Fuel Cell Using Liquid NaK Alloy Reducing Agent

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Conventional fuel cells face challenges in storing hydrogen gas due to its gaseous state at room temperatures, requiring high pressures to remain liquid, which limits their ability to provide sustained electrical power.

Innovation Solution

The development of fuel cells utilizing a liquid sodium-potassium alloy (NaK) as the reducing agent and a halogen oxidizing agent, such as chlorine, which remains liquid at moderate temperatures and pressures, allowing for a high energy density comparable to gasoline.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If hydrogen gas is used as the reducing agent, then the fuel cell can operate at room temperature, but the storage capacity is insufficient to provide significant electrical power over a significant period of time

Engineering Contradiction:
Improvestorage capacity of reducing agentVSAvoidstorage temperature requirements
Core Design Contradiction:
Quantity of substanceVSTemperature

Solution Approach 1:

The patent changes the physical state of the reducing agent from gaseous hydrogen to liquid metal alloy, fundamentally altering the storage parameters. The liquid metal alloy remains liquid at moderate temperatures (above its melting point of -12°C for eutectic NaK) and atmospheric pressure, eliminating the need for high-pressure storage tanks or cryogenic conditions while providing much higher energy density

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite approach by using a sodium-potassium alloy (NaK) rather than pure metal. This eutectic composition specifically engineered to achieve a low melting point while maintaining liquid state at operational temperatures, combining the advantages of both sodium and potassium metals in a synergistic formulation

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If high pressure is applied to store hydrogen in liquid form, then the energy density increases, but the device complexity and safety requirements increase

Engineering Contradiction:
Improveenergy density of fuelVSAvoidstorage system complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The patent eliminates the need for high-pressure storage by changing the physical state and chemical composition of the fuel. The liquid metal alloy achieves high energy density through its inherent liquid state at moderate conditions, removing the requirement for pressure vessels, safety valves, and complex pressure management systems

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs simple, readily available materials (sodium and potassium metals) that can be stored in conventional containers without specialized high-pressure infrastructure. The system trades the complexity of permanent high-pressure storage infrastructure for simpler, more replaceable fuel containers

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The NaK reducing agent and chlorine oxidizing agent system provides a high energy density, enabling fuel cells to offer a viable solution for sustained electrical power without the need for high-pressure storage, making them suitable for transportation applications.

Implementation Method 1

Fuel cells are electrochemical devices that utilize an oxidation-reduction reaction between two reactants (i.e., a reducing agent and an oxidizing agent) to convert chemical energy into electricity

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

Fuel cells are electrochemical devices that utilize an oxidation-reduction reaction between two reactants (i.e., a reducing agent and an oxidizing agent) to convert chemical energy into electricity

Methodology Applied
Scientific EffectReduction: Reduction

Implementation Method 3

an electrolyte present within the housing volume. The electrolyte is in fluid contact with the cathode electrode and extends between the NaK reducing agent and the cathode electrode

Methodology Applied
Scientific EffectIon transport: Electrolyte

Data Source

PatentUS10581105B2Fuel cells utilizing liquid metal alloy reducing agents and fuel cell systems including the same
Publication Date: 2020.03.03 DUFRESNE PAUL E
  • US10581105B2 patent drawing
  • US10581105B2 patent drawing

AI summary

Fuel cells utilizing liquid sodium-potassium alloy (NaK) reducing agent and fuel cell systems including the same. The fuel cells include a housing defining a housing volume and a reducing agent-containment structure defining a reducing agent-containment volume. The fuel cells also include a volume of NaK reducing agent extending within the reducing agent-containment volume and an anode conductor extending in electrical contact with the NaK reducing agent such that the NaK reducing agent forms at least a portion of an anode electrode of the fuel cell. The fuel cells further include a cathode electrode that extends within the housing volume and is spaced-apart from the NaK reducing agent, an electrolyte present within the housing volume, and an oxidizing agent supply structure configured to provide an oxidizing agent to the housing volume.