Fuel Cell Membrane Electrode Assembly Resin Frame Joining

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Solution Overview

Problem

Conventional fuel cell membrane electrode assemblies have low joining strength between the MEA and the gasket structure body, leading to inadequate mechanical stability and potential deformation issues due to adhesive-only bonding.

Innovation Solution

A resin frame member is integrated around the solid polymer electrolyte membrane, with an impregnation portion joining the resin frame member to the outer marginal portions of the electrodes, enhancing the joining strength and reducing deformation by localized heating and impregnation, rather than relying solely on adhesion.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If adhesive layer is used to join MEA and gasket structure body, then ease of manufacture is improved, but joining strength deteriorates

Engineering Contradiction:
Improveease of manufactureVSAvoidjoining strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent divides the joining interface into two distinct segments: an adhesive layer for initial positioning and a resin impregnation layer for strong bonding. The resin impregnation portion is formed by heating a specific region to melt resin that then penetrates into the electrode, creating a mechanically interlocked structure that significantly enhances joining strength while maintaining manufacturing simplicity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent employs a composite joining system combining adhesive material and resin material with different functions. The adhesive provides initial bonding and positioning, while the resin (particularly high-melting-point resin with glass fillers) provides structural strength and mechanical interlocking. This composite approach allows each material to optimize its properties for its specific function, resolving the contradiction between ease of manufacture and joining strength.

Inventive Principle:
Principle #40Composite materials

2Device complexity

If adhesive-only bonding is used, then device complexity is reduced, but reliability deteriorates

Engineering Contradiction:
Improvedevice complexityVSAvoidreliability
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The joining system is segmented into functional zones: the adhesive layer handles positioning and initial bonding, while the resin impregnation portion (formed by localized heating) provides reliable mechanical interlocking and structural integrity. This segmentation allows each component to perform its optimized function without significantly increasing overall device complexity.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the physical state parameter of the resin from solid to liquid through localized heating, enabling the resin to flow and penetrate into the electrode pores. This parameter change creates a reliable mechanical interlock that significantly enhances bonding reliability. The use of high-melting-point resin with glass fillers further improves reliability by maintaining structural integrity under fuel cell operating conditions.

Inventive Principle:
Principle #35Parameter changes

3Strength

If resin frame member is joined to both first electrode and second electrode, then joining strength is improved, but deformation increases

Engineering Contradiction:
Improvejoining strengthVSAvoiddeformation
Core Design Contradiction:
StrengthVSShape

Solution Approach 1:

The patent applies local quality by forming the resin impregnation portion only in specific localized regions rather than uniformly across the entire resin frame member. By concentrating the resin impregnation at critical joining points, the patent achieves sufficient joining strength while minimizing the total volume of resin that undergoes thermal processing, thereby reducing overall deformation and warpage of the resin frame member.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method provides improved joining strength, reduces peeling and warpage, and allows for the use of high-melting-point resin with glass fillers, resulting in a more stable and cost-effective fuel cell membrane electrode assembly.

Implementation Method 1

heating the overlapped portions of the first electrode and the resin frame member to melt only the inner marginal portion of the resin frame member

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 2

impregnate only the outer marginal portion of the first electrode with the inner marginal portion of the resin frame member

Methodology Applied
Scientific EffectImpregnation: Absorption (physical)

Data Source

PatentUS10658683B2Method for producing electrolyte membrane electrode assembly for fuel cells
Publication Date: 2020.05.19 HONDA MOTOR CO LTD
  • US10658683B2 patent drawing
  • US10658683B2 patent drawing
  • US10658683B2 patent drawing

AI summary

A method for preparing a fuel cell membrane electrode assembly, where the membrane electrode assembly includes a solid polymer electrolyte membrane and a first electrode and a second electrode provided on both sides of the solid polymer electrolyte membrane. The first electrode and the second electrode each include an electrode catalyst layer and a gas diffusion layer. The method includes forming the first electrode and the second electrode on both sides of the solid polymer electrolyte membrane, providing a preformed resin frame member around the solid polymer electrolyte membrane, overlapping an outer marginal portion of the first electrode and an inner marginal portion of the resin frame member with each other and applying heat and pressure to the overlapped portions of the first electrode and the resin frame member to join the resin frame member around the solid polymer electrolyte membrane.