Cascade Fuel Cell Recirculation for Stable Output and Steam Supply

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Solution Overview

Problem

In fuel cell power generation systems with cascade-connected fuel cell modules, the exhaust fuel gas from a preceding stage has a lower fuel component concentration, leading to reduced output and heat generation in subsequent stages, making it difficult to maintain stable operation, especially during partial load or transient operations.

Innovation Solution

A recirculation line is introduced to supply the exhaust fuel gas from a second fuel cell module back to the fuel-side electrode of the first fuel cell module, ensuring sufficient steam for reforming and maintaining a stable operating temperature across stages.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If multiple fuel cell modules are cascade-connected to improve fuel utilization rate, then system efficiency is improved, but the fuel component concentration in exhaust fuel gas decreases in subsequent stages, suppressing output and heat generation

Engineering Contradiction:
Improvefuel utilization rateVSAvoidoutput of fuel cell module
Core Design Contradiction:
Loss of energyVSPower

Solution Approach 1:

The patent implements a recirculation line that feeds back a portion of the exhaust fuel gas from the second fuel cell module to the first fuel cell module. This feedback mechanism maintains the fuel component concentration in the exhaust fuel gas supplied to the second module, ensuring stable output and heat generation while preserving the high fuel utilization rate achieved through cascade connection.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the parameter of fuel component concentration by recirculating exhaust fuel gas. By controlling the recirculation amount, the system adjusts the fuel component concentration in the exhaust fuel gas supplied to subsequent modules, thereby maintaining optimal power output and heat generation conditions throughout the cascade-connected modules.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If exhaust fuel gas is supplied from preceding stage to subsequent stage, then fuel utilization is improved, but sufficient steam for reforming may not be obtained depending on power generation state

Engineering Contradiction:
Improvefuel utilization rateVSAvoidsteam amount
Core Design Contradiction:
Loss of energyVSQuantity of substance

Solution Approach 1:

The recirculation line provides feedback of exhaust fuel gas containing steam from the second fuel cell module to the first module. This ensures that sufficient steam is continuously available for the reforming reaction in the first module, regardless of the power generation state, thereby maintaining both high fuel utilization and adequate steam supply.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent establishes continuous circulation of exhaust fuel gas containing steam through the recirculation line. This continuous action ensures that steam is constantly supplied to the reforming reaction in the first fuel cell module, preventing interruptions in the reforming process and maintaining stable power generation across varying load conditions.

Inventive Principle:
Principle #20Continuity of useful action

3Adaptability or versatility

If amount of water in exhaust fuel gas varies with power generation state, then system adaptability is improved, but appropriate S/C ratio becomes difficult to maintain during load transitions

Engineering Contradiction:
Improveresponse to power generation stateVSAvoidS/C ratio
Core Design Contradiction:
Adaptability or versatilityVSStability of the object's composition

Solution Approach 1:

The recirculation line implements feedback control of the S/C ratio by continuously circulating exhaust fuel gas containing steam. This feedback mechanism compensates for variations in water content caused by changes in power generation state, automatically adjusting the steam supply to maintain an appropriate S/C ratio during load transitions and varying operating conditions.

Inventive Principle:
Principle #23Feedback

4Loss of energy

If exhaust fuel gas has lower fuel component concentration in subsequent stages, then fuel utilization in preceding stages is maximized, but temperature for proper operation becomes difficult to maintain

Engineering Contradiction:
Improvefuel utilization rateVSAvoidoperating temperature
Core Design Contradiction:
Loss of energyVSTemperature

Solution Approach 1:

The recirculation line feeds back exhaust fuel gas containing fuel components and heat from the second fuel cell module to the first module. This feedback mechanism maintains both the fuel component concentration and temperature in the exhaust fuel gas supplied to the second module, ensuring that proper operating temperature is maintained while preserving high fuel utilization rates in the cascade-connected system.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent changes the temperature parameter by recirculating hot exhaust fuel gas. The recirculated exhaust fuel gas carries thermal energy from the second fuel cell module back to the first module, maintaining the temperature required for proper operation in subsequent stages while preserving the high fuel utilization achieved through cascade connection.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration stabilizes the operating state and improves system efficiency by maintaining consistent fuel component concentration and steam supply, even during changes in system load, enhancing load response performance and reducing energy consumption.

Implementation Method 1

A fuel cell for generating power by chemically reacting a fuel gas and an oxidizing gas

Methodology Applied
Scientific EffectFuel cell electrochemical reaction: Fuel Cell

Implementation Method 2

each fuel cell module uses steam to reform a methane component contained in the fuel gas to be used for the power generation reaction

Methodology Applied
Scientific EffectSteam reforming: Chemical Transport Reactions

Data Source

PatentUS20230411648A1Fuel cell power generation system
Publication Date: 2023.12.21 MITSUBISHI HEAVY IND LTD
  • US20230411648A1 patent drawing
  • US20230411648A1 patent drawing
  • US20230411648A1 patent drawing

AI summary

A fuel cell power generation module includes a first fuel cell module, and a second fuel cell module capable of generating power with a first exhaust fuel gas exhausted from the first fuel cell module. It is configured such that a first recirculation line recirculates from a second exhaust fuel gas line through which a second exhaust fuel gas exhausted from the second fuel cell module flows, and the second exhaust fuel gas is supplied to a fuel-side electrode of the second fuel cell module.