Fuel Cell Hydrogen Purity Screening by Pressure Rise Rate

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Solution Overview

Problem

Fuel cells experience irreversible performance degradation due to impurity gases in hydrogen-containing fuel gas, which existing technologies fail to detect before power generation, leading to inefficient power generation and potential catalyst degradation.

Innovation Solution

A fuel cell system equipped with a pressure sensor and controller that calculates the hydrogen pressure increase rate and prohibits power generation if the fuel gas pressure increase rate is lower, indicating the presence of impurities, thereby preventing the supply of poor-quality gas to the fuel cell.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If fuel gas with unknown purity is supplied to the fuel cell, then power generation can proceed, but irreversible performance degradation occurs due to impurity gases

Engineering Contradiction:
Improvepower generationVSAvoidfuel cell performance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent performs preliminary detection of fuel gas purity by measuring pressure increase rate before power generation begins. The controller calculates the pressure increase rate when fuel gas is supplied to the fuel cell, compares it against a predetermined threshold, and determines purity in advance. This preliminary action prevents impurity gas from reaching the fuel cell during power generation, resolving the contradiction between maintaining productivity and ensuring reliability.

Inventive Principle:
Principle #10Preliminary action

2Reliability

If pressure sensor and detection system are added to detect fuel gas purity, then fuel cell protection is improved, but device complexity increases

Engineering Contradiction:
Improvefuel cell protectionVSAvoidsystem structure
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent introduces a pressure sensor as an intermediary detection device that indirectly measures fuel gas purity by monitoring pressure increase rate in the fuel supply line. Instead of directly analyzing gas composition, the pressure sensor serves as a mediator that converts purity information into a measurable pressure signal. This intermediary approach enables reliable fuel cell protection while keeping the added device complexity minimal.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If fuel gas supply rate is increased to improve power generation efficiency, then productivity increases, but detection accuracy of impurity gas decreases

Engineering Contradiction:
Improvepower generation efficiencyVSAvoidimpurity detection accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent dynamically adjusts the fuel gas supply rate based on detection requirements. During the purity detection phase before power generation, the system supplies fuel gas at a controlled rate optimized for measurement accuracy. The controller calculates pressure increase rate under these dynamic conditions and compares it against thresholds. This dynamic adjustment of supply rate during the detection phase ensures high measurement precision without compromising overall power generation efficiency.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system effectively detects impurities in the fuel gas before power generation, preventing irreversible performance degradation and ensuring efficient operation by prohibiting power generation when impurities are detected, thus maintaining fuel cell integrity.

Implementation Method 1

a pressure sensor disposed in the fuel gas supply flow path

Methodology Applied
Scientific EffectPressure sensing:

Implementation Method 2

A fuel cell (FC) is a power generation device that generates electrical energy by electrochemical reaction between fuel gas (e.g., hydrogen) and oxidant gas (e.g., oxygen)

Methodology Applied
Scientific EffectElectrochemical reaction:

Implementation Method 3

hydrogen (H2) as the fuel gas supplied from the gas flow path and the gas diffusion layer, is protonated by the catalytic action of the catalyst layer

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

the protonated hydrogen goes to the oxidant electrode (cathode) through the electrolyte membrane

Methodology Applied
Scientific EffectIon transport through membrane: Permeation

Data Source

PatentUS11799108B2Fuel cell system
Publication Date: 2023.10.24 TOYOTA JIDOSHA KK
  • US11799108B2 patent drawing
  • US11799108B2 patent drawing
  • US11799108B2 patent drawing

AI summary

To provide a fuel cell system configured to suppress irreversible performance degradation of a fuel cell. A fuel cell system wherein the controller preliminarily stores a data group indicating a relationship between, when a predetermined amount of hydrogen gas is supplied from the fuel gas supplier, an amount of the supplied hydrogen gas and a hydrogen pressure increase rate; wherein the controller calculates a fuel gas pressure increase rate from a pressure change detected by the pressure sensor when the fuel gas is supplied to the fuel cell; wherein the controller determines whether or not the fuel gas pressure increase rate is smaller than the hydrogen pressure increase rate; and wherein, when the controller determines that the fuel gas pressure increase rate is smaller than the hydrogen pressure increase rate, the controller prohibits power generation of the fuel cell.