Fuel-Soluble Synergistic Cleaning Mixture for High-Pressure Injectors

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Solution Overview

Problem

Conventional fuel additives are ineffective in reducing fuel injector deposits in gasoline engines operating at high fuel pressures, particularly in newer engine technology that operates at pressures 15 to 100 times higher than traditional engines, leading to performance issues and fouling of injectors.

Innovation Solution

A synergistic combination of a quaternary ammonium internal salt and a hydrocarbyl substituted dicarboxylic anhydride derivative is injected into the engine as a fuel-soluble cleaning mixture, effective at high pressures (500 to 7,500 psi), providing a significant clean-up performance by reducing existing deposits and maintaining injector cleanliness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stress or pressure

If conventional fuel additives are used in high-pressure gasoline engines, then the engine can operate at high fuel pressures, but the fuel injector deposits are not effectively reduced

Engineering Contradiction:
Improvefuel pressureVSAvoidinjector cleanliness
Core Design Contradiction:
Stress or pressureVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the fuel additive by using a synergistic combination of a quaternary ammonium internal salt (Formula I) and a hydrocarbyl substituted dicarboxylic anhydride derivative (Formula II) with specific molecular structures and ratios (1:4 to 4:1), which enables effective deposit reduction at high fuel pressures where conventional additives fail

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies composite material principle by combining two different chemical compounds with complementary functions - the quaternary ammonium internal salt provides cationic character for interacting with deposits, while the dicarboxylic anhydride derivative provides anhydride groups for chemical reaction, creating a synergistic effect that achieves 30-100% clean-up performance

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If conventional detergents like hydrocarbyl substituted succinimides are used, then they can control deposit formation at low pressures, but they do not provide effective clean-up performance at high fuel pressures

Engineering Contradiction:
Improveadditive concentrationVSAvoidclean-up performance
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters from conventional succinimides to a novel combination of quaternary ammonium internal salt and dicarboxylic anhydride derivative, which fundamentally alters the mechanism of action to enable effective clean-up at high pressures while maintaining low treat rates

Inventive Principle:
Principle #35Parameter changes

3Power

If high fuel pressures (500-7500 psi) are used in newer engine technology, then engine performance is improved, but injector fouling and performance degradation occur

Engineering Contradiction:
Improveengine performanceVSAvoidinjector fouling
Core Design Contradiction:
PowerVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary anti-action by incorporating the synergistic cleaning mixture into the fuel before injection, which proactively prevents deposit formation and actively cleans existing deposits on injector surfaces before they can cause performance degradation, allowing the engine to maintain optimal performance at high pressures

Inventive Principle:
Principle #9Preliminary anti-action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The synergistic cleaning mixture achieves 30 to 100% clean-up of fuel injector deposits, as measured by long-term fuel trim, injector pulse width, and injection duration, at low treat rates, effectively addressing the limitations of conventional additives in high-pressure engines.

Implementation Method 1

combusting the fuel composition in the gasoline engine

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentEP3597726B1Fuel-soluble synergistic cleaning mixture for high pressure gasoline engines
Publication Date: 2021.03.10 AFTON CHEMICAL CORPORATION
  • EP3597726B1 patent drawingFigure 1
  • EP3597726B1 patent drawing
  • EP3597726B1 patent drawing

AI summary

The present disclosure relates to methods and fuel compositions for reducing fuel injector deposits in gasoline engines operated at high fuel pressures. The fuel compositions include hydrocarbons boiling in the gasoline range and a synergistic fuel injector cleaning mixture.