Ferritic Stainless Steel Fuel Pipe Crevice Coating

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Solution Overview

Problem

Fuel pipes made from lower-grade materials than SUS436L face challenges in achieving sufficient corrosion resistance, particularly in crevice structures exposed to salt spray environments, as existing coating methods are either costly or ineffective in covering internal crevice areas.

Innovation Solution

The use of cationic electrodeposition coating with a crevice opening amount of 0.2 mm or more, ensuring a coating film forms inside crevices, combined with a ferritic stainless steel composition that balances cost and corrosion resistance, and employing projections on metal fittings to enhance coating penetration and coverage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If lower-grade material (Mo-free AISI439 steel) is used to reduce material costs, then material cost is reduced, but corrosion resistance deteriorates

Engineering Contradiction:
Improvematerial costVSAvoidcorrosion resistance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent uses a composite structure combining Mo-free AISI439 steel (lower-grade material) with a cationic electrodeposition coating layer. This composite approach allows the base material to provide structural integrity while the coating layer provides the corrosion resistance that would otherwise require expensive alloying elements like Mo, thus resolving the contradiction between material cost and corrosion resistance

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical composition parameters of the steel by eliminating Mo while adjusting Cr content (13-18%) and adding specific elements (Ti: 0.03-0.30%, Nb: 0.03-0.30%). This parameter optimization allows the lower-grade material to achieve sufficient corrosion resistance when combined with the electrodeposition coating, enabling cost reduction without sacrificing reliability

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conventional coating methods are used to improve corrosion resistance, then corrosion proofing is improved, but coating cost increases

Engineering Contradiction:
Improvecorrosion proofingVSAvoidcoating cost
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent replaces conventional mechanical coating methods (such as spray coating or dip coating) with cationic electrodeposition, which uses electrochemical principles to deposit the coating. This substitution enables the coating to be drawn into crevice structures by electrochemical attraction, providing superior corrosion protection at lower cost compared to conventional coating methods that cannot effectively coat internal crevice surfaces

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If crevice opening amount is increased to allow coating penetration, then coating coverage is improved, but structural integrity may be compromised

Engineering Contradiction:
Improvecoating coverageVSAvoidstructural integrity
Core Design Contradiction:
Manufacturing precisionVSStrength

Solution Approach 1:

The patent optimizes the crevice opening amount to a specific parameter range (0.05-0.50 mm) that allows sufficient electrodeposition coating penetration while maintaining structural integrity. This precise parameter control enables the coating to reach internal crevice surfaces for complete corrosion protection without compromising the strength or structural function of the fuel pipe assembly

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach stabilizes salt spray corrosion resistance while providing an inexpensive fuel pipe solution, with improved corrosion protection even with lower-grade materials, as demonstrated by cyclic corrosion tests.

Implementation Method 1

coating by cationic electrodeposition

Methodology Applied
Scientific EffectElectrodeposition: Electrodeposition

Implementation Method 2

coating by cationic electrodeposition

Methodology Applied
Scientific EffectElectrostatic deposition: Electrostatic Deposition

Implementation Method 3

placing sacrificial positive electrodes of zinc at the locations where passivation films are damaged and making use of sacrificial corrosion

Methodology Applied
Scientific EffectSacrificial corrosion: Galvanometer

Data Source

PatentUS9249901B2Fuel pipe and method of production of same
Publication Date: 2016.02.02 NIPPON STEEL & SUMIKIN STAINLESS STEEL CORP
  • US9249901B2 patent drawing
  • US9249901B2 patent drawing
  • US9249901B2 patent drawing

AI summary

A fuel pipe which is inexpensive and is excellent in salt spray corrosion resistance, characterized by being comprised of a steel pipe member having as a material a ferritic stainless steel which contains, by mass %, C: 0.015% or less, Si: 0.01 to 0.50%, Mn: 0.01 to 0.50%, P: 0.050% or less, S: 0.010% or less, N: 0.015% or less, Al: 0.010 to 0.100%, and Cr: 13.0 to 18.0% and further, one or both of Ti: 0.03 to 0.30% and Nb: 0.03 to 0.30% and a metal fitting part, the metal fitting part and the steel pipe member having between them a crevice structure at the surface which the structure is exposed to a salt spray environment, an opening amount at a crevice part of the crevice structure being 0.2 mm or more, and an inside of the crevice part being coated by electrodeposition.