Gallium Oxide Semiconductor Interface Stability

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Solution Overview

Problem

Semiconductor devices with Ga2O3 and SiC materials face issues with breakdown voltage and chemical degradation due to oxidation-reduction reactions at p-n junction interfaces, particularly under heat and current stress.

Innovation Solution

An oxide semiconductor device structure is introduced, featuring an n-type gallium oxide layer, a p-type oxide semiconductor layer with a different main component, and an oxide layer made of a material distinct from gallium oxide, positioned between the n-type and p-type layers to inhibit chemical reactions and maintain interface integrity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If a p-n junction interface is formed between n-type gallium oxide layer and p-type oxide semiconductor layer, then the device structure is established, but chemical reactions (oxidation-reduction) occur at the interface causing deterioration of device characteristics

Engineering Contradiction:
Improveinterface stabilityVSAvoiddevice characteristics
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

An oxide layer is introduced as an intermediary between the n-type gallium oxide layer and the p-type oxide semiconductor layer. This intermediate oxide layer prevents direct contact between the two semiconductor layers, thereby preventing oxidation-reduction reactions at the interface while maintaining the p-n junction functionality. The intermediary layer acts as a buffer that preserves interface stability without compromising device characteristics.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If post-annealing or heat treatment is applied to the semiconductor device, then the manufacturing process is completed, but the heat causes oxidation-reduction reactions at the p-n interface deactivating conductivity

Engineering Contradiction:
Improvemanufacturing processVSAvoidconductivity
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The oxide layer is formed beforehand as a protective barrier before heat treatment is applied during manufacturing. This pre-formed protective layer cushions the interface against thermal effects during subsequent annealing processes, preventing heat-induced oxidation-reduction reactions that would otherwise deactivate the conductivity of the semiconductor layers.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

3Ease of operation

If current is applied to operate the device, then the device functions, but the current generates heat that brings oxidation-reduction reactions to the fore

Engineering Contradiction:
Improvedevice operationVSAvoidheat-induced chemical reactions
Core Design Contradiction:
Ease of operationVSObject-affected harmful factors

Solution Approach 1:

The oxide layer serves as a thermal buffer and chemical barrier during device operation. When current flows through the device and generates heat, the intermediate oxide layer prevents direct thermal and chemical interaction between the n-type and p-type layers, suppressing heat-induced oxidation-reduction reactions while allowing the device to function normally.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This structure prevents deterioration of the semiconductor device's characteristics, such as heat resistance and voltage resistance, by reducing chemical reactions at the p-n interface and enhancing breakdown voltage.

Implementation Method 1

chemical change (an oxidation-reduction reaction) at an interface of the p-n junction deactivates the conductivity of the p-type semiconductor

Methodology Applied
Scientific EffectOxidation-reduction reaction: Redox Reactions

Data Source

PatentUS11239323B2Oxide semiconductor device and method for manufacturing same
Publication Date: 2022.02.01 MITSUBISHI ELECTRIC CORP
  • US11239323B2 patent drawing
  • US11239323B2 patent drawing
  • US11239323B2 patent drawing

AI summary

An object is to provide a technology for enabling prevention of deterioration of characteristics of an oxide semiconductor device. The oxide semiconductor device includes an n-type gallium oxide epitaxial layer, a p-type oxide semiconductor layer, and an oxide layer. The p-type oxide semiconductor layer is disposed above the n-type gallium oxide epitaxial layer, contains an element different from gallium as a main component, and has p-type conductivity. The oxide layer is disposed between the n-type gallium oxide epitaxial layer and the p-type oxide semiconductor layer, and is made of a material different from gallium oxide and different at least partly from a material of the p-type oxide semiconductor layer.