Fumed Silica Functional Composition for Uniform Blackout Coatings

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Solution Overview

Problem

Existing light-blocking materials, such as blackout curtains and shades, face challenges in achieving a lightweight, flexible, and uniformly white appearance while maintaining light-absorptive properties, and there is a risk of dark opacifying agents escaping during handling and sewing, leading to undesirable shading and soiling.

Innovation Solution

A functional composition formulation incorporating fumed silica, water-soluble organic polymeric binders, and specific additives is applied to a dry opacifying layer, providing a uniform, white appearance and improved durability, with a method involving application, drying, and densification of a foamed aqueous composition on a substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If thick foam coatings with light scattering pigments are used to create light-colored blackout curtains, then light blocking performance is improved, but weight increases

Engineering Contradiction:
Improvelight blocking performanceVSAvoidweight
Core Design Contradiction:
Object-affected harmful factorsVSWeight of moving object

Solution Approach 1:

The patent uses a composite structure with a foam substrate containing carbon black particles for light absorption, overlaid with a functional composition containing fumed silica and titanium dioxide for light scattering and white appearance. This composite approach achieves light blocking without requiring excessively thick coatings of purely light-scattering materials, thereby reducing weight while maintaining performance.

Inventive Principle:
Principle #40Composite materials

2Weight of moving object

If carbon black layer is used to reduce weight of blackout materials, then weight is reduced, but risk of carbon black escaping during handling and sewing increases

Engineering Contradiction:
ImproveweightVSAvoidcarbon black escape and soiling
Core Design Contradiction:
Weight of moving objectVSObject-generated harmful factors

Solution Approach 1:

The patent introduces a functional composition layer as an intermediary between the carbon black-containing foam substrate and the external environment. This layer contains fumed silica and titanium dioxide that provide a protective matrix, preventing carbon black particles from escaping during handling and sewing while maintaining the weight reduction benefits of the foam structure.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent transforms the appearance from dark (carbon black exposed) to white/light-colored by applying a functional composition containing white pigments (titanium dioxide) and fumed silica. This color transformation not only improves aesthetics but also creates a protective barrier that prevents carbon black escape, solving both the weight reduction and contamination problems simultaneously.

Inventive Principle:
Principle #32Color changes

3Object-affected harmful factors

If multiple coating operations are used to create light-colored blackout curtains with light scattering pigments, then light blocking performance is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvelight blocking performanceVSAvoidmanufacturing complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The patent combines multiple functions into a single integrated foam substrate: the foam structure provides lightweighting and insulation, carbon black particles provide light absorption and blackout performance, and the porous structure allows for subsequent impregnation with functional composition. This merging of functions into one substrate reduces manufacturing complexity compared to applying multiple separate coating layers.

Inventive Principle:
Principle #5Merging (Combining)

4Manufacturing precision

If fumed silica is incorporated into functional composition, then uniform white appearance and durability are improved, but formulation complexity increases

Engineering Contradiction:
Improveuniformity of appearanceVSAvoidformulation complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent utilizes the unique properties of fumed silica (pyrogenic silica) with specific surface area and particle size parameters to achieve uniform dispersion and white appearance. By carefully selecting and controlling these physical parameters of the fumed silica, the formulation achieves superior uniformity and durability despite the increased complexity of the multi-component system.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a uniformly white and mottle-free appearance with enhanced durability and reduced risk of opacifying agents escaping, maintaining light-blocking properties and flexibility.

Implementation Method 1

the use of fumed silica provides a desired uniform, white, and mottle free appearance

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

Aqueous functional compositions that can be incorporated into foamed, opacifying elements

Methodology Applied
Scientific EffectAdhesion: Adhesive

Data Source

PatentUS11370924B2Aqueous functional composition for articles
Publication Date: 2022.06.28 EASTMAN KODAK CO

AI summary

An aqueous functional composition formulation is used to provide a top layer or pattern in light-blocking opacifying elements. This functional composition formulation has 0.5-15% solids and the essential (i) and (iv) components and any optional (ii), (v), (vi), and (vii) components. The essential components are (i) fumed silica particles at 0.5-10 weight %; and a (iv) water-soluble or water-dispersible organic polymeric binder having a glass transition temperature (Tg) below 25° C. The weight ratio of the (i) fumed silica particles to the (iv) water-soluble or water-dispersible organic polymeric binder is 10:1 to 1:5. The optional components include: a (ii) solid or non-solid lubricant; a (v) crosslinking agent; a (vi) thickener; and a (vii) coating aid. Glass particles can also be present. The presence of the (i) fumed silica provides improved brightness, e.g. an L* value of at least 80, and uniform coatings in the opacifying element.