Uniform Drying Method for Solid Polymer Electrolyte Fuel Cell Stacks

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Solution Overview

Problem

Existing drying methods for solid polymer electrolyte fuel cells often result in non-uniform drying, leading to damage and reduced lifetime, especially during shutdown and storage at freezing temperatures.

Innovation Solution

A method that ensures uniform drying power along the fuel cell length by adjusting operating parameters such as reactant humidities, flow rates, and stoichiometry, with a control system to maintain a desired drying power profile, typically less than 0.05 (Mol/sec)/(A/cm2), and terminating the drying process based on relative humidity in the oxidant exhaust.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If conventional drying methods are used to remove water from fuel cell stacks, then water content is reduced, but non-uniform drying occurs causing damage to the membrane and reduced cell lifetime

Engineering Contradiction:
Improvewater contentVSAvoidcell lifetime
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent applies local quality by varying operating parameters (current density, reactant flow rates, temperature, pressure) along the length of the fuel cell stack to achieve uniform drying power distribution. Different sections of the stack receive tailored drying conditions based on their local water content and drying requirements, preventing both over-drying and under-drying at different locations.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent employs parameter changes by dynamically adjusting multiple operating parameters during the drying process. Current density, reactant stoichiometry, flow rates, temperature, and pressure are varied in a coordinated manner to maintain optimal drying power throughout the stack, transforming the drying process from a static operation to a dynamically controlled multi-parameter process.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If drying power is increased to speed up the drying process, then drying time is reduced, but non-uniform drying and membrane damage occur

Engineering Contradiction:
Improvedrying speedVSAvoiddrying uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies dynamics by implementing a dynamic control strategy where operating parameters are continuously adjusted during the drying process. The system transitions from static, fixed-parameter drying to a dynamic process where current density, flow rates, and temperature are varied in real-time to maintain uniform drying power, allowing high drying speeds without sacrificing uniformity.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The patent employs feedback control by monitoring drying progress and adjusting operating parameters based on measured conditions. Sensors detect water content, temperature, and other parameters, and the control system modifies current density and reactant flow rates accordingly, creating a closed-loop system that maintains optimal drying uniformity while achieving high productivity.

Inventive Principle:
Principle #23Feedback

3Power

If the fuel cell is operated at high current density during drying, then drying power is increased, but non-uniform drying occurs along the cell length

Engineering Contradiction:
Improvedrying powerVSAvoiddrying uniformity along length
Core Design Contradiction:
PowerVSStability of the object's composition

Solution Approach 1:

The patent applies segmentation by dividing the fuel cell stack into multiple sections or zones along its length, each with potentially different optimal drying conditions. The control system manages each section independently or in groups, allowing high overall drying power while maintaining uniformity through localized parameter optimization in different stack regions.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces damage to the fuel cell membrane and extends its lifetime by ensuring consistent drying, preventing leaks and maintaining performance after freeze/thaw events.

Implementation Method 1

the drying is accomplished by operating the fuel cell at a low current density

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

the presence of ice inside can result in permanent damage to the stack

Methodology Applied
Scientific EffectHeat conduction: Conduction (thermal)

Data Source

PatentUS7659017B2Drying method for fuel cell stacks
Publication Date: 2010.02.09 FORD MOTOR CO
  • US7659017B2 patent drawing
  • US7659017B2 patent drawing
  • US7659017B2 patent drawing

AI summary

For various reasons, it can be desirable to subject fuel cells to drying procedures. In solid polymer electrolyte fuel cells for instance, drying may be carried out prior to storing at below freezing temperatures, or to recover cell performance lost following freeze/thaw events. An improved drying method involves drying the cell uniformly throughout. That is, the drying power over the length of the fuel cell is adjusted to be essentially uniform. This can be accomplished by using an appropriate set of operating conditions. The improved drying method can improve the lifetime of the fuel cell.