Functionalized Attapulgite Adsorbent for Cost-Efficient PFAS Removal

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Solution Overview

Problem

Existing technologies for removing PFAS from liquids, such as activated carbon, anion exchange resin, and high-pressure membranes, are inefficient or expensive, and there is a need for a more effective and cost-efficient adsorbent.

Innovation Solution

Surface-functionalized attapulgite with quaternary amine and mercapto groups, which includes a mono-quaternary or di-quaternary amine compound and mercapto silane, is used to adsorb PFAS, achieving high removal efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If activated carbon is used for PFAS removal, then the cost is low, but the removal efficiency is poor

Engineering Contradiction:
ImprovePFAS removal efficiencyVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent uses composite materials by combining attapulgite (a clay mineral) with quaternary amine functional groups and mercapto groups to create a hybrid adsorbent that leverages the structural benefits of natural clay with the enhanced chemical affinity of synthesized functional groups, achieving superior PFAS removal compared to single-material solutions

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the surface chemical parameters of attapulgite by introducing quaternary amine and mercapto functional groups through chemical treatment, transforming the physical adsorption mechanism into a chemically-enhanced adsorption process that significantly improves PFAS removal efficiency while maintaining cost-effectiveness

Inventive Principle:
Principle #35Parameter changes

2Reliability

If anion exchange resin is used for PFAS removal, then the removal efficiency is high, but the material cost and equipment cost are expensive

Engineering Contradiction:
ImprovePFAS removal efficiencyVSAvoidmaterial cost and equipment cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs a low-cost attapulgite-based adsorbent that can be easily manufactured and potentially disposed of or regenerated after use, replacing expensive anion exchange resins with a more economical material solution that achieves comparable or superior performance without requiring costly equipment infrastructure

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the chemical surface parameters of attapulgite by functionalizing it with quaternary amine and mercapto groups, transforming it from a simple clay mineral into a high-performance adsorbent that can compete with expensive specialized resins while maintaining low material and equipment costs

Inventive Principle:
Principle #35Parameter changes

3Reliability

If high-pressure membranes are used for PFAS removal, then the removal efficiency is high, but the equipment cost is expensive

Engineering Contradiction:
ImprovePFAS removal efficiencyVSAvoidequipment cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces the mechanical high-pressure membrane separation system with a chemical adsorption system based on functionalized attapulgite, substituting complex mechanical infrastructure with a simpler chemical process that achieves high PFAS removal efficiency without requiring expensive high-pressure equipment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent modifies the surface chemical properties of attapulgite through functional group introduction, creating an adsorbent with high affinity for PFAS that enables efficient removal through simple contact processes, eliminating the need for complex high-pressure membrane systems

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The attapulgite-based adsorbent achieves PFAS removal efficiencies of 70-100% in 12-25 hours, significantly outperforming existing technologies in efficiency and cost.

Implementation Method 1

a quaternary amine surface coating solution that includes a mono-quaternary amine compound or a di-quaternary amine compound, the mono-quaternary amine compound comprising one or more mono-quaternary amines that attach to the attapulgite surface

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

a surface coating agent that includes one or more mercapto groups that chemically bond to the attapulgite surface

Methodology Applied
Scientific EffectChemical Bonding: Chemical Bonding

Data Source

PatentUS12350644B2Product for PFAS adsorption
Publication Date: 2025.07.08 ACTIVE MINERALS INT LLC
  • US12350644B2 patent drawing
  • US12350644B2 patent drawing
  • US12350644B2 patent drawing

AI summary

A product for adsorbing one or more PFAS from a liquid is disclosed. The product may comprise attapulgite that has been surface functionalized with (a) a quaternary amine surface coating solution that comprises a mono-quaternary amine compound or a di-quaternary amine compound and (b) a mercapto surface coating solution that comprises a surface coating agent that includes one or more mercapto groups that chemically bond to the attapulgite surface. When the quaternary amine surface coating solution includes the mono-quaternary amine compound, the product is free of di-quaternary amines. When the quaternary amine surface coating solution includes the di-quaternary amine compound, the product is free of mono-quaternary amines. Also disclosed is a method of producing the product and a method of adsorbing a PFAS in a liquid using the product.