Fuel Cell Moisture Control via Membrane Separation

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Solution Overview

Problem

Existing fuel cell systems face issues with moisture management, leading to reduced reforming efficiency and fuel cell degradation due to excessive moisture supply, and insufficient steam during load variations, which affects electric power generation.

Innovation Solution

A fuel cell system with a moisture quantity adjustment device and feedback control unit that separates and adjusts moisture in the fuel gas to ensure appropriate moisture levels, using a steam reforming type reformer and a combination of steam and partial oxidization reforming, with a non-organic separation membrane and feedback channels to recycle moisture, preventing carbon precipitation and maintaining reaction efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a large quantity of moisture is supplied to the reformer to prevent reduction in reforming efficiency and degradation of catalytic reforming material, then reforming efficiency is maintained, but a large quantity of extra water is generated that causes fuel cell body degradation and reduced reaction efficiency

Engineering Contradiction:
Improvereforming efficiencyVSAvoidexcessive moisture
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The invention extracts and removes excess moisture from the fuel gas stream using a moisture separation device positioned between the reformer and fuel cell body. This separation process removes the harmful excess water while preserving the necessary moisture for reforming efficiency, preventing fuel cell degradation without sacrificing reforming performance

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention implements a feedback control system that monitors moisture content in the fuel gas and adjusts the moisture supply to the reformer accordingly. The control unit receives signals about the moisture content and regulates the moisture supply to maintain optimal levels, preventing both excessive moisture accumulation and insufficient moisture for reforming

Inventive Principle:
Principle #23Feedback

2Object-generated harmful factors

If moisture supply is reduced to avoid excessive water generation and fuel cell degradation, then water management is improved, but steam becomes insufficient during load variations causing reduced reaction efficiency

Engineering Contradiction:
Improveexcessive moistureVSAvoidreaction efficiency
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention employs dynamic control of moisture supply through the feedback control system that continuously adjusts moisture input based on operating conditions and load variations. The moisture separation device also dynamically adjusts the degree of moisture removal to maintain optimal moisture levels across different operating scenarios, ensuring reaction efficiency is maintained during load transitions

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The invention changes the moisture content parameter of the fuel gas by selectively removing excess moisture while preserving adequate steam levels. The system dynamically adjusts the moisture parameter based on load conditions, maintaining the moisture content within an optimal range that prevents degradation while ensuring sufficient steam for high-temperature reforming reactions during load variations

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If moisture is not adjusted during load variations from low to high output power, then system operation is simple, but steam quantity becomes insufficient causing reduced reaction efficiency

Engineering Contradiction:
Improvesystem operationVSAvoidreaction efficiency
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The feedback control unit automatically detects load variations and adjusts moisture supply and separation accordingly, eliminating the need for manual intervention while maintaining reaction efficiency. The system self-regulates based on operating conditions, keeping the operation simple yet effective

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively responds to load variations, maintains reaction efficiency, and improves fuel utilization and thermal efficiency by ensuring optimal moisture supply, achieving self-sufficiency in moisture and reducing thermal energy loss.

Implementation Method 1

a steam reforming type reformer (20) and a combination of steam and partial oxidization reforming

Methodology Applied
Scientific EffectSteam reforming: Chemical Transport Reactions

Implementation Method 2

a steam reforming type reformer (20) and a combination of steam and partial oxidization reforming

Methodology Applied
Scientific EffectPartial oxidization reforming: Chemical Transport Reactions

Implementation Method 3

using a non-organic separation membrane

Methodology Applied
Scientific EffectMembrane separation: Semipermeable Membrane

Implementation Method 4

caused to flow and contact on respective electrodes to perform electric power generation

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Data Source

PatentUS8497042B2Fuel cell system
Publication Date: 2013.07.30 NISSAN MOTOR CO LTD
  • US8497042B2 patent drawing
  • US8497042B2 patent drawing
  • US8497042B2 patent drawing

AI summary

Disclosed is a fuel cell system comprising a reformer and a fuel cell body to which a fuel gas reformed through the reformer and air are supplied and in which the supplied fuel gas and air are separated from each other and caused to flow and contact on respective electrodes to perform electric power generation. A moisture quantity adjustment device is configured to adjustably separate a portion of moisture included in the fuel gas supplied from the reformer in order for the moisture included in the fuel gas to be supplied to the fuel cell body in an appropriate quantity.