Functionalized Toner Compositions for Uniform Charge

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Solution Overview

Problem

Existing toner production methods face challenges with long-term stability and reliability due to nonuniform charge distribution and sensitivity to relative humidity, particularly in triboelectrically charged toner systems, which affects print quality and equipment performance.

Innovation Solution

The development of toner compositions with a core-shell configuration, where the latex is functionalized with an alkaline earth resin, such as calcium resinate, to enhance triboelectric robustness and reduce humidity sensitivity, resulting in uniform charge retention and improved manufacturing efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If triboelectric charging is used to charge toner particles, then charge can be obtained for image development, but nonuniform charge distribution occurs leading to high electrostatic adhesion and poor long-term stability

Engineering Contradiction:
Improvelong-term stabilityVSAvoidcharge distribution uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the charging mechanism from triboelectric to electrophoretic charging. By applying an electric field during development, uniform negative charges are induced on the toner particle surfaces, eliminating the nonuniform charge distribution inherent in triboelectric systems. This parameter change from contact-based charging to field-based charging resolves the contradiction between reliability and charge uniformity.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the mechanical triboelectric charging process with an electrical field-based electrophoretic charging process. Instead of relying on mechanical contact and friction between toner and carrier or blade, an electric field is applied to induce uniform charges on toner particles suspended in developer fluid, thereby achieving both reliability and uniform charge distribution.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If small toner particles (about 5 micron diameter) are used to achieve offset print quality, then print quality improves, but electrostatic adhesion forces increase making particles difficult to control

Engineering Contradiction:
Improveprint qualityVSAvoidelectrostatic adhesion force
Core Design Contradiction:
Manufacturing precisionVSForce

Solution Approach 1:

The patent changes the charging parameter from triboelectric charge (which creates localized high-density charge patches) to electrophoretic charge (which distributes charge uniformly across the particle surface). This parameter change reduces electrostatic adhesion forces on small particles while maintaining the ability to achieve offset print quality through controlled electrophoretic development.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If conventional emulsion aggregation methods are used to prepare toner, then toner particles can be formed, but production time is long and unit manufacturing costs are high

Engineering Contradiction:
Improvemanufacturing efficiencyVSAvoidproduction time
Core Design Contradiction:
Ease of manufactureVSLoss of time

Solution Approach 1:

The patent applies preliminary action by pre-forming monodisperse latex particles with controlled size and uniform properties before the aggregation step. This preliminary preparation of uniformly sized latex particles enables faster and more efficient aggregation processing, reducing overall production time and improving manufacturing efficiency compared to conventional emulsion aggregation methods that start from scratch.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves stable triboelectric charging, reduces production time, and lowers unit manufacturing costs by enhancing the hydrophobicity of toner particles, thus improving print quality and equipment performance while minimizing humidity-related issues.

Implementation Method 1

enhance triboelectric robustness

Methodology Applied
Scientific EffectTriboelectric effect: Triboelectric Effect

Implementation Method 2

enhancing the hydrophobicity of toner particles, thus improving print quality and equipment performance while minimizing humidity-related issues

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS7727696B2Toner compositions
Publication Date: 2010.06.01 GENESEE VALLEY INNOVATIONS LLC
  • US7727696B2 patent drawing
  • US7727696B2 patent drawing
  • US7727696B2 patent drawing

AI summary

A toner having its surface functionalized with alkaline resins is provided, and processes for producing the same.