Fuel Composition Merging Organometallic Compounds for Octane

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Solution Overview

Problem

There is a need to deliver combustion improvers to fuels in an efficient and cost-effective manner, as existing combustion improvers vary widely in cost, physical properties, handling, safety requirements, quality, and efficacy, and customers seek to reduce their usage while improving engine performance.

Innovation Solution

A method involving combining a secondary organometallic compound with methylcyclopentadienyl manganese tricarbonyl and introducing the mixture into a fuel to enhance octane performance, optimizing the blend by measuring the pre-eutectic transition point temperature to achieve synergistic effects, which includes using blends of organometallic cyclomatic manganese tricarbonyls and other metal compounds at ratios below individual component levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If combustion improvers are used to improve engine performance, then octane number increases, but cost increases

Engineering Contradiction:
Improveengine performanceVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines two different organometallic compounds (methylcyclopentadienyl manganese tricarbonyl and cyclopentadienyl manganese tricarbonyl) into a blended fuel composition. This merging of compounds creates a synergistic effect where the combination provides superior octane enhancement at lower overall concentrations compared to using either compound alone, thereby reducing cost while maintaining performance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite fuel formulation by blending organometallic compounds with hydrocarbon fuels. The composite nature of this fuel composition allows the organometallic compounds to work synergistically, providing enhanced combustion performance and octane number improvement at economically viable concentrations

Inventive Principle:
Principle #40Composite materials

2Reliability

If higher amounts of combustion improvers are used, then octane number increases, but the amount of additive required increases

Engineering Contradiction:
Improveoctane numberVSAvoidamount of additive
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent merges methylcyclopentadienyl manganese tricarbonyl and cyclopentadienyl manganese tricarbonyl in specific blended ratios. This combination produces a synergistic effect where the total amount of organometallic additive required is reduced compared to using higher concentrations of a single compound, achieving the same or better octane number improvement with less total additive

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention optimizes the concentration parameters of the organometallic compounds in the fuel blend. By adjusting the ratios and concentrations of the blended organometallic compounds to specific ranges, the formulation achieves maximum octane enhancement efficiency, providing superior performance at lower overall additive levels

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach results in a significant increase in octane number, up to 50% improvement, and cost reduction by utilizing lower-cost secondary organometallic compounds like cyclopentadienyl manganese tricarbonyl, while maintaining fuel performance and safety, with the pre-eutectic transition point temperature correlating with enhanced octane response.

Implementation Method 1

combining a secondary organometallic compound and methylcyclopentadienyl manganese tricarbonyl... blended at synergistic ratios that optimize octane performance

Methodology Applied
Scientific EffectSynergistic blend:

Implementation Method 2

measuring the pre-eutectic transition point temperature... measuring a pre-eutectic transition point temperature of a synergistic blend

Methodology Applied
Scientific EffectPre-eutectic transition: Phase Change

Data Source

PatentUS8852299B2Fuel composition
Publication Date: 2014.10.07 AFTON CHEMICAL CORPORATION
  • US8852299B2 patent drawing
  • US8852299B2 patent drawing
  • US8852299B2 patent drawing

AI summary

There is disclosed a method for combusting a secondary organometallic compound in an engine including (a) combining a secondary organometallic compound and methylcyclopentadienyl manganese tricarbonyl, (b) introducing the combination from (a) into a fuel, and (c) causing the fuel from (b) to be combusted in the engine.