Functionalized Surfaces for CO2 Conversion

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Solution Overview

Problem

The increasing levels of carbon-containing compounds like carbon monoxide (CO) and carbon dioxide (CO2) in the atmosphere contribute to global warming, necessitating efficient methods for producing fuels and chemicals from non-petroleum sources that minimize carbon footprint.

Innovation Solution

A system comprising an electrochemical reduction system with a separation unit, including an anode, cathode, and a membrane with pores, utilizing carbon nanotubes or graphene, and a catalyst like metal nanoparticles to convert CO or CO2 into C1+ products such as methanol, ethanol, or butanol, powered by renewable energy sources.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If conventional methods are used to produce fuels and chemicals from petroleum sources, then production efficiency is maintained, but carbon footprint increases

Engineering Contradiction:
Improvecarbon footprintVSAvoidproduction efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The invention changes the carbon source parameter from petroleum-based to atmospheric CO2-based, transforming the chemical feedstock while maintaining production capability. This parameter change enables carbon-neutral or negative production by utilizing abundant atmospheric CO2 as a renewable carbon source for synthesizing fuels and chemicals

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention converts the harmful factor (atmospheric CO2 causing global warming) into a beneficial resource (carbon feedstock for fuel and chemical production). By capturing and utilizing CO2 through electrochemical reduction, the system transforms a waste product into valuable commodities, simultaneously addressing climate change and production needs

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Object-affected harmful factors

If electrochemical reduction systems are implemented to convert CO2 into chemical products, then carbon footprint is reduced, but energy input requirements increase

Engineering Contradiction:
Improvecarbon footprintVSAvoidenergy input
Core Design Contradiction:
Object-affected harmful factorsVSUse of energy by moving object

Solution Approach 1:

The invention changes the energy source parameter from conventional fossil-fuel-based power to renewable energy sources (solar, wind, hydroelectric). This parameter substitution enables the electrochemical reduction process to operate with zero or negative carbon emissions, as the electricity required for CO2 reduction comes from clean, renewable sources rather than carbon-intensive sources

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention integrates multiple functions into a unified system: CO2 capture, electrochemical reduction, product synthesis, and renewable energy utilization all occur within an integrated platform. This multi-functionality reduces overall system complexity and enables synergistic optimization where the same infrastructure serves multiple purposes, thereby reducing total energy input requirements

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Manufacturing precision

If membrane separation units with small pores are used to direct C1+ products, then product selectivity increases, but manufacturing complexity increases

Engineering Contradiction:
Improveproduct selectivityVSAvoidmembrane structure complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The invention employs porous membranes with specifically engineered pore sizes (ranging from micrometers to nanometers) that enable selective passage of C1+ products based on molecular size and shape. These porous structures provide high selectivity through physical sieving effects while maintaining relatively simple membrane geometries that can be manufactured using established techniques

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The invention uses carbon nanotubes and graphene-based materials that replicate natural hierarchical structures observed in biological systems. These copied natural structures achieve complex separation functions through self-assembly and intrinsic material properties, reducing the need for additional processing steps and simplifying overall device architecture

Inventive Principle:
Principle #26Copying

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively reduces the carbon footprint by converting atmospheric CO2 into valuable chemical products with high single-pass selectivity, potentially creating net carbon sinks and decreasing energy input by up to 50% in chemical production processes.

Implementation Method 1

the plurality of pores are configured to direct the C1+ product from the first compartment to the second compartment

Methodology Applied
Scientific EffectPore transport: Permeation

Implementation Method 2

the cathode and the anode are configured to reduce the carbon-containing material to the C1+ product in the first compartment while a voltage is applied between the cathode and the anode

Methodology Applied
Scientific EffectElectrochemical reduction: Electrolysis

Implementation Method 3

the cathode further comprises a catalyst. In some embodiments, the catalyst comprises a metal nanoparticle

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 4

the gas contactor is configured to bring the carbon-containing material in contact with water to yield a solution comprising the carbon-containing material

Methodology Applied
Scientific EffectGas absorption: Absorption (physical)

Data Source

PatentUS20240218530A1Functionalized Surfaces for Conversion of Carbon Dioxide
Publication Date: 2024.07.04 PROMETHEUS FUELS INC
  • US20240218530A1 patent drawing
  • US20240218530A1 patent drawing
  • US20240218530A1 patent drawing

AI summary

The present disclosure provides systems and methods for functionalizing surfaces for the conversion of carbon dioxide, including a method comprising: (a) providing a substrate, wherein said substrate comprises one or more pores or a pore-like structure; (b) electrodepositing one or more metal nanoparticles on said one or more pores or said pore-like structure; and (c) attaching, bonding, or depositing a catalyst on said one or more pores or said pore-like structure, wherein said catalyst comprises nitrogen-doped carbon or one or mo're copper nanoparticles.