Gallium Oxide Mist CVD Flow Rectification for Uniform Film Growth

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Solution Overview

Problem

The mist CVD method faces challenges in maintaining in-plane uniformity of film thickness and film forming rate, especially with larger substrates, due to exponential decrease in mist supply and non-uniform film distribution, which existing solutions like substrate scanning and rotation fail to fully address, and can complicate apparatus design and maintenance.

Innovation Solution

A method and apparatus that rectifies the flow of mist and carrier gas to flow from the outer circumference to the center of the substrate within a film forming chamber using a middle plate, combined with a mist-forming unit, carrier gas supply, and exhaust system, ensuring uniform film thickness and increased forming rate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If heating is performed in a film forming chamber for film formation by thermal reaction, then the film can be formed on the substrate, but the amount of supplied mist decreases exponentially and the film forming rate decreases

Engineering Contradiction:
Improvefilm formation qualityVSAvoidfilm forming rate
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The process is divided into two separate chambers: a mist generation chamber where mist is produced without heating, and a film formation chamber where heating occurs. This segmentation allows mist generation and thermal reaction to occur independently, preventing the exponential decrease in mist supply while maintaining film formation quality.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Mist is generated and prepared in advance in the mist generation chamber before being supplied to the film formation chamber. This preliminary action ensures that sufficient mist is available for high-rate film formation without the constraints of in-chamber heating limitations.

Inventive Principle:
Principle #10Preliminary action

2Manufacturing precision

If scanning and rotating the substrate is implemented to improve uniformity, then in-plane uniformity can be partially improved, but the initial cost of the apparatus increases and maintenance becomes complicated

Engineering Contradiction:
Improvein-plane uniformity of film thicknessVSAvoidapparatus complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The complex scanning and rotating mechanisms are eliminated by extracting the uniformity control function to the mist supply system itself. The carrier gas-driven mist flow provides uniform distribution without requiring mechanical substrate movement, simplifying the apparatus while maintaining uniformity.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

Mechanical substrate scanning and rotation are replaced with a gas-flow-based mist delivery system. The carrier gas transports mist uniformly across the substrate surface, achieving the same uniformity goal without mechanical complexity.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Area of stationary object

If the diameter of the substrate is increased, then larger area coverage is achieved, but in-plane uniformity of film thickness becomes more difficult to maintain

Engineering Contradiction:
Improvesubstrate areaVSAvoidin-plane uniformity of film thickness
Core Design Contradiction:
Area of stationary objectVSManufacturing precision

Solution Approach 1:

The carrier gas serves as an intermediary that distributes mist uniformly across large substrate areas. The gas flow pattern ensures consistent mist delivery from the center to the edges of large-diameter substrates, maintaining uniformity regardless of substrate size.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

A pneumatic system using carrier gas flow replaces mechanical approaches for achieving uniform coverage. The gas flow dynamics are optimized to distribute mist uniformly across the entire substrate surface, enabling consistent film thickness on large-diameter substrates.

Inventive Principle:
Principle #29Pneumatics and hydraulics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method and apparatus achieve high in-plane uniformity of film thickness and improved film forming rate, particularly for large substrates, through a simple and efficient configuration that suppresses non-uniformity and enhances mist utilization.

Implementation Method 1

a raw material solution containing gallium is misted in a mist-forming unit to generate mist

Methodology Applied
Scientific EffectMisting/Atomization: Aerosol

Implementation Method 2

supplying a carrier gas for transferring the mist to the mist-forming unit

Methodology Applied
Scientific EffectGas flow transport: Convection

Implementation Method 3

rectifying flow of the mist and the carrier gas supplied to a surface of a substrate in the film forming chamber so as to flow along the surface of the substrate

Methodology Applied
Scientific EffectFlow rectification: Laminar Flow

Implementation Method 4

heat-treating the rectified mist to form a film on the substrate

Methodology Applied
Scientific EffectCondensation: Condensation

Implementation Method 5

form a film on the substrate

Methodology Applied
Scientific EffectDeposition: Deposition (physical)

Implementation Method 6

exhausting waste gas upward from the substrate

Methodology Applied
Scientific EffectExhaust flow: Pressure Gradient

Data Source

PatentUS12601054B2Method for producing a gallium oxide semiconductor film and a film forming apparatus
Publication Date: 2026.04.14 SHIN ETSU CHEMICAL CO LTD
  • US12601054B2 patent drawing
  • US12601054B2 patent drawing

AI summary

A method for producing a gallium oxide semiconductor film by a mist CVD method, including, a mist-forming step in which a raw material solution containing gallium is misted in a mist-forming unit to generate mist, a carrier gas supply step of supplying a carrier gas for transferring the mist to the mist-forming unit, a transferring step of transferring the mist from the mist-forming unit to a film forming chamber using the carrier gas via a supply pipe connecting the mist-forming unit and the film forming chamber, a rectification step of rectifying flow of the mist and the carrier gas supplied to a surface of a substrate in the film forming chamber so as to flow along the surface of the substrate, a film forming step of heat-treating the rectified mist to form a film on the substrate, and an exhaust step of exhausting waste gas upward from the substrate.