Ga2O3 Substrate with Chamfered Edge for Crack Resistance
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Solution Overview
Problem
Ga2O3 single-crystal substrates are prone to cracking due to their strong cleavability, and existing methods have not effectively addressed this issue.
Innovation Solution
A Ga2O3 single-crystal substrate with a uniform crystal structure and controlled crystal growth rate is manufactured, featuring a (001) plane with uniform hardness and a chamfered outer peripheral portion, reducing the likelihood of crack formation.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Ease of manufacture
If Ga2O3 single-crystal substrate is manufactured with strong cleavability, then crystal growth is facilitated, but cracking resistance deteriorates
Solution Approach 1:
The patent applies local quality by creating a chamfered region at the outer periphery of the substrate that has different structural characteristics from the central portion. This chamfered region with reduced thickness and modified geometry locally absorbs stress concentrations, while the central portion maintains the uniform crystal structure needed for device fabrication. This resolves the contradiction by providing crack resistance at critical locations without compromising overall crystal growth quality.
Solution Approach 2:
The patent implements preliminary action by pre-forming the chamfered region during crystal growth or subsequent processing before the substrate is subjected to stress or device fabrication. This preemptive structural modification eliminates potential crack initiation sites at the outer periphery, allowing the substrate to maintain strength during handling and processing while preserving the cleavability needed for crystal growth.
2Productivity
If substrate diameter is increased to 100 mm or more, then productivity is improved, but uniformity of hardness across the surface becomes more difficult to maintain
Solution Approach 1:
The patent applies local quality by dividing the substrate into distinct regions: a central portion with uniform crystal structure and hardness suitable for device fabrication, and an outer peripheral chamfered region with modified geometry. This regional differentiation allows the large-diameter substrate to maintain hardness uniformity in the central area where devices are manufactured, while the outer region accommodates the size increase without compromising overall quality.
Solution Approach 2:
The patent segments the substrate into functionally distinct zones: the central portion for active device fabrication and the outer peripheral chamfered region for stress relief and handling. This segmentation allows each region to be optimized independently, enabling large-diameter substrates to maintain hardness uniformity in the central area while the outer region provides structural support and crack resistance.
3Strength
If nanoindentation hardness is increased to 13 GPa to 20 GPa, then cracking resistance is improved, but crystal defect concentration may increase
Solution Approach 1:
The patent applies local quality by creating the chamfered region with specific geometric characteristics that enhance cracking resistance through stress distribution, rather than increasing hardness throughout the entire substrate. This localized structural modification achieves the desired strength improvement without introducing crystal defects across the whole substrate, preserving the uniform composition needed for high-quality device fabrication.
Solution Approach 2:
The patent implements preliminary action by pre-forming the chamfered region with optimized geometry that provides crack resistance before device fabrication. This preemptive structural design achieves the required hardness and strength characteristics without needing to increase overall crystal defect concentration, as the chamfered geometry itself provides the mechanical advantage for crack resistance.
Data Source
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AI summary
In the present invention, a digallium trioxide single crystal substrate has a circular main surface, the diameter of the digallium trioxide single crystal substrate being at least 100 mm, the main surface being the (100) plane of the digallium trioxide single crystals constituting the digallium trioxide single crystal substrate, the main surface having a central portion containing the center of the main surface and an outer peripheral portion surrounding the outer periphery of the central portion, and the outer peripheral portion being a processed part that has been chamfered. First nanoindention hardnesses measured according to a nanoindention method using a Berkovich indenter at nine locations on the main surface are all 13-20 GPa under a first condition in which the maximum load is set at 10 mN and a load is applied such that the angle of intersection of one side of the indention and the direction in which the [100] direction of the digallium trioxide single crystal projects onto the main surface is 0-10°.