Hot-dip Galvanized Steel Plate with Residual Austenite for Formability

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Solution Overview

Problem

Current methods for producing high-strength hot-dip galvanized steel sheets with excellent formability and plating adhesion face challenges in achieving both high tensile strength and ductility, particularly with the presence of silicon, which leads to material anisotropy and increased costs due to complex processing requirements.

Innovation Solution

A high-strength hot-dip galvanized steel sheet with a microstructure containing ferrite of 40% or more and residual austenite of 8% or more, combined with controlled hot-rolling and cold-rolling processes, and a specific zinc flow rate in the galvanizing bath to suppress zinc oxide reactions, reducing material anisotropy and enhancing formability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If large amounts of Si are added to ensure residual austenite for excellent formability, then formability is improved, but material anisotropy increases due to texture development

Engineering Contradiction:
ImproveformabilityVSAvoidmaterial anisotropy
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The invention changes the chemical composition parameters by precisely controlling Si content (0.5-3.0%) and Mn content (1.5-3.0%), and by adding specific microalloying elements (Ti: 0.005-0.3%, Nb: 0.005-0.3%, V: 0.005-0.5%) to modify the microstructure and suppress harmful texture development while maintaining formability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite microstructure consisting of multiple phases (ferrite, residual austenite, bainite, and martensite) with specific volume fractions, where each phase contributes different properties that collectively improve formability while reducing anisotropy through the synergistic effect of the multi-phase structure

Inventive Principle:
Principle #40Composite materials

2Strength

If alloy elements are added in large amounts to ensure strength of 980 MPa or more, then strength is improved, but texture development is promoted causing material anisotropy

Engineering Contradiction:
Improveultimate tensile strengthVSAvoidmaterial anisotropy
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

The invention optimizes the composition parameters by limiting C to 0.1-0.40%, Si to 0.5-3.0%, and Mn to 1.5-3.0%, while adding small amounts of microalloying elements (Ti: 0.005-0.3%, Nb: 0.005-0.3%, V: 0.005-0.5%) to achieve the required strength through precipitation hardening and grain refinement rather than excessive alloying, thereby suppressing texture development

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention applies local quality by introducing microalloying elements in trace amounts that selectively precipitate at grain boundaries and dislocation sites to provide localized strengthening without causing widespread texture development, achieving high strength with minimal anisotropy

Inventive Principle:
Principle #3Local quality

3Ease of operation

If Si content is increased to ensure residual austenite, then formability is improved, but plating adhesion deteriorates due to zinc oxide reactions

Engineering Contradiction:
ImproveformabilityVSAvoidplating adhesion
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The invention introduces Mn and microalloying elements (Ti, Nb, V) as intermediary elements that modify the interaction between Si and zinc during hot-dip galvanizing, preventing the formation of harmful zinc oxide reactions while allowing Si to maintain residual austenite for formability

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention optimizes the Si content to a specific range (0.5-3.0%) and combines it with controlled Mn content (1.5-3.0%) and microalloying additions to achieve the right balance between maintaining residual austenite for formability and preventing excessive zinc oxide formation that would harm plating adhesion

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution achieves a high tensile strength of 980 MPa or more with excellent formability and plating adhesion, suitable for automotive components, while minimizing material anisotropy and production costs.

Implementation Method 1

there is a TRIP (TRansformation Induced Plasticity) steel which uses martensite transformation of the residual austenite at the time of plastic processing

Methodology Applied
Scientific EffectMartensite transformation: Phase Change

Implementation Method 2

hot-dip galvanized steel sheet and alloyed hot-dip galvanized steel sheet having excellent plating adhesion

Methodology Applied
Scientific EffectHot-dip galvanizing: Deposition (physical)

Data Source

PatentEP2762588B1High-strength hot dip galvanized steel plate having excellent moldability, weak material anisotropy and ultimate tensile strength of 980 mpa or more, high-strength alloyed hot dip galvanized steel plate and manufacturing method therefor
Publication Date: 2020.05.20 NIPPON STEEL CORPORATION
  • EP2762588B1 patent drawingFigure 3
  • EP2762588B1 patent drawing
  • EP2762588B1 patent drawing

AI summary

[Abstract] Provided is a high-strength hot-dip galvanized steel sheet having small material anisotropy and excellent formability with an ultimate tensile strength of 980 MPa or more. The hot-dip galvanized steel sheet includes a hot-dip galvanized layer formed on a surface of a base steel plate. The base steel plate contains, by mass%, C: 0.1 to less than 0.40%, Si: 0.5 to 3.0%, Mn: 1.5 to 3.0%, O: limited to 0.006% or less, P: limited to 0.04% or less, S: limited to 0.01% or less, Al: limited to 2.0% or less, N: limited to 0.01% or less, and a balance including Fe and inevitable impurities. A microstructure of the base steel sheet contains ferrite of 40% or more, residual austenite of 8 to less than 60%, by volume fraction, and a balance being bainite or martensite. In a sheet thickness range of 5/8 to 3/8 from the surface of the base steel sheet, a pole density of specific crystal orientation is within a predetermined range. The hot-dip galvanized layer contains Fe: less than 7 mass% and a balance including Zn, Al, and inevitable impurities.