Fuel Cell Startup Thawing Frozen Coolant via Self-Generated Power

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Solution Overview

Problem

Fuel cell systems face challenges in starting up in freezing conditions due to frozen water in the coolant storage tank, which can lead to blockages and insufficient hydration or cooling, potentially preventing the system from operating at full power until the frozen water is thawed, and existing solutions rely on limited battery power for heating.

Innovation Solution

An evaporatively cooled fuel cell system startup method involving two phases: the first phase generates sufficient power to thaw frozen coolant using a specific oxidant-to-fuel flow ratio, and the second phase delivers heated coolant to the fuel cell assembly with a reduced oxidant-to-fuel flow ratio, allowing the system to operate efficiently and maintain thawed coolant availability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a heater is provided in the fuel cell system to maintain above-zero temperatures and prevent freezing, then the reliability of the system in freezing conditions is improved, but the device complexity increases and the battery power is limited and may fail or become discharged

Engineering Contradiction:
Improvereliability of system operation in freezing conditionsVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The fuel cell assembly itself generates the power needed to operate the heater element through controlled operation at a first oxidant-to-fuel flow ratio, making the system self-sufficient for heating without relying on external battery power or additional complex heating systems

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The system changes operational parameters by using a first oxidant-to-fuel flow ratio during the heating phase to generate sufficient power for the heater, then transitions to a second lower ratio for normal operation, allowing flexible adaptation to different operational requirements

Inventive Principle:
Principle #35Parameter changes

2Power

If the fuel cell system operates with a high oxidant-to-fuel flow ratio to generate sufficient power for heating, then the power generation capability is improved, but the operational efficiency decreases

Engineering Contradiction:
Improvepower generation capabilityVSAvoidoperational efficiency
Core Design Contradiction:
PowerVSLoss of energy

Solution Approach 1:

The system employs periodic action by operating at a first high oxidant-to-fuel flow ratio only during the initial heating phase when coolant is frozen, then transitioning to a second lower ratio for normal operation, thereby achieving high power only when necessary and maintaining efficiency during sustained operation

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The system performs preliminary action by generating sufficient power upfront to thaw the frozen coolant completely before normal operation begins, ensuring that the fuel cell assembly and coolant storage module are fully prepared for efficient operation without carrying the burden of heating during subsequent operation

Inventive Principle:
Principle #10Preliminary action

3Reliability

If the frozen coolant is thawed before delivery to the fuel cell assembly, then the reliability of coolant supply is improved, but the time required for system startup increases

Engineering Contradiction:
Improvereliability of coolant supplyVSAvoidstartup time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The fuel cell assembly performs self-service by generating its own heating power internally during the thawing process, eliminating the need for external heating systems and enabling rapid self-thawing that minimizes startup time while ensuring complete and reliable coolant thawing

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The system merges the power generation function and heating function by using the fuel cell assembly to generate power that directly drives the heater element, which in turn thaws the coolant, creating an integrated self-sufficient system that reduces overall startup time

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables reliable startup and operation of the fuel cell system in freezing conditions without relying on external power sources, ensuring continuous power generation by thawing coolant internally and maintaining efficient coolant supply, thus preventing re-freezing and ensuring reliable system commencement.

Implementation Method 1

Conventional electrochemical fuel cells convert fuel and oxidant into electrical energy and a reaction product

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Implementation Method 2

sufficient electrical power can be generated for the assembly itself to power a first heater element to thaw frozen coolant

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 3

operating a fuel cell assembly with a first ratio of oxidant flow to fuel flow sufficient to cool the fuel cell assembly

Methodology Applied
Scientific EffectEvaporative cooling: Evaporative Cooler

Data Source

PatentEP3595065B1Fuel cell and coolant storage
Publication Date: 2021.03.03 INTELLIGENT ENERGY LTD
  • EP3595065B1 patent drawingFigure 1~2
  • EP3595065B1 patent drawingFigure 3
  • EP3595065B1 patent drawingFigure 4

AI summary

A method of operating a fuel cell system (1) comprising a fuel cell assembly (2) configured to generate electrical power from a fuel flow and an oxidant flow, the method comprising a first phase and a subsequent second phase, the first phase comprising; operating the fuel cell assembly (2) with a first stoichiometric ratio of oxidant flow to fuel flow to generate electrical power; providing said generated electrical power to a heater element (12) for heating a coolant for supply to said fuel cell assembly (2); the second phase comprising; delivering coolant heated in the first phase to the fuel cell assembly (2); operating the fuel cell assembly (2) with a second stoichiometric ratio of oxidant flow to fuel flow to generate electrical power, the second stoichiometric ratio lower than the first ratio.