Fullerene Thermal Spraying for Low-Temperature Carburization

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Solution Overview

Problem

Current methods for carburizing iron-based metal materials require high temperatures, leading to coarse crystal grains and reduced mechanical strength, and often necessitate expensive equipment, while forming thick fullerene films is challenging without expensive apparatus.

Innovation Solution

A thermal spraying method using fullerene granules as a carbon source, allowing carburization at lower temperatures to inhibit crystal grain growth and forming a smooth amorphous carbon film without the need for expensive equipment, by reacting fullerenes to form an amorphous carbon layer with excellent adhesiveness.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If solid carburization process using wood charcoal or graphite is used, then carbon source is simple and equipment cost is low, but high temperature (900°C or more) and long heating time are required causing coarse crystal grains and reduced mechanical strength

Engineering Contradiction:
Improveequipment costVSAvoidmechanical strength
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The invention changes the chemical reactivity parameter of the carbon source from low (graphite) to high (fullerene), enabling carburization at lower temperatures (below 900°C) while maintaining effective carbon diffusion into the metal substrate, thus preserving mechanical strength

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses fullerene granules as a consumable carbon source that can be applied directly to the metal surface and heated briefly to achieve carburization, replacing the need for expensive vacuum deposition equipment while maintaining film quality

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Productivity

If gas carburization process is used, then mass production is suitable, but expensive apparatus is necessary

Engineering Contradiction:
Improvemass production capabilityVSAvoidapparatus cost
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The invention replaces expensive gas carburization apparatus with simple thermal spraying equipment by using fullerene granules as a disposable carbon source that can be sprayed onto metal surfaces, achieving mass production capability with significantly reduced equipment investment

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention substitutes the complex gas delivery and control systems of gas carburization with a simpler thermal spraying mechanism that deposits fullerene granules onto the metal surface, where subsequent heating activates the carbon diffusion process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Manufacturing precision

If vacuum deposition device is used to form fullerene film, then carbon film can be formed, but expensive apparatus is necessary and thick film formation is very difficult

Engineering Contradiction:
Improvefilm qualityVSAvoidapparatus cost
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention replaces expensive vacuum deposition apparatus with simple thermal spraying equipment by using fullerene granules as a consumable material that can be deposited in thick layers through repeated spraying passes, achieving both cost reduction and improved film thickness capability

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention applies fullerene granules locally to the metal surface through thermal spraying, allowing controlled deposition of carbon material where needed, and enables thick film formation by multiple passes while maintaining film quality through the high reactivity of fullerene

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method achieves improved mechanical strength and surface protection of iron-based metal materials by inhibiting crystal grain growth and forming a high-quality, cost-effective amorphous carbon film that acts as a surface protective layer.

Implementation Method 1

granules of fullerenes are thermally sprayed on a surface of a material

Methodology Applied
Scientific EffectThermal heating: Heating

Implementation Method 2

since the fullerene has, other than six-membered rings, five-membered rings high in the reactivity in a molecule, fullerenes, when heated, react with each other to form amorphous carbon

Methodology Applied
Scientific EffectChemical reaction: Chemical Bonding

Data Source

PatentEP1892312B1Method of producing a carbon film
Publication Date: 2019.01.09 TOYOTA JIDOSHA KK
  • EP1892312B1 patent drawingFigure 1
  • EP1892312B1 patent drawingFigure 2
  • EP1892312B1 patent drawingFigure 3

AI summary

A metal material that is, without using expensive apparatus, carburized in a low temperature region where crystal grains do not grow so much, and a producing method of the metal material are provided. A metal material mainly containing iron, wherein a surface of the metal material is subjected to a carburization treatment by a treatment using fullerenes as a carbon source.