Al-Alloyed Gallium Oxide Ohmic Contacts via Selective Ion Implantation

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Solution Overview

Problem

Existing methods for forming ohmic contacts on aluminum-alloyed gallium oxide (AlxGa2−xO3) require complex epitaxial processes and do not allow selective doping, leading to increased surface roughness and limited control over dopant concentration, which is crucial for transistor device fabrication.

Innovation Solution

A method involving ion implantation of Group IV elements like silicon into AlxGa2−xO3, followed by annealing to activate the dopants, and depositing electrically conductive materials to form ohmic contacts, with controlled parameters such as implant dosage, energy, and anneal temperature to achieve optimal conductivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If complex epitaxial processes are used to form ohmic contacts on aluminum-alloyed gallium oxide, then ohmic contacts can be formed, but the process complexity increases and selective doping is not enabled

Engineering Contradiction:
Improveohmic contact formationVSAvoidepitaxial process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent changes the doping method from complex epitaxial processes to ion implantation, altering the process parameters to achieve simpler, more controllable doping. By using ion implantation with controlled dosage and energy parameters, the patent achieves selective doping while reducing process complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the chemical epitaxial growth process with a physical ion implantation process. This substitution enables precise control over dopant concentration and spatial distribution through mechanical control of ion beam parameters, eliminating the need for complex epitaxial equipment and processes

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Quantity of substance

If conventional doping methods are used on aluminum-alloyed gallium oxide, then doping can be achieved, but surface roughness increases

Engineering Contradiction:
Improvedopant concentrationVSAvoidsurface roughness
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

The patent optimizes ion implantation parameters including dosage, energy, and temperature to achieve desired dopant concentration while minimizing surface damage. By carefully controlling these parameters, the patent maintains surface smoothness while achieving effective doping

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary annealing treatments before final ohmic contact formation to repair implantation damage and smooth the surface. This preliminary action prevents surface roughness from propagating through subsequent processing steps

Inventive Principle:
Principle #10Preliminary action

3Reliability

If dopant concentration is not precisely controlled, then doping process is simpler, but conductivity control for transistor devices is limited

Engineering Contradiction:
Improveconductivity controlVSAvoiddoping process control
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements feedback control through measurement and characterization of dopant concentration at different stages. By monitoring the doping process and adjusting parameters based on measured results, the patent achieves precise conductivity control while maintaining process simplicity

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent replaces indirect conductivity control methods with direct ion implantation control, where dopant concentration is precisely determined by implantation dosage and area. This mechanical control method provides direct, quantitative control over conductivity without complex intermediate steps

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of ohmic contacts with low contact resistance and sheet resistance, providing high activation efficiency and damage recovery, suitable for high-electric field applications.

Implementation Method 1

implanting a Group IV element as a donor impurity into the AlxGa2−xO3 crystal structure with an ion implantation process

Methodology Applied
Scientific EffectIon implantation: Ion Implantation

Implementation Method 2

annealing the implanted AlxGa2−xO3 crystal structure to activate the Group IV element to form an electrically conductive region

Methodology Applied
Scientific EffectAnnealing: Annealing

Data Source

PatentUS12532530B2Doped aluminum-alloyed gallium oxide and ohmic contacts
Publication Date: 2026.01.20 THE UNITED STATES OF AMERICA AS REPRESENTED BY THE SECRETARY OF THE NAVY
  • US12532530B2 patent drawing
  • US12532530B2 patent drawing
  • US12532530B2 patent drawing

AI summary

A method for controlling a concentration of donors in an Al-alloyed gallium oxide crystal structure includes implanting a Group IV element as a donor impurity into the crystal structure with an ion implantation process and annealing the implanted crystal structure to activate the Group IV element to form an electrically conductive region. The method may further include depositing one or more electrically conductive materials on at least a portion of the implanted crystal structure to form an ohmic contact. Examples of semiconductor devices are also disclosed and include a layer of an Al-alloyed gallium oxide crystal structure, at least one region including the crystal structure implanted with a Group IV element as a donor impurity with an ion implantation process and annealed to activate the Group IV element, an ohmic contact including one or more electrically conductive materials deposited on the at least one region.