Fuel Cell Sensor for Impurity Gas Detection

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Solution Overview

Problem

Anode dead-end-type fuel cells face issues with impurity gas accumulation, leading to decreased power generation performance and membrane electrode assembly deterioration due to carbon oxidation, as existing techniques either wastefully discharge fuel gas or fail to effectively monitor hydrogen deficiency across multiple cells.

Innovation Solution

A fuel cell system with a specific flow path structure in selected cells, equipped with sensors to measure parameter values indicating fuel gas concentration and impurity gas levels, allowing for targeted discharge of impurity gas-containing anode off-gas to maintain optimal fuel gas concentration and prevent membrane electrode assembly deterioration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If impurity gas-containing anode off gas is discharged out of the fuel cell to prevent membrane electrode assembly deterioration, then membrane electrode assembly durability is improved, but fuel gas is wastefully discharged

Engineering Contradiction:
Improvemembrane electrode assembly durabilityVSAvoidfuel gas waste
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The patent applies local quality by differentiating between cells with different potentials for hydrogen deficiency. Instead of uniformly discharging anode off gas from all cells, the system identifies specific cells (second cell with specific flow path structure) that are more prone to hydrogen deficiency and targets impurity gas discharge specifically to those cells. This localized approach prevents membrane electrode assembly deterioration in vulnerable cells while minimizing fuel gas waste from cells that do not require discharge.

Inventive Principle:
Principle #3Local quality

2Measurement precision

If local current is measured in all cells to detect hydrogen deficiency, then detection accuracy is improved, but device complexity increases

Engineering Contradiction:
Improvehydrogen deficiency detection accuracyVSAvoidnumber of sensors required
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent uses copying by creating a second cell that replicates the flow path structure of other cells but is specifically designed to be more prone to hydrogen deficiency. This second cell serves as a representative model or copy that, when monitored, provides information about the hydrogen deficiency status of the entire fuel cell stack. By measuring local current in this single representative cell rather than all cells, the system achieves adequate detection accuracy while significantly reducing the number of sensors required.

Inventive Principle:
Principle #26Copying

3Productivity

If fuel gas concentration is maintained in all cells by frequent discharge, then power generation performance is improved, but fuel gas loss increases

Engineering Contradiction:
Improvepower generation efficiencyVSAvoidfuel gas discharge frequency
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The patent applies local quality by identifying that different cells have different potentials for fuel gas concentration decrease due to manufacturing variations in pressure loss. Instead of maintaining fuel gas concentration uniformly across all cells through frequent discharge, the system targets concentration maintenance specifically in the second cell type that has higher potential for concentration decrease. This localized maintenance approach improves power generation efficiency in vulnerable cells while minimizing unnecessary fuel gas discharge from other cells.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables effective use of fuel gas while preventing membrane electrode assembly deterioration by accurately detecting and managing fuel gas and impurity gas concentrations, reducing unnecessary fuel gas discharge and enhancing power generation efficiency.

Implementation Method 1

the second cell is provided with a sensor that measures a specific parameter value relating to the decrease in concentration of the fuel gas in the second fuel gas flow path

Methodology Applied
Scientific EffectGas concentration detection:

Implementation Method 2

Fuel cells generating electricity by an electrochemical reaction of hydrogen (fuel gas) with oxygen (oxidizing gas)

Methodology Applied
Scientific EffectElectrochemical reaction:

Implementation Method 3

a membrane electrode assembly that is obtained by attaching an anode (hydrogen electrode) and a cathode (oxygen electrode) to respective surfaces of a proton-conductive electrolyte membrane

Methodology Applied
Scientific EffectProton conduction: Conduction (electrical)

Implementation Method 4

an impurity gas, such as nitrogen, which is included in the air supplied to the cathodes and has no contribution to power generation, is transmitted through the electrolyte membranes and is accumulated on the anodes

Methodology Applied
Scientific EffectGas transmission through membrane: Permeation

Data Source

PatentUS8652698B2Fuel cell, fuel cell system, and control method of fuel cell system
Publication Date: 2014.02.18 NIPPON SOKEN
  • US8652698B2 patent drawing
  • US8652698B2 patent drawing
  • US8652698B2 patent drawing

AI summary

A fuel cell has multiple cells, the multiple cells including a first cell having a first fuel gas flow path, and a second cell having a second fuel gas flow path and a sensor that measures a specific parameter value relating to a decrease in concentration of fuel gas in the second fuel gas flow path.