Gallium Oxide Layer Structure for Crack-Resistant Interfaces

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Solution Overview

Problem

Gallium oxide-based semiconductor devices face issues with cracks at the interface between n-type and i-type semiconductor layers due to significant differences in lattice constants, leading to stress and potential cracking during manufacturing and usage.

Innovation Solution

A semiconductor device structure with a first n-type gallium oxide-based semiconductor layer and a second n-type layer having a higher electrically active donor concentration, where the difference in donor concentration between the two layers is minimized, reducing the lattice constant difference and stress at the interface, and incorporating a transition layer to further suppress cracking.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If an i-type semiconductor layer with low donor concentration is formed on an n-type semiconductor layer with high donor concentration, then the carrier concentration difference between layers is increased, but the lattice constant difference and stress at the interface increase causing cracks

Engineering Contradiction:
Improvedevice reliabilityVSAvoidinterface strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the donor concentration parameter of the semiconductor layer from low (i-type) to high (n-type with 1×10^18 to 1×10^20 atoms/cm³), which reduces the lattice constant difference and stress at the interface between layers, preventing cracks while maintaining the necessary carrier concentration difference for device operation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a gradient in donor concentration across the semiconductor layer thickness, with the donor concentration being higher near the interface with the n-type layer and decreasing toward the opposite side. This local variation in quality allows the interface region to have matched lattice constants (reducing stress) while the bulk maintains the required carrier concentration difference for device function

Inventive Principle:
Principle #3Local quality

2Strength

If the donor concentration difference between semiconductor layers is reduced, then the lattice constant difference and stress are minimized, but the carrier concentration difference needed for device operation may be compromised

Engineering Contradiction:
Improveinterface strengthVSAvoiddevice reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent simultaneously optimizes two parameters: the average donor concentration is set to 1×10^18 to 1×10^20 atoms/cm³ (higher than conventional i-type) to reduce lattice mismatch, while the thickness is controlled at 10 nm to 10 μm to maintain the necessary carrier concentration gradient for device operation, achieving both interface strength and device reliability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent introduces the thickness dimension (10 nm to 10 μm) as a critical parameter to resolve the contradiction. By controlling the layer thickness, the patent enables the donor concentration to be high enough to reduce lattice mismatch stress while still maintaining sufficient carrier concentration difference across the layer for proper device operation

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach effectively reduces stress at the interface, minimizing the occurrence of cracks and enhancing the reliability of the semiconductor device by maintaining a smaller difference in donor concentration and carrier concentration between the layers.

Implementation Method 1

significant differences in lattice constants, leading to stress and potential cracking during manufacturing and usage

Methodology Applied
Scientific EffectLattice constant difference:

Implementation Method 2

leading to stress and potential cracking during manufacturing and usage

Methodology Applied
Scientific EffectStress:

Data Source

PatentUS12136654B2Method for manufacturing semiconductor device
Publication Date: 2024.11.05 DENSO CORP
  • US12136654B2 patent drawing
  • US12136654B2 patent drawing
  • US12136654B2 patent drawing

AI summary

A semiconductor device includes: a first semiconductor layer having an N conductive type and made of a gallium oxide-based semiconductor; and a second semiconductor layer made of a gallium oxide-based semiconductor, in contact with the first semiconductor layer, and having the N conductive type with an electrically active donor concentration higher than an electrically active donor concentration of the first semiconductor layer. A difference between a donor concentration of the first semiconductor layer and a donor concentration of the second semiconductor layer is smaller than a difference between the electrically active donor concentration of the first semiconductor layer and the electrically active donor concentration of the second semiconductor layer.