Fuel Oil Conversion via Segmented Hydrocracking
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Solution Overview
Problem
Refineries face challenges in fully converting residuum into high-value products due to limitations in existing thermal cracking technologies, resulting in the production of low-value fuel oils, which are often used as marine or industrial fuels, and the high capital costs associated with new conversion facilities.
Innovation Solution
A system and method for processing fuel oil that includes a series of units such as flash columns, hydrocracking units, solvent de-asphalting units, and hydrotreating units to separate and convert fuel oil into higher-value products like transportation fuels, petrochemical feedstocks, and ultra-low sulfur diesel, with the ability to process 100% thermally cracked residue and contaminants like sulfur, nitrogen, and ash, achieving a conversion rate of 80% or greater.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If thermal cracking technology is used to process residuum, then the viscosity of straight run residual is improved and economic value of product yields is improved, but the fuel oil is limited to low-value uses such as marine bunker fuel and power plant fuel
Solution Approach 1:
The process segments the fuel oil production into multiple stages: initial thermal cracking to improve viscosity, followed by fractionation to separate different hydrocarbon ranges, and selective hydrocracking of specific fractions (vacuum gas oil, atmospheric gas oil) to produce high-value distillates. This segmentation allows different portions of the feedstock to be treated differently, enabling both viscosity improvement and high-value product production.
Solution Approach 2:
The process changes operating parameters selectively across different units. The hydrocracking units operate at specific temperatures (350-450°C), pressures (500-2000 psi), and catalyst-to-oil ratios to optimize conversion to high-value products. By controlling these parameters differently in different process sections, the system achieves both viscosity improvement and expansion into high-value fuel markets.
2Productivity
If new conversion facilities are built to process fuel oil, then conversion capability is improved, but capital costs increase significantly
Solution Approach 1:
The hydrocracking units are designed to process multiple feedstock types (vacuum gas oil, atmospheric gas oil, and their blends) and produce multiple product types (diesel, jet fuel, gasoline blending components). This multi-functionality increases conversion capability without requiring separate dedicated facilities for each feedstock-product combination, thereby reducing overall capital requirements.
Solution Approach 2:
The process applies partial conversion strategies where only specific fractions of the feedstock undergo intensive hydrocracking, while other fractions are processed differently or blended. This selective approach achieves sufficient conversion capability for high-value product production without the excessive capital investment required for complete conversion of all feedstock streams.
3Productivity
If hydrocracking is used to convert fuel oil into high-value products, then conversion rate increases to 80% or greater, but the process complexity and operating conditions become more stringent
Solution Approach 1:
Catalysts serve as intermediaries in the hydrocracking process, enabling high conversion rates (80% or greater) under controlled conditions. The catalysts facilitate the breaking of carbon-carbon bonds and hydrogenation of hydrocarbon molecules, achieving high productivity while managing process complexity through catalytic mediation rather than extreme thermal conditions alone.
Solution Approach 2:
The hydrocracking process operates continuously with steady-state conditions maintained in the reactors. Feedstock is continuously fed, converted, and products are continuously removed, maintaining high conversion rates without interruption. This continuous operation optimizes productivity while managing process complexity through stable, repeatable operating conditions.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The system effectively converts low-value cracked fuel oil into high-value products, expanding processing scales, reducing operating costs, and improving economic value by producing transportation fuels, petrochemical feedstocks, and ultra-low sulfur diesel, while allowing for industrial-scale processing and integration with existing facilities.
Implementation Method 1
a flash column configured to receive the stream as feedstock and separate the stream into a flash distillate stream and a flash residue stream
Implementation Method 2
a vacuum column configured to receive the flash residue stream and separate the flash residue stream into a vacuum distillate stream, a vacuum gas oil stream, and a vacuum residue stream
Implementation Method 3
a first hydrocracking unit configured to receive and process at least a portion of the vacuum residue stream
Implementation Method 4
hydrotreating units to separate and convert fuel oil into higher-value products like transportation fuels, petrochemical feedstocks, and ultra-low sulfur diesel
Data Source
AI summary
A system for processing a stream including fuel oil includes an atmospheric flash column for receiving the stream as feedstock and separate the stream into an atmospheric flash distillate stream and an atmospheric flash residue stream. The system includes a vacuum flash column for receiving the atmospheric flash residue stream and separating the atmospheric flash residue stream into a vacuum flash distillate stream, a vacuum flash residue stream, and a vacuum gas oil stream. The system includes a first hydrocracking unit for receiving and processing at least a portion of the vacuum flash residue stream to produce an intermediate stream and a slurry. The system includes a second hydrocracking unit for receiving and processing the vacuum gas oil stream and the intermediate stream to produce a naphtha product and a light ends product. The system includes a pelletization unit for receiving and processing the slurry to produce a pelletized product.


