Fuel Condenser Desulfurization for Fuel Cell Reformer Protection

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Solution Overview

Problem

Fuel cell systems face contamination and performance issues due to sulfur compounds in fuels, which traditional desulfurization methods using absorbents are cumbersome and require frequent maintenance.

Innovation Solution

A fuel desulfurization system that condenses gaseous fuel into a liquid phase using a fuel condenser, allowing for direct delivery to a reformer while returning uncondensed fuel vapor to inert the fuel source, thereby reducing sulfur content without the need for absorbents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If traditional absorbent-based desulfurization methods are used, then sulfur compounds in fuel are removed, but system weight increases and maintenance requirements increase

Engineering Contradiction:
Improvesulfur compound contaminationVSAvoidsystem weight
Core Design Contradiction:
Object-affected harmful factorsVSWeight of moving object

Solution Approach 1:

The patent extracts and removes the absorbent component from the desulfurization system, replacing it with a condensation-based approach. The fuel is condensed to separate sulfur compounds through phase change rather than chemical absorption, eliminating the need for heavy absorbent materials while maintaining desulfurization effectiveness.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent replaces the chemical absorption mechanism with a physical condensation process. By using temperature and pressure control to condense fuel vapors, the system achieves desulfurization through phase transition rather than chemical reaction with absorbents, reducing system weight and maintenance needs.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Object-affected harmful factors

If traditional absorbent-based desulfurization methods are used, then sulfur compounds in fuel are removed, but maintenance requirements increase due to routine absorbent replacement

Engineering Contradiction:
Improvesulfur compound contaminationVSAvoidmaintenance requirements
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The condensation-based desulfurization system operates continuously without requiring manual intervention for absorbent replacement. The system self-regulates through temperature and pressure control, automatically condensing fuel vapors and separating sulfur compounds without needing routine maintenance or absorbent replenishment.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent utilizes phase transition (condensation) as the core mechanism for desulfurization. By controlling the phase change of fuel from vapor to liquid, the system naturally separates sulfur compounds without requiring consumable absorbent materials, eliminating routine maintenance associated with absorbent replacement.

Inventive Principle:
Principle #36Phase transitions

3Device complexity

If gaseous fuel is used directly in the reformer, then system complexity is reduced, but sulfur compounds contaminate the reformer and fuel cell catalysts

Engineering Contradiction:
Improvesystem complexityVSAvoidcatalyst contamination
Core Design Contradiction:
Device complexityVSObject-affected harmful factors

Solution Approach 1:

The patent implements preliminary condensation and desulfurization of the fuel before it enters the reformer. By pre-processing the fuel vapor through condensation to remove sulfur compounds, the system protects the reformer and catalysts from contamination without adding significant complexity to the overall system architecture.

Inventive Principle:
Principle #10Preliminary action

4Object-affected harmful factors

If absorbent-based desulfurization is implemented, then sulfur removal is achieved, but system weight and maintenance burden increase

Engineering Contradiction:
Improvesulfur contentVSAvoidsystem complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent extracts the absorbent component from the system entirely, replacing it with a condensation-based desulfurization approach. This eliminates the need for heavy absorbent materials and their associated handling, storage, and replacement infrastructure, thereby reducing both system weight and overall complexity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent employs phase transition (condensation) as a simpler alternative to chemical absorption. By using temperature and pressure control to condense fuel vapors and separate sulfur compounds, the system achieves desulfurization with fewer components and less complexity compared to absorbent-based systems.

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively reduces sulfur compounds in fuels, enhancing fuel cell performance and reducing maintenance needs by eliminating the requirement for absorbents, thus improving system efficiency and longevity.

Implementation Method 1

a fuel condenser that condenses gaseous fuel to a liquid phase

Methodology Applied
Scientific EffectCondensation: Condensation

Data Source

PatentUS10158138B2Systems and methods for fuel desulfurization
Publication Date: 2018.12.18 HONEYWELL INTERNATIONAL INC
  • US10158138B2 patent drawing
  • US10158138B2 patent drawing
  • US10158138B2 patent drawing

AI summary

A fuel cell system is provided. The fuel cell system includes a source of fuel, and a fuel desulfurization system fluidly coupled to the source of fuel to receive the fuel in a gaseous phase. The fuel desulfurization system includes a fuel condenser that condenses at least a portion of the fuel from the gaseous phase to a liquid phase. The fuel cell system includes a reformer fluidly coupled to the fuel desulfurization system that receives the fuel from the fuel desulfurization system in the liquid phase to generate hydrogen enriched fuel and a fuel cell stack fluidly coupled to the reformer to receive the hydrogen enriched fuel.