Fuel Cell with Segmented Electrochemical Cells for Pollutant Characterization

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Solution Overview

Problem

Fuel cells face performance degradation due to pollutants in reactive gases, which current technologies struggle to characterize without stopping energy supply to the electrical load.

Innovation Solution

A fuel cell design incorporating multiple coplanar electrochemical cells with a monitoring and characterization device that allows for continuous energy supply while detecting and characterizing pollutants using electrochemical methods like cyclic voltammetry, impedance spectroscopy, and polarization curves.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If operating cycles are performed to remove pollutants from reactive gas by desorption, then fuel cell performance is restored, but energy supply to electrical load is interrupted

Engineering Contradiction:
Improvefuel cell performanceVSAvoidenergy supply continuity
Core Design Contradiction:
ReliabilityVSDuration of action of moving object

Solution Approach 1:

The fuel cell stack is divided into multiple independent electrochemical cells, allowing one cell to undergo pollutant removal cycles while other cells continue to supply energy to the electrical load. This segmentation enables independent operation of characterization and power generation functions.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different electrochemical cells within the same stack are assigned different functions: some cells are dedicated to pollutant characterization and removal cycles, while other cells maintain continuous power supply. This local differentiation allows simultaneous achievement of performance restoration and energy continuity.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If pollutant characterization is performed using dedicated sensors or separate devices, then measurement precision is improved, but device complexity increases

Engineering Contradiction:
Improvepollutant detection accuracyVSAvoidsystem structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The electrochemical cells serve dual purposes: they generate electrical energy for power supply and simultaneously function as sensors for pollutant characterization. By applying electrochemical methods to the cells, the system achieves both power generation and precise pollutant detection without requiring separate dedicated sensing devices.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent combines the power generation function and pollutant sensing function into the same electrochemical cells. The cells that would traditionally only produce electricity are now also used for electrochemical characterization of pollutants, merging two functions into a single component.

Inventive Principle:
Principle #5Merging (Combining)

3Productivity

If all electrochemical cells are used for continuous power supply, then productivity is maximized, but ability to characterize pollutants is lost

Engineering Contradiction:
Improveenergy outputVSAvoidpollutant characterization capability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The stack is segmented into multiple cells with differentiated roles. A subset of cells is allocated for pollutant characterization while the remaining cells are optimized for continuous power supply, allowing the system to maintain high productivity while acquiring pollutant information.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Instead of using all cells for power supply, the system applies partial action by dedicating only some cells to characterization activities. This partial allocation ensures that productivity is not significantly compromised while still enabling pollutant detection and analysis capabilities.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enables real-time monitoring and characterization of pollutants without interrupting energy supply, improving fuel cell performance and air quality evaluation by identifying degrading substances in reactive gases.

Implementation Method 1

An electrochemical reaction takes place between two reacting gases that are continuously introduced. In a hydrogen fuel cell, the fuel gas (hydrogen) is introduced at the anode, while the oxidizing gas (pure oxygen or air) is introduced at the cathode.

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

characterize a pollutant present in at least one of the reactive gases from at least the measured response electrical signal

Methodology Applied
Scientific EffectCyclic voltammetry:

Implementation Method 3

characterize a pollutant present in at least one of the reactive gases from at least the measured response electrical signal

Methodology Applied
Scientific EffectImpedance spectroscopy:

Data Source

PatentEP3813168B1Fuel cell adapted for characterising at least one pollutant present in a reagent gas
Publication Date: 2023.03.15 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3813168B1 patent drawingFigure 1
  • EP3813168B1 patent drawingFigure 2A~2B
  • EP3813168B1 patent drawingFigure 3

AI summary

The invention relates to a fuel cell comprising: several electrochemical cells (10), including a characterization cell, coplanar with each other; a monitoring device (20) adapted to detect a decrease in the performance of the fuel cell (1) from the measured value of the reference electrical signal measured by a measuring sensor (22); and a characterization device (30) adapted to characterize a pollutant present in at least one of the reactive gases from at least the electrical response signal measured by a measuring sensor (32) connected to the characterization cell.