Fuel Cell Water Volume Estimation via Total Energy

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Solution Overview

Problem

In solid-state polymer fuel cell systems, it is challenging to accurately estimate the residual water volume after shutdown, which affects the restart performance due to insufficient or excessive water content, leading to issues like gas diffusion hindrance and increased membrane resistance.

Innovation Solution

A fuel cell system that computes total generated electrical energy from startup and uses this value to estimate residual water volume, allowing for a controlled water/air purge process to achieve an optimal wet state, thereby ensuring reliable restart performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If a water/air purge process is performed before shutdown to remove residual water, then gas flow path clogging is prevented, but the electrolyte membrane resistance becomes excessively high due to insufficient water content

Engineering Contradiction:
Improvegas flow path cloggingVSAvoidelectrolyte membrane resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent changes the parameter being monitored from gas pressure differential to total generated electrical energy. By integrating electrical energy generation from startup, the system accurately tracks water content changes in the electrolyte membrane, enabling precise control of the purge process to maintain optimal water content without causing excessive resistance or clogging

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The system implements feedback control by continuously monitoring total generated electrical energy and using this information to control the water/air purge process. The controller adjusts purge duration and intensity based on real-time energy generation data, ensuring residual water content remains within the optimal range to prevent both clogging and excessive resistance

Inventive Principle:
Principle #23Feedback

2Productivity

If the water/air purge process is performed quickly to save time, then productivity is improved, but accurate estimation of residual water volume becomes difficult

Engineering Contradiction:
Improveshutdown process timeVSAvoidresidual water volume estimation
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent replaces traditional mechanical measurement methods (gas pressure differential monitoring) with an electrical measurement approach. By measuring total generated electrical energy, the system can quickly and accurately estimate residual water volume without requiring lengthy purge processes or complex mechanical sensing systems

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The system uses the fuel cell's own electrical energy generation as a self-indicating parameter for water content. The total generated electrical energy from startup naturally reflects the water content state, eliminating the need for separate measurement systems and enabling rapid assessment during shutdown procedures

Inventive Principle:
Principle #25Self-service

3Reliability

If residual water content is reduced to prevent freezing in sub-freezing environments, then reliability in cold conditions is improved, but the fuel cell cannot generate sufficient electrical power during warm-up

Engineering Contradiction:
Improvecold environment operationVSAvoidelectrical power generation during warm-up
Core Design Contradiction:
ReliabilityVSPower

Solution Approach 1:

The patent implements dynamic control of the water/air purge process based on environmental conditions and fuel cell operation state. The controller adjusts purge parameters in real-time, allowing flexible optimization between preventing freezing and maintaining sufficient water content for power generation during different operational phases and environmental conditions

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables accurate estimation of residual water volume, preventing water-related issues during restart, such as freezing and membrane drying, ensuring efficient and reliable fuel cell operation.

Implementation Method 1

an anode catalyst electrode layer and a cathode catalyst electrode layer are respectively arranged on the two surfaces of a solid- state polymer electrolyte membrane having hydrogen ion conductivity

Methodology Applied
Scientific EffectHydrogen ion conductivity: Conduction (electrical)

Implementation Method 2

when a fuel gas containing hydrogen is fed to the anode catalyst electrode layer while air containing oxygen is fed to the cathode catalyst electrode layer, the following electrochemical reactions take place

Methodology Applied
Scientific EffectElectrochemical reaction: Fuel Cell

Data Source

PatentEP2158631B1Fuel cell system and operation method thereof
Publication Date: 2015.12.02 NISSAN MOTOR CO LTD
  • EP2158631B1 patent drawingFigure 1
  • EP2158631B1 patent drawingFigure 2
  • EP2158631B1 patent drawingFigure 3

AI summary

A fuel cell system (1) and a method for controlling the same. The system and method employ a fuel cell stack (2) that generates electrical power by electrochemical reaction of a fuel gas and an oxidant gas, a total generated electrical energy computation device (31) that computes a value pertaining to the total generated electrical energy as the sum of the electrical energy generated by said fuel cell stack from start-up of the fuel cell system, and a residual water volume estimation device (32) that estimates the residual water volume left in the fuel cell stack based on said value pertaining to said total generated electrical energy computed by said total generated electrical energy computation device (31).