Fused Polycyclic Compound for OLED Emission Layer

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving low driving voltage, high luminous efficiency, and long service life, with existing materials failing to stabilize these characteristics effectively.

Innovation Solution

A light emitting device is developed that incorporates a fused polycyclic compound, specifically designed for the emission layer, which includes a structure where aromatic rings are fused via a boron atom and nitrogen atoms, with substituents providing steric hindrance to prevent structural deterioration and enhance luminous efficiency and service life.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic compounds are used in the emission layer, then the device can operate, but luminous efficiency is low and service life is short

Engineering Contradiction:
Improveluminous efficiencyVSAvoidservice life
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the organic compound by introducing a specific fused polycyclic framework with boron and nitrogen atoms, along with specific substituents. This structural parameter change results in improved luminous efficiency and extended service life by optimizing the compound's photophysical and chemical properties for OLED operation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite molecular structure combining a fused polycyclic core with specific substituents (R1-R7 groups). This composite approach integrates multiple functional elements within a single molecule to achieve both high luminous efficiency and enhanced stability, resolving the contradiction between productivity and reliability.

Inventive Principle:
Principle #40Composite materials

2Power

If the emission layer uses standard organic materials, then device operation is achieved, but driving voltage remains high

Engineering Contradiction:
Improvedriving voltageVSAvoidluminous efficiency
Core Design Contradiction:
PowerVSProductivity

Solution Approach 1:

The patent modifies the energy levels and electronic structure parameters of the emission layer material through the fused polycyclic structure. This changes the HOMO-LUMO gap and charge transport characteristics, enabling lower driving voltage while maintaining or improving luminous efficiency.

Inventive Principle:
Principle #35Parameter changes

3Illumination intensity

If conventional emission layer materials are used, then the device functions, but quenching phenomena occur and color purity is reduced

Engineering Contradiction:
Improvecolor purityVSAvoidquenching phenomena
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The patent introduces local steric hindrance through specific substituents (R1-R7) attached to the fused polycyclic core. This local structural feature prevents harmful intermolecular interactions and quenching phenomena at specific positions, thereby reducing energy loss and improving color purity without affecting overall device function.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this fused polycyclic compound in the emission layer increases luminous efficiency and extends the service life of the light emitting device by suppressing intermolecular interactions and Dexter energy transfer, leading to improved blue emission with high color purity and reduced quenching phenomena.

Implementation Method 1

holes and electrons respectively injected from a first electrode and a second electrode recombine in an emission layer, so that a luminescent material including an organic compound in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

suppressing intermolecular interactions and Dexter energy transfer, leading to improved blue emission with high color purity

Methodology Applied
Scientific EffectDexter energy transfer:

Data Source

PatentUS20240124497A1Light emitting device and fused polycyclic compound for the light emitting device
Publication Date: 2024.04.18 SAMSUNG DISPLAY CO LTD
  • US20240124497A1 patent drawing
  • US20240124497A1 patent drawing
  • US20240124497A1 patent drawing

AI summary

Embodiments provide a fused polycyclic compound and a light emitting device including the fused polycyclic compound. The light emitting device includes a first electrode, a second electrode facing the first electrode, and an emission layer disposed between the first electrode and the second electrode, wherein the emission layer includes the fused polycyclic compound, which is represented by Formula 1 and is explained in the specification: