Fuel Cell Cooling Water Control for Purity and Conductivity

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Solution Overview

Problem

In fuel cell systems, managing water levels and purity in a closed loop cooling circuit is challenging due to insufficient water recovery from cathode exit streams and increased conductivity from contaminants, which can lead to performance degradation and corrosion.

Innovation Solution

The method involves controlling the amount of water removed from the fuel cell stack based on operational parameters like current draw, conductivity, or total dissolved solids, using a closed loop system with heat exchangers and pumps to maintain desired water levels and purity, with the amount of water removed proportional to the current drawn, and using a controller to adjust operations dynamically.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If water is recovered from cathode exit streams to maintain closed loop operation, then water availability for cooling and hydration is improved, but water purity deteriorates due to contaminants and corrosion products

Engineering Contradiction:
Improvewater availabilityVSAvoidwater purity
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by monitoring conductivity (a parameter indicating water purity) and adjusting the proportion of fresh water addition dynamically. When conductivity exceeds a threshold, the system increases fresh water addition to restore purity, while maintaining closed-loop operation to conserve water quantity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system implements feedback control by continuously monitoring water conductivity and using this information to adjust the proportion of fresh water added to the closed loop. This closed-loop feedback mechanism ensures water purity is maintained while minimizing water loss, resolving the contradiction between water availability and purity.

Inventive Principle:
Principle #23Feedback

2Manufacturing precision

If proportion of fresh water addition is increased to maintain water purity, then water quality is improved, but system complexity and parasitic loads increase

Engineering Contradiction:
Improvewater purityVSAvoidsystem complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies dynamics by making the fresh water addition proportion variable rather than fixed. The system dynamically adjusts the fresh water addition rate based on real-time conductivity measurements, allowing simple proportional control that adapts to changing conditions without requiring complex control systems.

Inventive Principle:
Principle #15Dynamics

Solution Approach 2:

The system changes the parameter of fresh water addition proportion based on conductivity measurements. This simple parameter-based control approach maintains water purity through straightforward proportional adjustment, avoiding the need for complex multi-variable control systems or additional processing equipment.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If dynamic adjustment of water removal and addition is implemented based on operational parameters, then fuel cell performance is maintained, but control system complexity increases

Engineering Contradiction:
Improvefuel cell performanceVSAvoidcontrol system complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by using operational parameters (current, temperature, humidity) to dynamically adjust water management strategies. The system modifies water addition and removal rates based on real-time operational conditions, maintaining optimal fuel cell performance through simple proportional control rather than complex algorithms.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The water management system serves multiple functions simultaneously: it maintains water purity, manages cooling, and ensures membrane hydration. By using a unified dynamic adjustment mechanism based on operational parameters, the system achieves multiple objectives without requiring separate complex control systems for each function.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach ensures the coolant water remains at optimal purity and conductivity levels, reducing parasitic loads and maintaining fuel cell performance by dynamically adjusting water removal and addition based on operational conditions.

Implementation Method 1

The temperature of the exhaust stream is therefore preferably reduced (e.g. using a heat exchanger) so as to reduce the dew point and condense at least part of the vapour to liquid water.

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 2

Reaction of protons (hydrogen ions) conducted through the PEM from an anode flow path, with oxygen present in a cathode flow path, produces water.

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Data Source

PatentEP2342776B1Fuel cell cooling
Publication Date: 2013.05.08 INTELLIGENT ENERGY LTD
  • EP2342776B1 patent drawingFigure 1
  • EP2342776B1 patent drawing
  • EP2342776B1 patent drawing

AI summary

A method of operating a fuel cell system (100) comprising a fuel cell stack (110) and a closed loop water cooling circuit for direct injection of cooling water into the stack (110), the method comprising: measuring an operational parameter of the fuel cell system (100) over a time period; adding an amount of water to the closed loop cooling circuit from the total amount of water generated during operation of the fuel cell stack (110) over the time period; and removing the amount of water from the closed loop cooling circuit generated during operation of the fuel cell stack (110) over the time period is automatically determined by the fuel cell system (100) as a function of the operational parameter.