Fuel Cell Stack Sealing Tightness Detection Method

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Solution Overview

Problem

Existing fuel cell systems face challenges in quickly and efficiently checking the sealing tightness of fuel cell stacks without delaying startup, and in minimizing fuel cell degradation during parking periods, particularly due to the formation of oxygen/hydrogen fronts and the slow crossover of hydrogen to the cathode, which is energy-intensive and prone to errors.

Innovation Solution

A method involving the provision of fuel into a sealed-off cathode space within the fuel cell stack, with pressure equalization between the anode and cathode spaces, allowing for rapid detection of pressure changes indicative of tightness, using cathode-side stack shutoff valves to isolate the cathode space and prevent gas exchange through the membrane, and utilizing an anode purge line to introduce fuel directly into the cathode space for chemical conversion before pressure detection.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen is pressurized in the anode during parking period to consume oxygen, then fuel cell degradation is minimized, but energy consumption increases and system complexity increases

Engineering Contradiction:
Improvefuel cell degradation preventionVSAvoidenergy consumption during parking
Core Design Contradiction:
ReliabilityVSUse of energy by moving object

Solution Approach 1:

Instead of pressurizing the anode with hydrogen to consume oxygen (conventional approach), the patent inverts the approach by pressurizing the cathode with hydrogen through the membrane crossover. This allows oxygen consumption on the cathode side directly, achieving the same degradation prevention effect with lower energy consumption and simpler system requirements.

Inventive Principle:
Principle #13The other way round (Inversion)

2Reliability

If hydrogen is pressurized in the anode during parking period, then oxygen is consumed, but the system becomes sluggish and requires long waiting time for hydrogen to reach cathode

Engineering Contradiction:
Improveoxygen consumption efficiencyVSAvoidstartup delay
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent reverses the conventional approach by directly pressurizing the cathode with hydrogen. This eliminates the time delay associated with hydrogen crossover from anode to cathode, as hydrogen is introduced directly into the cathode space where oxygen consumption occurs immediately.

Inventive Principle:
Principle #13The other way round (Inversion)

3Device complexity

If simple means are used to check sealing tightness, then system complexity is reduced, but detection reliability may be compromised

Engineering Contradiction:
Improvetightness check system complexityVSAvoidleakage detection accuracy
Core Design Contradiction:
Device complexityVSReliability

Solution Approach 1:

The patent employs the fuel cell stack's own components (shutoff valves, pump, and existing pressure sensing capability) to perform the tightness check. The pump serves dual purposes: it pressurizes the cathode for both the tightness check and for the actual oxygen consumption function. This self-service approach achieves reliable detection without adding dedicated complex testing equipment.

Inventive Principle:
Principle #25Self-service

4Ease of manufacture

If tightness check is performed with simple means, then manufacturing cost is reduced, but detection precision may be insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidpressure change detection accuracy
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The existing pressure sensing infrastructure of the fuel cell system is utilized for tightness detection. The system uses its own pump to create pressure differentials and monitors pressure changes through existing sensors, achieving precise leak detection without requiring specialized expensive equipment, thereby maintaining ease of manufacture while ensuring measurement precision.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables rapid, energy-efficient, and reliable detection of leaks and minimizes fuel cell degradation by ensuring the cathode space is inert, reducing the likelihood of oxygen/hydrogen fronts and allowing for accurate identification of pipe damage or leakage, thus enhancing the system's service life and startup efficiency.

Implementation Method 1

providing of fuel into a cathode space K, sealed off gas-tight against further components of a cathode subsystem, formed at least partly by the fuel cell stack; and/or converting of the provided fuel chemically with an oxidizing agent present in the cathode space K into another compound

Methodology Applied
Scientific EffectChemical conversion: Chemical Bonding

Implementation Method 2

there is no possibility of deliberately pressurizing the cathode with hydrogen through the membrane. Instead, one must wait for a rather long time until hydrogen arrives at the cathode side through the crossover

Methodology Applied
Scientific EffectHydrogen crossover: Permeation

Implementation Method 3

detecting of at least one value which is indicative of a pressure change in the cathode space K

Methodology Applied
Scientific EffectPressure detection:

Data Source

PatentUS11251448B2Method for determining the sealing tightness of a fuel cell stack
Publication Date: 2022.02.15 BAYERISCHE MOTOREN WERKE AG
  • US11251448B2 patent drawing
  • US11251448B2 patent drawing

AI summary

A method for determining a sealing tightness of a fuel cell stack includes providing of fuel into a cathode space, sealed off gas-tight against further components of a cathode subsystem, formed at least partly by the fuel cell stack, and detecting of a value which is indicative of a pressure change in the cathode space, where a cathode test pressure in the cathode space is higher than a pressure outside the fuel cell stack.