GaN HEMT Two-Step Annealing for Oxide Removal

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The challenge in fabricating high electron mobility transistors (HEMTs) on silicon substrates is the low quality surface native oxide, which hinders material electron mobility and device performance due to the larger lattice mismatch between silicon and gallium nitride, leading to suboptimal radio frequency (RF) performance.

Innovation Solution

A two-step annealing process using rapid thermal annealing in forming gas (FG) followed by nitrogen (N2) is employed to remove the native oxide, improving the surface properties of InAlN/GaN HEMTs on silicon substrates, involving epitaxial layer deposition, mesa formation, metal stack deposition, and T-shaped gate formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If in-situ remote plasma pretreatment is used to remove surface native oxide, then surface oxide removal capability is improved, but surface damage increases

Engineering Contradiction:
Improvesurface oxide removalVSAvoidsurface damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the chemical environment parameters by using forming gas (5% H2 in N2) instead of plasma, and controls temperature parameters (700-900°C) to achieve oxide removal through chemical reduction rather than plasma etching, thereby avoiding surface damage while removing native oxide

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses forming gas (5% H2 in N2) as an inert/reducing atmosphere for annealing, which provides a controlled environment that removes surface oxide through chemical reduction while preventing further oxidation and minimizing surface damage compared to plasma treatment

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

2Ease of manufacture

If silicon substrate is used instead of silicon carbide substrate, then cost is reduced and scaling capability is improved, but lattice mismatch increases leading to lower material quality

Engineering Contradiction:
Improvecost and scalingVSAvoidmaterial quality
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent changes the thermal processing parameters by implementing a two-step annealing process with specific temperature ranges (700-900°C in forming gas, then 750-950°C in N2), which compensates for the lattice mismatch by improving material quality through controlled thermal treatment

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses inert/reducing atmosphere annealing to improve material quality on silicon substrate by removing surface oxide and reducing defects, thereby compensating for the lattice mismatch between silicon and GaN while maintaining the cost and scaling advantages of silicon substrates

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Ease of manufacture

If surface native oxide is present, then device fabrication is simplified, but electron mobility and device performance deteriorate

Engineering Contradiction:
Improvefabrication simplicityVSAvoidelectron mobility and device performance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent performs preliminary surface treatment through two-step annealing in forming gas and nitrogen atmospheres before subsequent fabrication steps, which removes surface native oxide in advance and improves electron mobility, thereby ensuring high device performance without complicating the overall fabrication process

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach effectively increases two-dimensional electron gas (2DEG) electron density, reduces ohmic contact resistance, and enhances RF performance by minimizing surface damage and unintentional oxidation, resulting in improved subthreshold swing, transconductance, and power gain cutoff frequency.

Implementation Method 1

subjecting the semiconductor layer surface to a rapid thermal annealing (RTA) system for ohmic contact annealing in H2/N2 forming gas

Methodology Applied
Scientific EffectThermal reduction: Reduction

Implementation Method 2

subjecting the semiconductor layer surface to the RTA system for ohmic contact annealing in nitrogen (N2)

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 3

subjecting the semiconductor layer surface to an oxygen plasma treatment

Methodology Applied
Scientific EffectPlasma etching: Plasma

Implementation Method 4

depositing an epitaxial layer over a substrate to form a semiconductor layer surface

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Data Source

PatentUS20220399458A1Semiconductor device and fabrication methods thereof
Publication Date: 2022.12.15 UNIVERSITY OF DELAWARE
  • US20220399458A1 patent drawing
  • US20220399458A1 patent drawing
  • US20220399458A1 patent drawing

AI summary

A semiconductor device and fabricating method thereof is disclosed. The method comprises depositing epitaxial layers over a silicon substrate to form a semiconductor layer surface; forming at least one mesa portion on the semiconductor layer surface; depositing a metal stack on the semiconductor layer surface; subjecting the semiconductor layer surface to a rapid thermal annealing system for a two-step ohmic contact annealing in H2/N2 forming gas (FG) and then nitrogen; subjecting the semiconductor layer surface to an oxygen plasma treatment; and depositing a T-shaped metal gate on the semiconductor layer surface. A semiconductor device comprises a semiconductor layer surface having an epitaxial layer disposed over a silicon substrate; at least one mesa portion formed on the semiconductor layer surface; a metal stack, disposed on the semiconductor layer surface, and sequentially annealed in FG and nitrogen; and a T-shaped metal gate on the semiconductor layer surface.