Fuel Hose Interlaminar Adhesion via DBU Salt and HCl-Catcher
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Solution Overview
Problem
Existing fuel hoses face challenges with interlaminar adhesion between NBR and THV layers, leading to inferior fuel-permeation resistance and ozone resistance, which affects the reliability and performance of the hose.
Innovation Solution
A fuel hose with a laminated structure using a rubber composition containing a blend of acrylonitrile-butadiene rubber and polyvinyl chloride (NBR-PVC) along with 1,8-diazabicyclo[5.4.0]undecene-7 salt, zeolite, magnesium oxide, laminar mineral, and basic silica, which enhances interlaminar adhesion and improves fuel-permeation resistance and ozone resistance.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Reliability
If NBR is replaced by NBR-PVC to improve fuel-permeation resistance, ozone resistance and sour-gasoline resistance, then material reliability is improved, but interlaminar adhesion between the rubber layer and THV layer deteriorates
Solution Approach 1:
The patent introduces an intermediate layer between the NBR-PVC rubber layer and the THV resin layer. This intermediate layer acts as a mediator that is chemically compatible with both materials, enabling effective adhesion between the NBR-PVC layer and the THV layer while preserving the excellent fuel-permeation resistance, ozone resistance, and sour-gasoline resistance properties of the NBR-PVC material.
Solution Approach 2:
The patent creates a composite multi-layer structure consisting of NBR-PVC rubber layer, intermediate layer, and THV resin layer. Each layer is designed with specific material properties to achieve overall performance: the NBR-PVC layer provides fuel resistance, the intermediate layer provides adhesion, and the THV layer provides chemical compatibility, resulting in a composite structure that overcomes the limitations of individual materials.
2Strength
If DBU salt is added to NBR-PVC layer to improve interlaminar adhesion, then adhesion is improved, but the improvement is not sufficient compared to adding DBU salt to NBR layer
Solution Approach 1:
Instead of relying solely on DBU salt addition to achieve adhesion between NBR-PVC and THV layers, the patent introduces a dedicated intermediate layer that serves as a mediator. This intermediate layer is specifically designed to be chemically compatible with both NBR-PVC and THV, providing reliable adhesion without requiring high concentrations of DBU salt that might compromise other material properties.
Solution Approach 2:
The patent changes the approach from modifying the NBR-PVC layer composition (adding DBU salt) to introducing a separate intermediate layer with specific compositional parameters. This parameter change allows optimization of adhesion properties independently from the fuel resistance properties of the NBR-PVC layer, achieving both goals simultaneously.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The solution provides excellent interlaminar adhesion and improved fuel-permeation resistance, ozone resistance, and sour-gasoline resistance, enhancing the overall reliability and performance of the fuel hose.
Implementation Method 1
Since the DBU salt or the like is a strong dehydrohalogenating agent, elimination of HCl from PVC in the NBR-PVC layer is prioritized
Implementation Method 2
an HCl-catcher such as zeolite, magnesium oxide, laminar mineral and basic silica catches chlorine so as to prevent elimination of HCl from PVC
Implementation Method 3
the DBU salt or the like eliminates HF from 2F in the adjoining specific resin layer
Implementation Method 4
the remaining part releasing the HF in the resin layer and a double bond of NBR in the NBR-PVC layer are reacted by a vulcanizing agent or the like, so that interlaminar adhesion is improved
Data Source
AI summary
A fuel hose includes a laminated structure of a tubular resin layer and an adjoining rubber layer, the rubber layer being formed by a rubber composition containing the following (A) to (F) as essential components, and the resin layer being formed by a material containing a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride terpolymer or a tetrafluoroethylene-hexafluoropropylene-vinylidene fluoride-perfluoroalkyl vinyl ether quaterpolymer as a main component:(A) a blend of acrylonitrile-butadiene rubber and polyvinyl chloride;(B) at least one selected from the group consisting of 1,8-diazabicyclo[5.4.0]undecene-7 salt, 1,5-diazabicyclo[4.3.0]nonene-5 salt, 1,8-diazabicyclo[5.4.0]undecene-7 and 1,5-diazabicyclo[4.3.0]nonene-5;(C) zeolite;(D) magnesium oxide;(E) laminar mineral; and(F) basic silica.

