Fuel Cell Shutdown Using Nitrogen Displacement

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Fuel cells supplied with pure oxygen face challenges in controlled shutdown without nitrogen, leading to persistent electric voltage and pressure differences that can be harmful, and complicate subsequent restarts.

Innovation Solution

A shutdown procedure for fuel cells involving interruption of oxygen supply, sustained current draw, opening the oxygen feed circuit to the atmosphere, and eventual interruption of fuel gas supply, allowing for controlled voltage reduction and cessation of electrochemical reactions without nitrogen.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Power

If the fuel cell is supplied with pure oxygen, then the efficiency and power density are improved, but the cell cannot stop operating immediately when valves are turned off, leading to persistent electrochemical reactions

Engineering Contradiction:
Improvepower densityVSAvoidcontrolled shutdown
Core Design Contradiction:
PowerVSReliability

Solution Approach 1:

The patent applies preliminary action by introducing nitrogen into the fuel cell channels before shutting down the oxygen supply. This pre-prepared inert atmosphere prevents the electrochemical reaction from continuing after shutdown, solving the problem of persistent reactions that occur with pure oxygen supply. The nitrogen is readied in advance to immediately displace any remaining oxygen and hydrogen when shutdown occurs.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs an inert atmosphere by using nitrogen to replace the reactive pure oxygen environment. Nitrogen's inert properties prevent further electrochemical reactions between hydrogen and oxygen after the supply valves are closed. This creates a non-reactive environment that safely stops the fuel cell operation while maintaining the benefits of pure oxygen operation during normal functioning.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Reliability

If nitrogen is used to stop the electrochemical reaction, then the shutdown control is improved, but a reserve of nitrogen is required and subsequent restarting is interfered with by nitrogen presence

Engineering Contradiction:
Improveshutdown controlVSAvoidnitrogen supply system
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies universality by making the existing air intake system serve dual functions: providing oxygen during normal operation and providing nitrogen during shutdown. The air intake valve and associated piping are used to introduce ambient air (which contains nitrogen) into the fuel cell channels when needed, eliminating the need for a separate dedicated nitrogen storage system while maintaining effective shutdown control.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The fuel cell system performs self-service by using its own existing air intake infrastructure to provide the nitrogen needed for shutdown. Rather than requiring an external nitrogen supply system, the system utilizes ambient air introduced through its normal air intake pathways, making the shutdown function available using already-present components and eliminating additional system complexity.

Inventive Principle:
Principle #25Self-service

3Duration of action of stationary object

If the electrochemical reaction continues after shutdown, then the voltage persists, but this creates safety risks and pressure differences harmful to cell elements

Engineering Contradiction:
Improvereaction persistenceVSAvoidpressure differences
Core Design Contradiction:
Duration of action of stationary objectVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful effect of persistent electrochemical reactions into a beneficial outcome by using the reaction's own gas consumption to create a vacuum that draws in nitrogen. The continued reaction consumes the remaining hydrogen and oxygen, creating a pressure difference that actively pulls nitrogen into the channels, which then stops the reaction. The harmful persistence becomes the driving force for introducing the inert atmosphere.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent uses nitrogen as an intermediary substance that mediates between the persistent electrochemical reaction and the desired shutdown state. The nitrogen enters the channels and acts as a buffer that gradually displaces the reactive gases, allowing the reaction to continue at a controlled rate while progressively reducing the harmful effects until complete shutdown is achieved.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables rapid and controlled shutdown of fuel cells, reducing the risk of pressure differences and hot spots, while maintaining the system in a favorable state for quick restarts, without the need for a nitrogen supply.

Implementation Method 1

a polymer membrane that enables ions to pass between the anode and the cathode

Methodology Applied
Scientific EffectIonic conduction: Conduction (electrical)

Implementation Method 2

direct production of electrical energy by an electrochemical redox reaction between hydrogen (the fuel) and oxygen (the combustion-supporting gas)

Methodology Applied
Scientific EffectElectrochemical redox reaction: Redox Reactions

Data Source

PatentUS7901821B2Stopping a fuel cell supplied with pure oxygen
Publication Date: 2011.03.08 CONCEPTION & DEV MICHELIN SA
  • US7901821B2 patent drawing
  • US7901821B2 patent drawing
  • US7901821B2 patent drawing

AI summary

A method for shutting down an electricity supply system comprising a fuel cell, the cell being supplied with pure oxygen as the combustive gas and delivering an electric voltage to an electric power line, the system comprising a fuel gas feed circuit on the anode side and an oxygen feed circuit on the cathode side, the oxygen feed circuit comprising means that enable the said oxygen feed circuit to be opened to the atmosphere and means for delivering a stop signal to a control unit of the fuel cell. The shutting down procedure is activated on reception of a stop signal and comprises an initial stage during which the supply of oxygen is interrupted, a consumption stage during which a sustained current is drawn from the fuel cell, a neutralisation phase during which the oxygen feed circuit is opened to the atmosphere, and a final stage during which the supply of hydrogen is interrupted.