Fuel Cell Separator Antimony-Doped Tin Oxide Coating

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Solution Overview

Problem

Fuel cell separators with conductive oxide coatings face challenges in achieving high electrical conductivity between units due to the rigidity of the separators, which hinders effective contact and conductivity when pressed against flexible carbon sheets.

Innovation Solution

A fuel cell separator featuring an antimony-doped tin oxide film with a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer content of 15% to 25% by volume, which enhances flexibility and electrical conductivity while maintaining corrosion resistance, and an element ratio of sulfur and carbon to tin between 0.6 and 1.1, allowing improved contact resistance and adhesion between separators.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If the separator is made rigid to maintain structural stability, then structural stability is improved, but electrical conductivity between separators deteriorates due to inability to deform and make close contact

Engineering Contradiction:
Improvestructural stabilityVSAvoidelectrical conductivity between separators
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent employs a flexible polymer coating film containing antimony-doped tin oxide particles that can deform under pressure. This flexible thin film structure allows the separator to conform to contact surfaces and establish intimate electrical contact with adjacent separators, while the underlying rigid substrate maintains overall structural stability.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The composite structure of polymer-coated antimony-doped tin oxide particles embedded in a substrate creates a multi-phase material that combines the rigidity of the substrate with the flexibility of the polymer coating, enabling simultaneous achievement of structural stability and electrical contact conductivity.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves high electrical conductivity and improved corrosion resistance between separators, optimizing the contact resistance and maintaining the conductive network of tin oxide particles, thereby enhancing the overall performance of the fuel cell separator.

Implementation Method 1

CVD coating film made of a conductive oxide... electrical conductivity... antimony-doped tin oxide film

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Implementation Method 2

poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer... flexibility and electrical conductivity

Methodology Applied
Scientific EffectPolymer flexibility: Elasticity

Data Source

PatentUS11127957B2Fuel cell separator
Publication Date: 2021.09.21 TOYOTA JIDOSHA KK
  • US11127957B2 patent drawing
  • US11127957B2 patent drawing
  • US11127957B2 patent drawing

AI summary

A fuel cell separator having high electrical conductivity is provided. A fuel cell separator including, on a substrate, an antimony-doped tin oxide film, in which the antimony-doped tin oxide film contains a poly(3,4-ethylenedioxythiophene)/polyethylene glycol (PEDOT/PEG) copolymer in a content of 15% by volume or more but 25% by volume or less is provided.