Fusion Weld Precipitation Control for Crack-Resistant Dissimilar Joints

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Solution Overview

Problem

The variability in nitrogen and carbon content in ERNiCr-3 welding materials leads to inconsistent chemical, microstructural, and mechanical properties, affecting weld quality and susceptibility to cracking during fusion welding of dissimilar metals.

Innovation Solution

Control of nitrogen and carbon content in the weld material through adjustments in shield gas composition, addition of nitrogen and carbon sources, and modification of weld metal composition to achieve specific precipitate formation, thereby regulating carbide and nitride precipitation and improving mechanical properties and crack resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If nitrogen and carbon content are not controlled in ERNiCr-3 welding materials, then material variability is high and manufacturing is easier, but weld quality and crack resistance deteriorate

Engineering Contradiction:
Improveweld quality and crack resistanceVSAvoidcontrol process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by precisely controlling the nitrogen content (0.01-0.05 wt%) and carbon content (0.03-0.07 wt%) of the welding material to optimize precipitate formation. This controlled variation in chemical parameters directly improves weld reliability and crack resistance while maintaining manageable manufacturing complexity through defined compositional ranges.

Inventive Principle:
Principle #35Parameter changes

2Strength

If nitrogen and carbon content are controlled to optimize precipitate formation, then mechanical properties improve, but manufacturing precision requirements increase

Engineering Contradiction:
Improvemechanical strength and crack resistanceVSAvoidcompositional control precision
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent specifies precise compositional ranges for nitrogen (0.01-0.05 wt%) and carbon (0.03-0.07 wt%) to control precipitate volume fractions and distribution. These parameter changes directly enhance mechanical strength and crack resistance, while the defined ranges provide clear manufacturing targets that balance precision requirements with practical producibility.

Inventive Principle:
Principle #35Parameter changes

3Strength

If precipitate volume fraction is increased through nitrogen and carbon addition, then mechanical strength improves, but harmful factors such as cracking susceptibility may increase

Engineering Contradiction:
Improvemechanical strengthVSAvoidcracking susceptibility
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent optimizes precipitate volume fraction by carefully controlling nitrogen (0.01-0.05 wt%) and carbon (0.03-0.07 wt%) content, achieving a balance where sufficient precipitates provide mechanical strength while avoiding excessive precipitates that would increase cracking susceptibility. This parameter optimization resolves the contradiction between strength enhancement and harmful factor reduction.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potential harm of nitrogen and carbon (which can cause cracking) into a benefit by controlling their content to form beneficial precipitates. The controlled nitrogen and carbon content create MC-type and M23C6-type carbide precipitates that strengthen the weld metal, while the precise compositional control prevents harmful intergranular carbide formation and cracking.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The controlled nitrogen and carbon content in the weld material enhances mechanical strength, reduces cracking susceptibility, and improves the overall performance of weldments by optimizing precipitate volume fractions and distribution.

Implementation Method 1

controlling precipitates, particularly carbide (e.g. MC-type), nitride (e.g. MN-type) and/or complex carbide/nitride (e.g. MX-type) type precipitates, in weld material

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 2

early formation and presence of high temperature nitrides have a prominent effect on the volume (via enhanced nucleation) and morphology of carbide or nitride type phases

Methodology Applied
Scientific EffectNucleation: Nucleation

Implementation Method 3

adjusting the shield gas composition to increase nitrogen gas and nitride species, adjusting the shield gas composition to increase carbon gas and carbide species

Methodology Applied
Scientific EffectGas dissolution in molten metal: Absorption (physical)

Implementation Method 4

forming a region of molten material between a first metallic body and a second metallic body

Methodology Applied
Scientific EffectMelting: Melting

Implementation Method 5

solidifying the molten material to form a weld material

Methodology Applied
Scientific EffectSolidification: Freezing

Data Source

PatentUS11413710B2Metal carbide/nitride precipitation control in fusion welding
Publication Date: 2022.08.16 BWXT NUCLEAR OPERATIONS GROUP INC
  • US11413710B2 patent drawing
  • US11413710B2 patent drawing
  • US11413710B2 patent drawing

AI summary

Properties and performance of weld material between metals in a weldment is controlled by modifying one or more of the nitrogen content and the carbon content to produce carbide (e.g. MC-type), nitride and/or complex carbide/nitride (e.g. MX-type) type precipitates. Fusion welding includes (i) adjusting shield gas composition to increase nitrogen/carbon gas and nitride/carbide species, (ii) adjusting composition of nitrogen/carbon in materials that participate in molten welding processes, (iii) direct addition of nitrides/carbides (e.g. powder form), controlled addition of nitride/carbide forming elements (e.g. Ti, Al), or addition of elements that increase/impede solubility of nitrogen/carbon or nitride/carbide promoting elements (e.g. Mn), and (iv) other processes, such as use of fluxes and additive materials. Weld materials have improved resistance to different cracking mechanisms (e.g., hot cracking mechanisms and solid state cracking mechanisms) and improved tensile related mechanical properties.