GaN HEMT TiN Gate Layer Composition Against Etching and Oxidation

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Solution Overview

Problem

Existing high electron mobility transistors (HEMTs) fabricated from GaN-based materials face challenges in maintaining the integrity of the titanium nitride (TiN) layer during manufacturing processes, leading to issues with etching and oxidation.

Innovation Solution

The method involves forming a TiN layer with a nitrogen to titanium (N/Ti) ratio greater than 1 and adjusting the (200)/(111) orientation ratio to enhance the strength and protection of the p-type semiconductor layer. This is achieved by optimizing the semiconductor equipment power and gas ratio during TiN layer formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional TiN layer is formed during HEMT fabrication, then the layer provides basic protection and electrical function, but the layer suffers from etching and oxidation issues leading to integrity loss

Engineering Contradiction:
ImproveTiN layer integrityVSAvoidetching and oxidation
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies parameter changes by controlling the nitrogen to titanium (N/Ti) ratio greater than 1 during TiN layer formation and adjusting the (200)/(111) orientation ratio. These parameter modifications transform the TiN layer properties to achieve enhanced anti-etching and anti-oxidation capabilities while maintaining electrical performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material approach by forming a TiN layer with specific compositional characteristics (N/Ti ratio > 1) and crystallographic orientation properties. This composite structure combines protective properties with electrical functionality, resolving the contradiction between basic protection and resistance to harmful factors

Inventive Principle:
Principle #40Composite materials

2Reliability

If the TiN layer is optimized for better protection, then anti-etching and anti-oxidation features improve, but the manufacturing process complexity increases

Engineering Contradiction:
Improveanti-etching and anti-oxidation featuresVSAvoidmanufacturing process
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent implements parameter changes during the TiN layer formation process, specifically controlling the N/Ti ratio and (200)/(111) orientation ratio. These parameter adjustments are integrated into the existing manufacturing workflow, enhancing protection features without requiring fundamentally new manufacturing steps

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies preliminary action by optimizing the TiN layer properties during its formation process itself, rather than requiring subsequent treatment steps. The N/Ti ratio and orientation control are established during deposition, preventing etching and oxidation issues before they occur

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The approach results in a TiN layer with improved anti-etching and anti-oxidation features, reducing thickness loss during manufacturing and enhancing the overall performance and reliability of the HEMT.

Implementation Method 1

The approach results in a TiN layer with improved anti-etching and anti-oxidation features

Methodology Applied
Scientific EffectOxidation resistance: Oxidation

Implementation Method 2

The approach results in a TiN layer with improved anti-etching and anti-oxidation features

Methodology Applied
Scientific EffectEtching resistance: Ablation

Implementation Method 3

forming a titanium nitride (TiN) layer on the p-type semiconductor layer

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 4

forming a titanium nitride (TiN) layer on the p-type semiconductor layer

Methodology Applied
Scientific EffectChemical vapor deposition: Chemical Vapour Deposition

Data Source

PatentUS12336245B2High electron mobility transistor and method for fabricating the same
Publication Date: 2025.06.17 UNITED MICROELECTRONICS CORP
  • US12336245B2 patent drawing

AI summary

A method for fabricating high electron mobility transistor (HEMT) includes the steps of forming a buffer layer on a substrate, forming a barrier layer on the buffer layer, forming a p-type semiconductor layer on the barrier layer, forming a titanium nitride (TiN) layer on the p-type semiconductor layer as a nitrogen to titanium (N/Ti) ratio of the TiN layer is greater than 1, forming a passivation layer on the TiN layer and the barrier layer, removing the passivation layer to form an opening, forming a gate electrode in the opening, and then forming a source electrode and a drain electrode adjacent to two sides of the gate electrode on the barrier layer.