Continuous Furfural Production via Vapor Counterflow Stripping

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Solution Overview

Problem

Current furfural production methods, particularly the two-step process using lignocellulosic raw materials, face issues of discontinuous reactions, low yield, high labor intensity, environmental pollution, and inefficient energy use due to batch reactors and heterogeneous mixing, leading to by-products and low sugar concentration.

Innovation Solution

A continuous production system involving an acid solution output unit, raw material mixing, feeding, main reaction, discharging, stripping reaction column, separation, and purification units, where lignocellulosic raw materials are mixed with acid solutions under pressure, and a vapor counterflow stripping reaction process is used to enhance yield and reduce by-products and energy consumption.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If batch reactors are used for hydrolysis and dehydration reactions, then the process is simple to operate, but the production efficiency is low and labor intensity is high

Engineering Contradiction:
Improveoperation simplicityVSAvoidproduction efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The patent implements continuous reaction systems where lignocellulosic raw materials undergo hydrolysis in a continuous reactor to produce pentose, which then continuously flows to a dehydration reactor to produce furfural. This continuous operation eliminates batch processing interruptions, significantly improving production efficiency while maintaining operational simplicity through automated flow control.

Inventive Principle:
Principle #20Continuity of useful action

2Device complexity

If dilute acid hydrolysis is used in batch reactors, then the equipment investment is low, but the sugar yield is small and sugar concentration is low

Engineering Contradiction:
Improveequipment investmentVSAvoidsugar yield
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The continuous hydrolysis reactor maintains constant reaction conditions with continuous material flow, allowing for optimized acid concentration and contact time. This continuous operation enables higher sugar yields and concentrations compared to batch processing, while the reactor design remains relatively simple and cost-effective.

Inventive Principle:
Principle #20Continuity of useful action

3Device complexity

If heterogeneous mixing of material and acid solution occurs, then the mixing process is simple, but the decomposition of hydrolyzed sugar occurs leading to more by-products

Engineering Contradiction:
Improvemixing process complexityVSAvoidby-products
Core Design Contradiction:
Device complexityVSObject-generated harmful factors

Solution Approach 1:

The patent replaces mechanical mixing with vapor-phase acid delivery system. The acid is vaporized and introduced into the reaction zone where it uniformly distributes over the lignocellulosic material without requiring mechanical agitation. This substitution eliminates heterogeneous mixing issues and prevents sugar decomposition while maintaining process simplicity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

4Device complexity

If heterogeneous heating of water vapor occurs, then the heating system is simple, but the decomposition of hydrolyzed sugar and low sugar concentration occur

Engineering Contradiction:
Improveheating system complexityVSAvoidsugar concentration
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The patent replaces conventional liquid-phase heating with vapor-phase heating system. Water is vaporized and the vapor directly contacts the reaction mixture, providing uniform heat distribution throughout the reaction zone. This eliminates hot spots and heterogeneous heating issues, preventing sugar decomposition while maintaining simple heating system design.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

5Device complexity

If the one-step method is used, then the equipment investment is low, but the furfural yield is low and environmental pollution is serious

Engineering Contradiction:
Improveequipment investmentVSAvoidfurfural yield
Core Design Contradiction:
Device complexityVSQuantity of substance

Solution Approach 1:

The patent divides the furfural production process into two separate continuous reactors: a hydrolysis reactor for converting lignocellulose to pentose, and a dehydration reactor for converting pentose to furfural. This segmentation allows each reactor to be optimized for its specific function, achieving high furfural yields while keeping individual reactor designs simple and cost-effective.

Inventive Principle:
Principle #1Segmentation

6Ease of manufacture

If the two-step method with batch reactors is used, then the reaction steps are clearly separated, but the labor intensity is high and production cost is high

Engineering Contradiction:
Improvereaction step separationVSAvoidlabor intensity
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The patent implements continuous flow systems for both hydrolysis and dehydration steps. The pentose produced in the continuous hydrolysis reactor automatically flows to the continuous dehydration reactor, creating an integrated continuous production line. This eliminates the need for manual intervention between batches, significantly reducing labor intensity while maintaining clear separation of reaction steps through dedicated reactor units.

Inventive Principle:
Principle #20Continuity of useful action

7Device complexity

If conventional batch processing is used, then the process control is simple, but the energy consumption is high and environmental pollution is serious

Engineering Contradiction:
Improveprocess control complexityVSAvoidunit energy consumption
Core Design Contradiction:
Device complexityVSUse of energy by moving object

Solution Approach 1:

The continuous reaction system maintains constant operating conditions with steady material and energy flow. Heat exchangers recover energy from product streams to preheat feedstocks, and the continuous operation eliminates repeated heating and cooling cycles inherent in batch processing. This reduces unit energy consumption while maintaining simple automated control systems.

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The system achieves a 10-30% higher furfural yield and 10-20% lower unit energy consumption compared to traditional methods, with improved production efficiency and reduced labor intensity, while minimizing side reactions and environmental pollution.

Implementation Method 1

The hemicellulose is hydrolyzed to be pentose under a certain temperature and with acid catalysis, and the pentose is simultaneously dehydrated to form the furfural

Methodology Applied
Scientific EffectAcid catalysis: Catalysis

Implementation Method 2

the hemicellulose is hydrolyzed to be pentose under a certain temperature and with acid catalysis

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Implementation Method 3

a vapor counterflow stripping reaction process is used to enhance yield and reduce by-products and energy consumption

Methodology Applied
Scientific EffectHeat transfer: Convection

Data Source

PatentUS11767304B2System and method for continuously preparing furfural using lignocellulosic raw material
Publication Date: 2023.09.26 ECO BIOMASS TECH CO LTD
  • US11767304B2 patent drawing
  • US11767304B2 patent drawing
  • US11767304B2 patent drawing

AI summary

The present invention discloses a system and a method for continuously preparing furfural using lignocellulosic raw material. The system comprises an acid solution output unit, a raw material mixing unit, a feeding unit, a main reaction unit, a discharging unit, a stripping reaction column, a separation unit, and a purification unit. The method comprises an acid solution output step, a raw material mixing step, a feeding step, a hydrolysis reaction step, a discharging step, a stripping reaction step, a separation step, and a purification step. The present invention is a genuine continuous production system, which achieves continuous acquisition of products in terms of time, reduces labor intensity, and improves production efficiency. The whole process has a reasonable design, high furfural yields and low unit energy consumption.