Galvannealed Steel Sheet Coating for Weld Crack Resistance

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Solution Overview

Problem

Conventional galvannealed steel sheets fail to provide sufficient resistance to cracking during resistance welding, particularly in high-strength Si-containing sheets, due to issues with grain boundary oxidation and liquid metal embrittlement.

Innovation Solution

A specific heat treatment process is applied to form an Fe-based electroplating layer on a Si-containing cold-rolled steel sheet, controlling the properties of the layer to refine crystal grains and form internal oxides, thereby delaying zinc penetration and reducing residual stresses during welding.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If high-strength Si-containing steel sheets are used to increase strength, then tensile strength is improved, but resistance to cracking in resistance welding deteriorates due to liquid metal embrittlement

Engineering Contradiction:
Improvetensile strengthVSAvoidresistance to cracking in resistance welding
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies preliminary action by performing Fe-based electroplating treatment before hot-dip galvanizing to pre-form a protective layer on the steel sheet surface. This pre-layer prevents zinc penetration and grain boundary oxidation during subsequent hot-dip galvanizing and resistance welding processes, thereby suppressing liquid metal embrittlement cracking while maintaining high strength

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses an Fe-based electroplating layer as an intermediary between the high-strength Si-containing steel sheet and the hot-dip galvanizing coating. This intermediate layer acts as a barrier that prevents direct contact between molten zinc and the steel substrate, eliminating the condition for liquid metal embrittlement while allowing the high-strength steel to maintain its mechanical properties

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If grain boundary oxidation depth is reduced to suppress cracking, then resistance to cracking is improved, but the protective effect against zinc penetration is weakened

Engineering Contradiction:
Improveresistance to crackingVSAvoidzinc penetration
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies preliminary action by forming an Fe-based electroplating layer before hot-dip galvanizing. This pre-formed layer serves as a protective barrier that prevents zinc penetration during the hot-dip process, eliminating the need to reduce grain boundary oxidation depth to suppress cracking while still providing adequate protection against zinc penetration

Inventive Principle:
Principle #10Preliminary action

3Ease of operation

If welding is performed with electrode at angle to steel sheet to accommodate part geometry, then ease of assembly is improved, but residual stresses increase and cracking risk worsens

Engineering Contradiction:
Improveease of assemblyVSAvoidresistance to cracking
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies preliminary action by pre-forming an Fe-based electroplating protective layer before welding. This pre-layer is applied regardless of the welding electrode angle and provides continuous protection against zinc penetration and grain boundary oxidation, thereby maintaining resistance to cracking even when welding is performed at angles that generate residual stresses

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method enhances the steel sheet's resistance to cracking, especially internal cracking, by dispersing penetration paths and relaxing stress, resulting in improved weld integrity.

Implementation Method 1

a specific heat treatment process is applied to form an Fe-based electroplating layer on a Si-containing cold-rolled steel sheet, controlling the properties of the layer to refine crystal grains and form internal oxides

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Implementation Method 2

form internal oxides, thereby delaying zinc penetration and reducing residual stresses during welding

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 3

liquid metal embrittlement (LME) may occur during resistance welding when residual stresses are generated in the vicinity of a welded portion and the zinc in the coated or plated layer melts and diffuses into crystal grain boundaries

Methodology Applied
Scientific EffectLiquid metal embrittlement:

Implementation Method 4

reducing residual stresses during welding

Methodology Applied
Scientific EffectStress relaxation: Stress Relaxation

Data Source

PatentUS12473652B2Galvannealed steel sheet, electrodeposition-coated steel sheet, automotive part, method of producing electrodeposition-coated steel sheet, and method of producing galvannealed steel sheet
Publication Date: 2025.11.18 JFE STEEL CORP
  • US12473652B2 patent drawing
  • US12473652B2 patent drawing
  • US12473652B2 patent drawing

AI summary

Disclosed is a galvannealed steel sheet including: a Si-containing cold-rolled steel sheet containing Si in an amount of 0.1 mass % or more and 3.0 mass % or less; an Fe-based electroplating layer formed on at least one surface of the Si-containing cold-rolled steel sheet; and a galvannealed layer formed on the Fe-based electroplating layer, in which in an intensity profile measured by glow discharge optical emission spectrometry, ISi,Fe/ISi,bulk is 0.30 or more, and an average value of C concentration in a region ranging from 10 μm to 20 μm in the thickness direction from the interface between the galvannealed layer and the Fe-based electroplating layer towards the Fe-based electroplating layer is 0.10 mass % or less.