Fused Polycyclic Boron Compound for OLED Emission Layer

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving low driving voltage, high emission efficiency, and long lifetime, particularly in stabilizing materials for efficient light emission.

Innovation Solution

A light emitting element incorporating a fused polycyclic compound represented by Formula 1, which is used in the emission layer to enhance emission properties and lifetime, with the compound having a specific structure that includes aromatic rings fused via a boron atom and heteroatoms, and a first substituent connected to the third aromatic ring, contributing to improved intermolecular interaction and reduced triplet excitation state concentration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic compounds are used in the emission layer, then the device can operate, but the emission efficiency is low and lifetime is short

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifetime
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent modifies the molecular structure of organic compounds by introducing specific fused polycyclic frameworks with boron atoms and heteroatoms, changing chemical parameters to achieve both high emission efficiency and long device lifetime simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention uses composite organic compounds combining multiple functional units (aromatic rings, boron atoms, heteroatoms) within a single molecular structure to achieve synergistic effects that improve both emission properties and device stability

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If materials are optimized for high emission efficiency, then light output improves, but device lifetime decreases due to material instability

Engineering Contradiction:
Improvelight emission intensityVSAvoiddevice lifetime
Core Design Contradiction:
Illumination intensityVSDuration of action of stationary object

Solution Approach 1:

The patent introduces specific local structural features (boron atoms at specific positions, heteroatom configurations) within the molecular structure that locally enhance both emission efficiency and stability without compromising the other properties

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The invention develops organic compounds with enhanced intrinsic stability that can maintain high emission efficiency over extended periods, effectively replacing the need for short-living materials with long-lasting alternatives

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Productivity

If triplet state energy is utilized for phosphorescence emission, then emission efficiency improves, but driving voltage increases

Engineering Contradiction:
Improveemission efficiencyVSAvoiddriving voltage
Core Design Contradiction:
ProductivityVSStress or pressure

Solution Approach 1:

The patent modifies the energy levels and electronic structure of the organic compound through molecular design, changing parameters to enable efficient phosphorescence emission at lower driving voltages

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the fused polycyclic compound in the light emitting element improves emission efficiency and extends the device's lifetime by suppressing Dexter energy transfer and aggregation, while maintaining a narrow emission spectrum, thus achieving enhanced performance in organic electroluminescence.

Implementation Method 1

Development is currently directed to thermally activated delayed fluorescence (TADF) materials which use delayed fluorescence phenomenon

Methodology Applied
Scientific EffectDelayed fluorescence: Fluorescence

Implementation Method 2

fluorescence emission, which uses triplet-triplet annihilation (TTA) in which singlet excitons are generated by the collision of triplet excitons

Methodology Applied
Scientific EffectTriplet-triplet annihilation:

Implementation Method 3

An organic electroluminescence display is different from a liquid crystal display in that it is a so-called self-luminescent display in which holes and electrons respectively injected from a first electrode and a second electrode recombine in an emission layer so that a light emitting material including an organic compound in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS20240284795A1Light emitting element and fused polycyclic compound for the light emitting element
Publication Date: 2024.08.22 SAMSUNG DISPLAY CO LTD
  • US20240284795A1 patent drawing
  • US20240284795A1 patent drawing
  • US20240284795A1 patent drawing

AI summary

Embodiments provide a fused polycyclic compound and a light emitting element that includes the fused polycyclic compound. The light emitting element includes a first electrode, a second electrode disposed on the first electrode, and at least one functional layer disposed between the first electrode and the second electrode, wherein the at least one functional layer includes the fused polycyclic compound. The fused polycyclic compound is represented by Formula 1, which is explained in the specification.