Fuel Cell Stack Leak Detection Using Shutdown Voltage Discharge

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Solution Overview

Problem

Current methods for detecting hydrogen leaks in fuel cell systems are inadequate, particularly in humid environments where hydrogen sensors can be damaged, and do not effectively address gas crossover leaks that occur due to aging or poor sealing, leading to inefficiencies and potential safety hazards.

Innovation Solution

A method and system that utilize a controller to initiate a shutdown process, measure and replenish hydrogen in a reservoir, discharge voltage through a resistor, and detect leaks based on the rate of voltage discharge or minimum anode negative pressure, correlating these measurements with expected values using look-up tables or calculations to identify hydrogen leaks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If hydrogen sensors are used to detect leaks in fuel cell systems, then leak detection capability is provided, but the sensors can be damaged in humid environments

Engineering Contradiction:
Improveleak detection capabilityVSAvoidsensor damage from humidity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent uses voltage discharge rate as an intermediary indicator to detect hydrogen leaks indirectly, avoiding direct exposure of sensors to humid hydrogen environments. The controller measures voltage discharge through a resistive load, and the discharge rate serves as a proxy indicator for hydrogen presence and leak detection, eliminating the need for direct hydrogen sensing in harsh conditions

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces the mechanical/electrical hydrogen sensor system with an electrochemical measurement system. Instead of using physical hydrogen sensors that are vulnerable to humidity, the system measures the electrochemical voltage discharge rate of hydrogen through a resistive load, substituting a vulnerable sensing mechanism with a more robust electrical measurement approach

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If traditional leak detection methods are used, then some leak detection is provided, but they do not effectively address gas crossover leaks due to aging or poor sealing

Engineering Contradiction:
Improveleak detection effectivenessVSAvoiddetection of aging-related leaks
Core Design Contradiction:
ReliabilityVSAdaptability or versatility

Solution Approach 1:

The patent performs preliminary leak detection during the shutdown process before the fuel cell system is fully deactivated. By initiating the shutdown sequence and measuring voltage discharge rate during this transition period, the system can detect leaks including crossover leaks from aging membranes before normal operation ceases, providing an additional detection opportunity that traditional continuous operation methods miss

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent implements periodic leak detection by utilizing the shutdown process as a regular detection interval. The voltage discharge rate measurement is performed periodically during each shutdown cycle, allowing the system to detect leaks including aging-related crossover leaks at regular intervals without requiring continuous specialized monitoring during operation

Inventive Principle:
Principle #19Periodic action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for accurate and safe detection of hydrogen leaks, preventing inefficiencies and safety hazards by identifying leaks through voltage discharge rate and pressure measurements, even in humid environments, and differentiating between internal and external leaks.

Implementation Method 1

discharging voltage in the fuel cell stack of the fuel cell system by the controller, wherein hydrogen and oxygen in the fuel cell stack are consumed in an electrochemical reaction

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Data Source

PatentUS11855320B2Fuel leak detection in fuel cell stack
Publication Date: 2023.12.26 HYDROGENICS CORP
  • US11855320B2 patent drawing
  • US11855320B2 patent drawing
  • US11855320B2 patent drawing

AI summary

The present disclosure generally relates to systems and methods for detecting a hydrogen leak in a fuel cell system including initiating a shutdown process of a fuel cell stack in the fuel cell system by a controller, measuring a volume of hydrogen in a reservoir, pulsing a volume of hydrogen into the reservoir or pulsing hydrogen directly into the fuel cell stack if the volume of hydrogen is insufficient to sustain a voltage discharge process during the shutdown process, making the fuel cell system enter a discharge state by the controller, wherein hydrogen and oxygen in the fuel cell stack are consumed in an electrochemical reaction to discharge voltage in the fuel cell stack, measuring a rate of the voltage discharge by the controller, and detecting the hydrogen leak based on the rate of the voltage discharge or via negative pressure measurements made at the anode inlet.