Galvanized Steel Decarburization for Spot Welding

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Solution Overview

Problem

High-strength galvanized steel sheets face challenges in electrical resistance spot weldability due to degradation of spot weldability and the occurrence of liquid metal embrittlement (LME) caused by microcracks and zinc permeation.

Innovation Solution

A galvanized steel sheet with a decarburized surface layer, achieved through a specific manufacturing process involving hot-rolling, coiling, edge portion heating, cold-rolling, annealing, and hot-dip galvanizing, to create a high decarburization ratio of at least 30% in the surface layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the strength of high-strength steel sheet is increased, then the tensile strength and yield strength are improved, but the spot weldability deteriorates due to microcrack formation and liquid metal embrittlement

Engineering Contradiction:
Improvetensile strengthVSAvoidspot weldability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by creating a decarburized layer specifically at the surface region (0-35μm depth) of the steel sheet, while maintaining high carbon content in the bulk material. This localized modification of carbon concentration (0.05-0.30% Ceq in surface layer, 0.20-0.50% Ceq in bulk) allows the surface to have improved weldability by reducing microcrack susceptibility, while the core retains high strength properties. The differential carbon distribution resolves the contradiction between overall strength and local weldability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the carbon concentration parameter across different depths of the steel sheet. By controlling the carbon equivalent (Ceq) to be 0.05-0.30% in the surface layer and 0.20-0.50% in the bulk, the material properties are modified to achieve both high strength and good weldability. This parameter gradient approach allows the surface to resist liquid metal embrittlement while the core maintains high tensile strength.

Inventive Principle:
Principle #35Parameter changes

2Strength

If the carbon concentration in the surface layer is high to maintain strength, then the overall strength is improved, but the spot weldability deteriorates due to increased microcrack susceptibility

Engineering Contradiction:
Improveyield strengthVSAvoidmicrocrack formation
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent creates a localized decarburized layer at the surface (0-35μm depth) with lower carbon equivalent (0.05-0.30% Ceq) compared to the bulk (0.20-0.50% Ceq). This local quality modification reduces the susceptibility to microcrack formation and liquid metal embrittlement in the surface region where welding occurs, while the core material maintains high strength through higher carbon content.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The steel sheet is segmented into two distinct regions based on carbon concentration: a surface layer (0-35μm) with low carbon equivalent for weldability, and a bulk region with high carbon equivalent for strength. This segmentation of the material structure allows each region to optimize its properties independently, resolving the contradiction between strength and microcrack resistance.

Inventive Principle:
Principle #1Segmentation

3Strength

If alloy elements such as Mn, Al, and Si are increased to enhance strength, then the tensile strength is improved, but surface quality deteriorates due to oxide formation

Engineering Contradiction:
Improvetensile strengthVSAvoidsurface quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating a decarburized surface layer with controlled composition that is less prone to oxide formation. The surface layer (0-35μm) has lower carbon equivalent (0.05-0.30% Ceq) which reduces the reactivity with atmosphere during handling and processing, thereby improving surface quality and plating adhesion. The bulk material maintains high alloy content for strength.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The decarburization process is performed as a preliminary action during hot rolling (coiling temperature 550-750°C) to create the low-carbon surface layer before subsequent cold rolling and galvanizing. This preliminary modification of the surface composition prevents oxide formation during later processing steps by reducing the carbon content that would otherwise react with oxygen and form surface defects.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in a galvanized steel sheet with excellent surface quality and resistance to liquid metal embrittlement, thereby enhancing electrical resistance spot weldability.

Implementation Method 1

heating an edge portion of the coiled hot-rolled steel sheet at 600-800° C. for 5 to 24 hours in a nitrogen atmosphere including 0.5-2% of oxygen

Methodology Applied
Scientific EffectDecarburization: Reduction

Implementation Method 2

annealing the cold-rolled steel sheet in an atmosphere of a dew point of -10-30° C. at 650-900° C.

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

hot-dip galvanizing the annealed cold-rolled steel sheet

Methodology Applied
Scientific EffectHot-dip galvanizing: Electroplating

Data Source

PatentUS12221701B2Welded member of galvanized steel sheets
Publication Date: 2025.02.11 POHANG IRON & STEEL CO LTD
  • US12221701B2 patent drawing

AI summary

A welded member includes: a first steel sheet including a base steel sheet and a zinc-based plating layer formed on a surface of the base steel sheet; and a second steel sheet spot-welded on the first steel sheet and facing the zinc-based plating layer of the first steel sheet, a spot-welded zone being formed between the first steel sheet and the second steel sheet. A surface layer of the base steel sheet has a decarburization ratio of 30% or more. The decarburization ratio is represented by equation: Decarburization ratio (%) of surface layer=(1−average carbon concentration in surface layer/bulk carbon concentration)*100 where the surface layer refers to a region of the base steel sheet from the surface thereof to a depth of 35 μm. A shoulder portion of the spot-welded zone includes a B-type crack having a length of 100 μm or less, and no C-type crack.