Fuel Hose Interlaminar Adhesion via DBU Salt and HCl-Catcher

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing fuel hoses face challenges with interlaminar adhesion between NBR and THV layers, leading to inferior fuel-permeation resistance and ozone resistance, which affects the reliability and performance of the hose.

Innovation Solution

A fuel hose with a laminated structure using a rubber composition containing a blend of acrylonitrile-butadiene rubber and polyvinyl chloride (NBR-PVC) along with 1,8-diazabicyclo[5.4.0]undecene-7 salt, zeolite, magnesium oxide, laminar mineral, and basic silica, which enhances interlaminar adhesion and improves fuel-permeation resistance and ozone resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If NBR is replaced by NBR-PVC to improve fuel-permeation resistance, ozone resistance and sour-gasoline resistance, then material reliability is improved, but interlaminar adhesion between the rubber layer and THV layer deteriorates

Engineering Contradiction:
Improvefuel-permeation resistance, ozone resistance, sour-gasoline resistanceVSAvoidinterlaminar adhesion
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent introduces an intermediate layer between the NBR-PVC rubber layer and the THV resin layer. This intermediate layer acts as a mediator that is chemically compatible with both materials, enabling effective adhesion between the NBR-PVC layer and the THV layer while preserving the excellent fuel-permeation resistance, ozone resistance, and sour-gasoline resistance properties of the NBR-PVC material.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite multi-layer structure consisting of NBR-PVC rubber layer, intermediate layer, and THV resin layer. Each layer is designed with specific material properties to achieve overall performance: the NBR-PVC layer provides fuel resistance, the intermediate layer provides adhesion, and the THV layer provides chemical compatibility, resulting in a composite structure that overcomes the limitations of individual materials.

Inventive Principle:
Principle #40Composite materials

2Strength

If DBU salt is added to NBR-PVC layer to improve interlaminar adhesion, then adhesion is improved, but the improvement is not sufficient compared to adding DBU salt to NBR layer

Engineering Contradiction:
Improveinterlaminar adhesionVSAvoidadhesion effectiveness
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

Instead of relying solely on DBU salt addition to achieve adhesion between NBR-PVC and THV layers, the patent introduces a dedicated intermediate layer that serves as a mediator. This intermediate layer is specifically designed to be chemically compatible with both NBR-PVC and THV, providing reliable adhesion without requiring high concentrations of DBU salt that might compromise other material properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the approach from modifying the NBR-PVC layer composition (adding DBU salt) to introducing a separate intermediate layer with specific compositional parameters. This parameter change allows optimization of adhesion properties independently from the fuel resistance properties of the NBR-PVC layer, achieving both goals simultaneously.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides excellent interlaminar adhesion and improved fuel-permeation resistance, ozone resistance, and sour-gasoline resistance, enhancing the overall reliability and performance of the fuel hose.

Implementation Method 1

Since the DBU salt or the like is a strong dehydrohalogenating agent, elimination of HCl from PVC in the NBR-PVC layer is prioritized

Methodology Applied
Scientific EffectDehydrohalogenation:

Implementation Method 2

an HCl-catcher such as zeolite, magnesium oxide, laminar mineral and basic silica catches chlorine so as to prevent elimination of HCl from PVC

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 3

the DBU salt or the like eliminates HF from 2F in the adjoining specific resin layer

Methodology Applied
Scientific EffectDehydrofluorination:

Implementation Method 4

the remaining part releasing the HF in the resin layer and a double bond of NBR in the NBR-PVC layer are reacted by a vulcanizing agent or the like, so that interlaminar adhesion is improved

Methodology Applied
Scientific EffectVulcanization:

Data Source

PatentUS8092880B2Fuel hose
Publication Date: 2012.01.10 SUMITOMO RIKO CO LTD
  • US8092880B2 patent drawing
  • US8092880B2 patent drawing

AI summary

A fuel hose includes a laminated structure of a tubular resin layer and an adjoining rubber layer, the rubber layer being formed by a rubber composition containing the following (A) to (F) as essential components, and the resin layer being formed by a material containing a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer or a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride-perfluoroalkyl vinyl ether quaterpolymer as a main component:(A) a blend of acrylonitrile-butadiene rubber and polyvinyl chloride;(B) at least one selected from the group consisting of 1,8-diazabicyclo[5.4.0]undecene-7 salt, 1,5-diazabicyclo[4.3.0]nonene-5 salt, 1,8-diazabicyclo[5.4.0]undecene-7 and 1,5-diazabicyclo[4.3.0]nonene-5;(C) zeolite;(D) magnesium oxide;(E) laminar mineral; and(F) basic silica.