Fused Polycyclic OLED Emitter for Efficient Blue Emission Life

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Solution Overview

Problem

Current organic electroluminescence devices face challenges in achieving high emission efficiency, long lifespan, and low driving voltage, with existing materials not adequately addressing these demands.

Innovation Solution

Incorporating a fused polycyclic compound represented by specific formulas into the emission layer of an organic electroluminescence device, which includes two fused polycyclic heterocycles connected via a five- or six-member aromatic ring linker, optimizing boron and nitrogen positions for improved light-emitting properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional organic electroluminescence materials are used, then device structure and operation are maintained, but emission efficiency and lifespan are insufficient

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical structure parameters of the organic electroluminescence material by introducing a fused polycyclic heterocyclic core structure with specific substituents (Formula 1), which modifies the HOMO-LUMO energy levels and improves electron-hole recombination efficiency, thereby simultaneously enhancing emission efficiency and device lifespan

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material strategy by combining the fused polycyclic heterocyclic core structure with various aromatic hydrocarbon ring and heterocycle substituents (Cy1-Cy7), creating a series of compounds with optimized properties that achieve both high emission efficiency and extended device operation life

Inventive Principle:
Principle #40Composite materials

2Use of energy by moving object

If driving voltage is reduced, then energy consumption decreases, but emission efficiency may be compromised

Engineering Contradiction:
Improvedriving voltageVSAvoidemission efficiency
Core Design Contradiction:
Use of energy by moving objectVSProductivity

Solution Approach 1:

The patent optimizes the energy level parameters of the organic compound by adjusting the HOMO and LUMO levels through substituent selection, enabling lower driving voltage operation while maintaining efficient charge injection and recombination that sustains high emission efficiency

Inventive Principle:
Principle #35Parameter changes

3Productivity

If emission efficiency is increased, then light output improves, but device lifespan may decrease due to material degradation

Engineering Contradiction:
Improveemission efficiencyVSAvoiddevice lifespan
Core Design Contradiction:
ProductivityVSDuration of action of stationary object

Solution Approach 1:

The patent modifies the chemical stability parameters of the organic material through the fused polycyclic heterocyclic core structure, which provides enhanced structural rigidity and resistance to degradation, allowing high emission efficiency to be maintained over extended device operation periods

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent avoids using expensive heavy metal complexes typically required for phosphorescence by employing purely organic fluorescent materials with extended lifetimes, achieving a sustainable solution that eliminates the usual trade-off between efficiency and lifespan

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this fused polycyclic compound enhances emission efficiency and extends the lifespan of organic electroluminescence devices while maintaining a suitable full width at half maximum and wavelength range for blue light emission, outperforming comparative examples in device longevity.

Implementation Method 1

The emission layer may be to emit delayed fluorescence

Methodology Applied
Scientific EffectDelayed fluorescence: Fluorescence

Implementation Method 2

an organic electroluminescence display device is a so-called self-luminescent display device in which holes and electrons respectively injected from a first electrode and a second electrode recombine in an emission layer, and a light-emitting organic compound in the emission layer emits light

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11832506B2Organic electroluminescence device and fused polycyclic compound for organic electroluminescence device
Publication Date: 2023.11.28 SAMSUNG DISPLAY CO LTD
  • US11832506B2 patent drawing
  • US11832506B2 patent drawing
  • US11832506B2 patent drawing

AI summary

An organic electroluminescence device of an embodiment includes a first electrode, an oppositely disposed second electrode, and a plurality of organic layers disposed between the first electrode and the second electrode, wherein at least one of the plurality of organic layers includes a fused polycyclic compound represented by Formula 1 and has an improved emission efficiency and long device life span: