

Engineering Contradiction:
Improveimpregnation process simplicityVSAvoidproton transport passage continuity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the viscosity parameter of the ionomer solution to low viscosity, which enables the solution to completely fill the pores of the porous support in a single impregnation step. This maintains process simplicity while achieving continuous proton transport passages

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If high-viscosity ionomer solution is used, then the ionomer layer formation is easier, but the solution cannot penetrate the pores completely, leaving air bubbles

Engineering Contradiction:
Improveionomer layer formation easeVSAvoidpore filling completeness
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the viscosity parameter to low viscosity, which resolves the contradiction by enabling complete pore penetration while still allowing easy ionomer layer formation on the membrane surface through controlled application

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively increases proton conductivity, reduces discontinuity in the ionomer layers, and enhances the durability of the electrolyte membrane by ensuring complete pore impregnation without bubbles, thus improving the overall performance of the fuel cell.

Implementation Method 1

a first ionomer layer including a first ionomer solution penetrating into the pores from a first surface of the porous support, and a second ionomer layer including a second ionomer solution penetrating into the pores from a second surface of the porous support

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Data Source

PatentUS11855311B2Electrolyte membrane for fuel cell having improved ion channel continuity and method of manufacturing same
Publication Date: 2023.12.26 HYUNDAI MOTOR CO LTD
  • US11855311B2 patent drawing
  • US11855311B2 patent drawing
  • US11855311B2 patent drawing

AI summary

Disclosed are an electrolyte membrane and a method of manufacturing the same. The electrolyte membrane, in which the continuity of a channel through which protons move is improved, may include ionomer solutions having different viscosities and a porous support having pores therein.