Galvanized Steel Sheet Microstructure for Spot Weldability

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Solution Overview

Problem

High-strength galvanized steel sheets face challenges with spot weldability due to the risk of liquid metal embrittlement (LME) and deterioration in surface quality, primarily caused by microcracks and the diffusion of alloy elements leading to non-plating issues.

Innovation Solution

The development of a high-strength hot-dipped galvanized steel sheet with a specific microstructure in the surface layer regions, including a first surface layer region with 55% or more ferrite and a second surface layer region with 30% or more ferrite, along with an internal oxidation layer of sufficient thickness and uniformity, to enhance crack resistance and plating quality.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If the strength of the steel sheet is increased to reduce fuel consumption, then weight reduction and fuel efficiency are improved, but spot weldability deteriorates due to liquid metal embrittlement and microcrack formation

Engineering Contradiction:
ImprovestrengthVSAvoidspot weldability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies local quality by creating distinct surface layer regions with different microstructural characteristics. The first surface layer region (0-25μm from interface) contains 55% or more ferrite with grain size 2-10μm, while the second surface layer region (25-50μm from interface) contains 30% or more ferrite with grain size 1.35-7μm. This localized microstructural control improves spot weldability at the surface while maintaining high strength in the bulk material, resolving the contradiction between strength and weldability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent applies preliminary action by forming an internal oxidation layer with average depth of 2μm or more before the hot-dip galvanizing process. This pre-formed oxidation layer serves as a barrier that prevents zinc penetration into microcracks during subsequent welding operations, thereby preventing liquid metal embrittlement before the welding process occurs.

Inventive Principle:
Principle #10Preliminary action

2Strength

If alloy elements (Si, Al, Mn) are added to increase strength, then tensile strength and yield strength are improved, but surface quality deteriorates due to oxide formation and non-plating

Engineering Contradiction:
Improvetensile strengthVSAvoidsurface quality
Core Design Contradiction:
StrengthVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by forming an internal oxidation layer with average depth of 2μm or more through controlled oxidation before hot-dip galvanizing. This pre-formed oxidation layer acts as a barrier that prevents excessive diffusion of alloy elements (Si, Al, Mn) to the surface during subsequent processing, thereby preventing surface oxide formation and non-plating defects while maintaining the strength-enhancing alloy composition in the bulk material.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent applies local quality by creating a specific microstructure in the surface layer regions with controlled ferrite content and grain size. The first surface layer region has 55% or more ferrite with grain size 2-10μm, and the second surface layer region has 30% or more ferrite with grain size 1.35-7μm. This localized microstructural control reduces oxide formation on the surface while maintaining high strength properties in the bulk material.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively reduces the likelihood of LME during spot welding and improves surface quality by inhibiting the formation of oxides and ensuring uniform plating adhesion, thereby enhancing the overall performance of the galvanized steel sheet.

Implementation Method 1

an average depth (a) of an internal oxidation layer formed on the base steel sheet may be 2 μm or more

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 2

a fraction of ferrite contained in the first surface layer region may be 55 area % or more, an average grain size of the ferrite contained in the first surface layer region may be 2 to 10 μm

Methodology Applied
Scientific EffectPhase transformation: Phase Change

Data Source

PatentUS12331405B2High-strength hot-dipped galvanized steel sheet having excellent surface quality and spot weldability, and manufacturing method therefor
Publication Date: 2025.06.17 POHANG IRON & STEEL CO LTD

AI summary

A galvanized steel sheet including a base steel sheet, and a zinc-based plating layer on the surface of the base steel sheet. The base steel sheet may include a first surface layer region corresponding to a depth of 25 μm from an interface between the base steel sheet and the zinc-based plating layer in a thickness direction of the base steel sheet, and a second surface layer region adjacent to the first surface layer region and corresponding to a depth of 25 μm to 50 μm in the thickness direction of the base steel sheet. A fraction of ferrite contained in the first surface layer region is 55 area % or more, an average grain size of the ferrite contained in the first surface layer region is 2 to 10 μm, and a fraction of ferrite contained in the second surface layer region is 30 area % or more.