Fused Polycyclic Compound for OLED Emission Layer Efficiency

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Solution Overview

Problem

Current organic electroluminescence display devices face challenges in achieving high light efficiency and service life due to limitations in materials used for light emitting devices.

Innovation Solution

A light emitting device incorporating a fused polycyclic compound, specifically a central structure with a fused ring of five rings containing two nitrogen atoms and one boron atom, is used in the emission layer, which enhances charge transfer properties and reduces nonradiative decay, thereby improving light emitting efficiency and service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional materials are used in the emission layer, then device structure is simple, but light emitting efficiency and service life are insufficient

Engineering Contradiction:
Improvelight emitting efficiencyVSAvoidmaterial structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies the chemical structure parameters of the emission layer materials by introducing a fused polycyclic compound with specific ring structures containing nitrogen and boron atoms. This structural parameter change enhances charge transfer properties and reduces nonradiative decay, directly improving light emitting efficiency while maintaining reasonable device complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system where the fused polycyclic compound (Formula 1) is combined with specific host materials (Formulae HT-1, ET-1, or D-1) in the emission layer. This composite approach leverages the complementary properties of different materials to achieve high light emitting efficiency and extended service life

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If conventional emission materials are used, then device manufacturing is simple, but service life is limited

Engineering Contradiction:
Improveservice lifeVSAvoidmaterial synthesis complexity
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent changes the molecular parameters of the emission material by incorporating a fused polycyclic core structure with specific heteroatoms (nitrogen and boron). This parameter modification reduces triplet exciton accumulation and Dexter energy transfer, thereby extending service life despite increased synthesis complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The fused polycyclic compound acts as an intermediary material in the emission layer that mediates between charge carriers and luminescent centers. It facilitates efficient charge transfer while minimizing harmful interactions, thus extending device service life through its intermediary function

Inventive Principle:
Principle #24Intermediary (Mediator)

3Use of energy by moving object

If standard emission materials are used, then device structure is straightforward, but light efficiency is insufficient

Engineering Contradiction:
Improvelight efficiencyVSAvoidcompound structure complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent optimizes energy utilization by changing the electronic structure parameters of the emission layer materials. The fused polycyclic compound with specific ring configurations and heteroatom arrangements enhances radiative recombination efficiency, improving light efficiency despite the complex molecular structure

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces local structural features (fused rings with nitrogen and boron atoms) within the emission layer materials to create localized regions of enhanced charge transfer and reduced nonradiative decay. This local quality improvement boosts light efficiency without requiring complete redesign of the entire device structure

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of the fused polycyclic compound in the emission layer leads to increased light emitting efficiency and extended service life by reducing triplet excitons and Dexter energy transfer, resulting in improved luminous efficiency and device durability.

Implementation Method 1

a central structure with a fused ring of five rings containing two nitrogen atoms and one boron atom, is used in the emission layer, which enhances charge transfer properties

Methodology Applied
Scientific EffectCharge transfer:

Implementation Method 2

reduces nonradiative decay, thereby improving light emitting efficiency and service life

Methodology Applied
Scientific EffectNonradiative decay:

Implementation Method 3

reducing triplet excitons and Dexter energy transfer, resulting in improved luminous efficiency and device durability

Methodology Applied
Scientific EffectTriplet excitons:

Implementation Method 4

reducing triplet excitons and Dexter energy transfer, resulting in improved luminous efficiency and device durability

Methodology Applied
Scientific EffectDexter energy transfer:

Data Source

PatentUS20240315134A1Light emitting device and fused polycyclic compound for the same
Publication Date: 2024.09.19 SAMSUNG DISPLAY CO LTD
  • US20240315134A1 patent drawing
  • US20240315134A1 patent drawing
  • US20240315134A1 patent drawing

AI summary

A light emitting device that includes a first electrode, a second electrode provided on the first electrode, and an emission layer provided between the first electrode and the second electrode is provided. The emission layer includes a fused polycyclic compound, and may also include at least one of a second compound, a third compound, or a fourth compound. The fused polycyclic compound includes three aromatic rings fused by boron and nitrogen atoms and also includes substituents with steric properties that may reduce or prevent the negative impact caused by intermolecular interactions and improve the emission efficiency and service life of the light emitting device.