Functional Material Granulation for Low-Dust OLED Processing

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Solution Overview

Problem

Existing powders and pellets used in manufacturing electronic devices, such as organic light-emitting diodes (OLEDs), suffer from dust generation, electrostatic charging, low bulk density, complexity in production, and high cost, which affect processability, transportability, and storability, while also requiring stringent safety measures.

Innovation Solution

A method to produce granules from a functional material melt by transferring it under controlled pressure and cooling, resulting in granules with a low fine fraction and improved properties for use in electronic devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If powders are used as functional material, then the material can be easily processed, but dust is generated and electrostatic charging occurs leading to residue and safety issues

Engineering Contradiction:
ImproveprocessabilityVSAvoiddust generation and electrostatic charging
Core Design Contradiction:
Ease of manufactureVSObject-generated harmful factors

Solution Approach 1:

The patent changes the physical form parameter of the functional material from powder to granules with controlled size distribution (0.1-1.0 mm). This parameter change eliminates dust generation while maintaining processability, as the granular form does not generate harmful dust or electrostatic charging during handling.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality by creating granules with a specific size distribution where the majority of particles fall within the 0.1-1.0 mm range. This localized control of particle size ensures that the material has optimal properties for both handling and device performance, eliminating the harmful effects of fine powder while maintaining manufacturability.

Inventive Principle:
Principle #3Local quality

2Object-generated harmful factors

If pellets are used as functional material, then dust generation is reduced, but production becomes complex and expensive

Engineering Contradiction:
Improvedust contentVSAvoidproduction complexity
Core Design Contradiction:
Object-generated harmful factorsVSDevice complexity

Solution Approach 1:

The patent segments the functional material into granules of controlled size (0.1-1.0 mm) rather than using fully densified pellets. This segmentation approach reduces dust generation compared to powder while avoiding the complex multi-step production process required for traditional pellets, achieving a balance between harmful factor reduction and manufacturing simplicity.

Inventive Principle:
Principle #1Segmentation

3Ease of manufacture

If fine fraction is increased in granules, then processability improves, but device performance and lifetime are adversely affected

Engineering Contradiction:
ImproveprocessabilityVSAvoiddevice lifetime and efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent optimizes the particle size distribution parameter by limiting the fine fraction (particles <0.1 mm) to less than 10 wt.%. This parameter optimization ensures sufficient processability while preventing the adverse effects on device performance and lifetime that would result from excessive fine particles.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies local quality control by specifying that at least 90 wt.% of granules should have a diameter of 0.1-1.0 mm. This localized quality control ensures that the majority of the material has optimal properties for both processing and device performance, while allowing a small controlled amount of finer particles for manufacturability.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The granules enhance processability, transportability, and storability, with improved device performance, particularly in OLEDs, by reducing dust and electrostatic issues, and maintaining consistent quality and efficiency.

Implementation Method 1

the melt transferred into the drop tube according to step B) is cooled with an inert gas in step C)

Methodology Applied
Scientific EffectCooling: Cooling

Implementation Method 2

the pressure at which the melt is transferred into a drop tube according to step B) is higher than the pressure in the drop tube

Methodology Applied
Scientific EffectPressure gradient: Pressure Gradient

Data Source

PatentEP3857621B1Method for the production of a granular material
Publication Date: 2025.10.29 MERCK PATENT GMBH
  • EP3857621B1 patent drawingFigure 1~2
  • EP3857621B1 patent drawing
  • EP3857621B1 patent drawing

AI summary

The present invention describes a method for producing granular material, containing at least one functional material (FM), which can be used to produce functional layers of electronic devices. The invention also relates to a granular material obtainable according to the present method, and to the use of said granular material for the production of an electronic device.